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101.
SHEN Yehua WANG Haibo BAI Quan & GENG Xindu Institute of Modern Separation Science Shaanxi Key Laboratory of Modern Separation Science Northwest University Xi''''an China 《中国科学B辑(英文版)》2005,(Z1)
The renaturation of the denaturedα-chymotrypsin (α-Chy) with 1.7 mol·L-1 gua-nidine hydrochloride (GuHCI) by three kinds of stationary phase of high performance hydropho-bic interaction chromatography (STHIC) with a comparable hydrophobicity but different ligand structures was investigated. The obtained result indicates that the ligand structures of the three STHIC contribute to the renaturation efficiency ofα-Chy in the order of the end ligands PEG-600< phenyl group < tetrahydrofurfuryl alcohol (THFA). 相似文献
102.
Yun Gong Changwen Hu Hui Li Wanlong Pan Xueli Niu Zhifa Pu 《Journal of Molecular Structure》2005,740(1-3):153-158
Two nickel (imidazole) complexes, Ni(im)6Cl2·4H2O (1) and Ni(im)6(NO3)2 (2) (im=imidazole) have been synthesized and characterized by elemental analysis, IR, UV, TG and single crystal X-ray diffraction. 1 crystallizes in the triclinic space group P-1 with a=8.800(6) Å, b=9.081(6) Å, c=10.565(7) Å, =75.058(9)°, β=83.143(8)°, γ=61.722(8)°, V=718.3(8) Å3, Z=1 and R1 (wR2)=0.0469 (0.1497). 2 crystallizes in the trigonal space group R-3 with a=12.370(6) Å, b=12.370(6) Å, c=14.782(14) Å, =90.00°, β=90.00°, γ=120.00°, V=1959(2) Å3, Z=3 and R1 (wR2)=0.0358 (0.0955). 1 and 2 exhibit different supramolecular network due to their different counter anions and different hydrogen bonding connection. In compound 1, [Ni(im)6]2+ cation and counter anions Cl− alternatively array in an ABAB fashion via N–HCl hydrogen bonding. In compound 2, the plane of each NO32− is almost parallel and each NO32− connect three different [Ni(im)6]2+ cations via N–HO hydrogen bonding. 相似文献
103.
Electrostatic layer-by-layer assembled carbon nanotube multilayer film and its electrocatalytic activity for O2 reduction 总被引:1,自引:0,他引:1
Zhang M Yan Y Gong K Mao L Guo Z Chen Y 《Langmuir : the ACS journal of surfaces and colloids》2004,20(20):8781-8785
Multilayer films of shortened multiwalled carbon nanotubes (MWNTs) are homogeneously and stably assembled on glassy carbon electrodes with the layer-by-layer (LBL) method, based on electrostatic interaction of positively charged poly(diallyldimethylammonium chloride) and negatively charged and shortened MWNTs. The film assembly and electrochemical property as well as the electrocatalytic activity toward O2 reduction of the MWNT multilayer film are studied. Scanning electron microscopy, the quartz crystal microbalance technique, ultraviolet-visible-near-infrared spectroscopy, and cyclic voltammetry are used for characterization of film assembly. Experimental results revealed that film growth is uniform, almost with the same coverage of the MWNTs in each layer, and that the assembled MWNTs are mainly in the form of small bundles or single tubes on the electrodes. Electrochemical studies indicate that the LBL assembled MWNT films possess a remarkable electrocatalytic activity toward O2 reduction in alkaline media. This property, combined with the well-dispersed, porous and conductive features of the MWNT film illustrated with the LBL method, suggests the potential application of the MWNT film for constructing an efficient alkaline air electrode for energy conversions. 相似文献
104.
Chung‐Cheng Chang Kuo‐Ching Yang Jeng‐Gong Guo Leigh‐May Huang Li‐Chyung Wang Gene‐Hsiang Lee Shie‐Ming Peng 《中国化学会会志》2003,50(5):965-971
The insertion reaction of CS2 with Mg(NR2)2 (R= Et, iPr), MgR′2 (R′= Et, Ph) and R″MgBr (R″= iPr, Ph) respectively lead solid products, Mg(S2CNR2)2(THF)n ( 1 : R= Et, n=2; 2 : R= iPr, n=1), Mg(S2C′R)2(THF)2 ( 3 : ′R= Et, 4 : ′R= Ph), BrMg(S2C″R) (THF)3 ( 5 : ″R= iPr, 6 : ″R= Ph) in which the inserted carbon disulfides act as terminal chelating ligands. These compounds were characterized with 1H, 13C NMR, IR spectroscopy, mass spectrometry, elemental analyses, and X‐ray crystallography. 相似文献
105.
The effects of the hyperbranched polyester with hydroxyl end groups (HBPE‐OH) on the curing behavior and toughening performance of a commercial epoxy resin (diglycidyl ether of bisphenol A, DGEBA) were presented. The addition of HBPE‐OH into DGEBA strongly increased its curing rate and conversion of epoxide group due to the catalytic effect of hydroxyl groups in HBPE‐OH and the low viscosity of the blend at curing temperature. The improvements on impact strength and critical stress intensity factor (or fracture toughness, K1c) were observed with adding HBPE‐OH. The impact strength was 8.04 kJ m?1 when HBPE‐OH reached 15 wt% and the K1c value was approximately two times the value of pure epoxy resin when HBPE‐OH content was 20 wt%. The morphology of the blends was also investigated, which indicated that HBPE‐OH particles, as a second phase in the epoxy matrix, combined with each other as the concentration of HBPE‐OH increased. Copyright © 2004 John Wiley & Sons, Ltd. 相似文献
106.
正Perovskite nanocrystals and quantum dots(QDs) have attracted great attention due to their potential in optical and optoelectronic applications, especially in ultra-high definition displays because of their high purity of photo/electroluminescence(PL/EL) [1,2]. Although the external quantum efficiency(EQE) of light-emitting diodes(LEDs) based on perovskite quantum dots(PeQDs) has been over 20% [3,4],another key problem, the PL/EL stability, still remains open.The thermal PL/EL quenching phenomenon, which is ubiquitously observed, has not aroused enough attention in this 相似文献
107.
Fengtian Lv Nan Li Chuankai Liu Haibo Gao Liang Ding Zongquan Deng Guangjun Liu 《Entropy (Basel, Switzerland)》2022,24(9)
It is important for Mars exploration rovers to achieve autonomous and safe mobility over rough terrain. Terrain classification can help rovers to select a safe terrain to traverse and avoid sinking and/or damaging the vehicle. Mars terrains are often classified using visual methods. However, the accuracy of terrain classification has been less than 90% in read operations. A high-accuracy vision-based method for Mars terrain classification is presented in this paper. By analyzing Mars terrain characteristics, novel image features, including multiscale gray gradient-grade features, multiscale edges strength-grade features, multiscale frequency-domain mean amplitude features, multiscale spectrum symmetry features, and multiscale spectrum amplitude-moment features, are proposed that are specifically targeted for terrain classification. Three classifiers, K-nearest neighbor (KNN), support vector machine (SVM), and random forests (RF), are adopted to classify the terrain using the proposed features. The Mars image dataset MSLNet that was collected by the Mars Science Laboratory (MSL, Curiosity) rover is used to conduct terrain classification experiments. The resolution of Mars images in the dataset is 256 × 256. Experimental results indicate that the RF classifies Mars terrain at the highest level of accuracy of 94.66%. 相似文献
108.
Biao Mu Xianfang Wu Yunfei Niu Yan Chen Xinlun Cai Yanxiao Gong Zhenda Xie Xiaopeng Hu Shining Zhu 《中国光学快报(英文版)》2021,(6):28-32
Periodically poled lithium niobate on insulator[LNOI]ridge waveguides are desirable for high-efficiency nonlinear frequency conversions,and the fabrication proc... 相似文献
109.
Haibo Wang Senling Tang Guoqing Zhang Yang Pan Wei Jiao Huawu Shao 《Molecules (Basel, Switzerland)》2022,27(17)
A series of N-substituted iminosugar C-glycosides were synthesized and tested for α-glucosidase inhibition. The results suggested that 6e is a promising and potent α-glucosidase inhibitor. Enzymatic kinetic assays indicated that compound 6e may be classified as an uncompetitive inhibitor. The study of structure-activity relationships of those iminosugars provided a starting point for the discovery of new α-glucosidase inhibitors. 相似文献
110.
In the present study, metallophthalocyanines were modified with NIT nitroxide radicals through chemical bonds to prepare a series of metallophthalocyanines–NIT catalysts (MPcTcCl8-NIT, M=Mn2+, Fe2+, Co2+, Ni2+, Cu2+ and Zn2+) applied for oxidative desulfurization of thiophene (T) in model fuel. The MPcTcCl8-NIT catalysts were characterized by FTIR, UV-Vis, ESR, and XPS spectra. The oxidative desulfurization activity of MPcTcCl8-NIT catalysts was studied in a biomimetic catalytic system using molecular O2 as the oxidant. The MPcTcCl8-NIT catalysts exhibited high catalytic activities for the oxidation of thiophene in model fuel. The desulfurization rate of ZnPcTcCl8-NIT for thiophene reached to 99.61%, which was 20.53% higher than that of pure ZnPcTcCl8 (79.08%) under room temperature and natural light. The results demonstrated that MPcTcCl8-NIT catalysts could achieve more effective desulfurization rate under milder conditions than that of the metallophthalocyanines. The NIT nitroxide radicals also could improve the catalytic activity of metallophthalocyanine based on the synergistic oxidation effect. The stability experiments for ZnPcTcCl8-NIT showed that the catalyst still had a high desulfurization rate of 92.37% after five times recycling. All these findings indicate that the application of MPcTcCl8-NIT catalysts provides a potential new way for the desulfurization performance of thiophene in fuel. 相似文献