矩孔金属光栅矢量模式理论的数值计算

根据矩孔金属光栅的矢量模式理论，计算了不同入射方向，波长及偏振态情况下衍射场的分布，研究了不同光栅结构对衍射效率，偏振态变化的影响；同时，根据实际需要，加工制作了一批不同深度的矩孔光栅样品，进行了实验测量，并将计算值与实验值进行了比较，两者基本相符。     

用13CNMR研究聚甲基丙烯酸锡酯的立构序列分布

本文测定了自由基型溶液聚合的聚甲基丙烯酸三甲基锡酯(PTMTM),聚甲基丙烯酸三乙基锡酯(PTETM)和聚甲基丙烯酸三丁基锡酯(PTBTM)的¹³C-NMR谱,对其C-2谱扩展分峰,计算立构序列,从定量数据表明,聚合物样品的空间立构富于或稍富于间规立构,随取代基的体积增大而趋于无规分布,作者认为受空间位阻效应和分子内或分子间形成配位键的影响。     

Enantioseparation of Dencichine and D-Isomer on L-Cysteine Derivative Phase by Ligand-exchange Chromatography

Dencichine (β-N-oxalyl-L-α, β-diaminopropionic acid, L-ODAP), a nonprotein amino acid, is a haemostatic agent present in important Chinese medicinal herbs such as Panax notoginseng, as well as other Panax species1. It was first isolated from the seeds …     

多功能旋流燃烧器的工业性试验研究

秦皇岛热电厂2＃锅炉燃烧不稳定、燃烧效率低等问题主要是由于燃烧器的一次风管道结构不合理造成的。本文采用多功能旋流燃烧器的设计思想对旋流燃烧器进行了技术改造和工业性试验研究。结果表明,改造后的旋流燃烧器其着火点提前,并且仅改造6只主力燃烧器就可以使锅炉在50％负荷时达到不投油而稳定燃烧,排烟温度、飞灰含碳量和NOx排放量明显下降。     

一种区间数的因子分析技术及其在证券市场中的应用

传统的因子分析技术能够有效地对高维变量空间进行降维处理,但它对于样本空间却缺乏行之有效的降维效果.为了解决这一问题,一种针对大量样本数据、新的因子分析技术———区间数因子分析技术(intervaldatafactoranalysis,IFA)被提出并得到了迅速的发展。IFA方法对传统的数据概念做了本质性的扩张,运用'数据打包'的理念,对海量原始数据在不破坏其原有内在逻辑关系的前提下,可以进行变量和样本点维度的双重降维。本文详细阐述了区间数因子分析技术的原理,并以中国股票市场为案例研究背景,结果表明IFA分析技术对大规模多维数据系统做综合简化是十分有效的。     

有限局部环Z/2\+kZ上斜对称矩阵标准形和伪辛群的阶

设R=Z/2\+kZ(k>1)是\{2\}[TX-]为非单位的有限局部环. 该文首先确定了R上斜对称矩阵标准形. 设G\+m\-p(R,H)={P∈GL\-m(R)|PHP′=H}是由矩阵H确定的伪辛群,其中H=[JB((][HL(2]0[]I\+\{(v)\}\=-I\+\{(v)\}[]0[HL)][JB))]Δ，Δ=[JB((][HL(2]\{2\}[TX-]\+\{k-1\}[]\{1\}[TX-]\=-\{1\}[TX-][]0[HL)][JB))]. 其次,计算了伪辛群G\+m\-P(R,H)的阶|G\+m\-P(R,H)|.     

Assembly and Photophysics of Ternary Luminescent Lanthanide Molecular Complex Systems

In this paper, according to the molecular fragment principle, a series of eight ternary luminescent lanthanide complex systems were assembled, and whose compositions were determined with elemental analysis and infrared spectrum: Ln(MA)₃(L)·H₂O, where Ln = Sm, Eu, Tb, Dy; HMA = α‐methylacrylic acid; L = 1,10‐phenanthroline (phen), 2,2′‐bipyridine (bipy). The photophysical properties of these functional molecular systems were studied with ultraviolet‐visible absorption spectrum, and fluorescence excitation and emission spectrum. It was found that the heterocylic compounds (phen and bipy) act as the main energy donor and luminescence sensitizer for their suitable energy match and effective energy transfer to the emission energy level of Ln³⁺ ions. MMA ligand was only used as the terminal structural ligand to influence the luminescence. Especially terbium complex systems show the strongest luminescence for the optimum energy match and transfer between phen (bipy) and Tb³⁺ ion.     

基于cDNA宏阵列的系统聚类分析猪发育阶段的基因表达谱

取杜洛克猪胚胎第33,45,55，65．75天的背最长肌样本．用cDNA Macroarray分析方法和聚类分析技术分析了327个EST在骨骼肌内不同发育阶段的基因表达谱．结果表明有98条EST在不同发育时期显著差异表达．第33天和第45天两阶段基因表达状态相似．第55天和第65天基因表达状态相似．而第75天的基因表达与第55天和第65天两个阶段的基因表达具有相近的聚类关系．表达状态相近，基因功能相似的基因大都被聚类在一起．     

On W-solvability for special vectorial Hamilton-Jacobi systems

We study the solvability of special vectorial Hamilton-Jacobi systems of the form F(Du(x))=0 in a Sobolev space. In this paper we establish the general existence theorems for certain Dirichlet problems using suitable approximation schemes called W^1,p-reduction principles that generalize the similar reduction principle for Lipschitz solutions. Our approach, to a large extent, unifies the existing methods for the existence results of the special Hamilton-Jacobi systems under study. The method relies on a new Baire's category argument concerning the residual continuity of a Baire-one function. Some sufficient conditions for W^1,p-reduction are also given along with certain generalization of some known results and a specific application to the boundary value problem for special weakly quasiregular mappings.     

Clustering study in Eu(DBM)3Phen-doped polymer optical fibers by optical properties and near-field scanning microscopy

The clusters of Eu3+ ion in Eu(DBM)3Phen-doped polymethyl methacrylate (PMMA) have been studied by three means. The relative fluorescence intensity ratio of the 5D0 → 7F2 to 5D0 → 7F1 transitions with different concentrations of Eu3+ in Eu(DBM)3Phen-doped PMMA and metastable-state (5D0) lifetime dependence on Eu3+ concentration are analyzed. The analysis indicates that there are no clustering effects in Eu3+ ions of Eu(DBM)3Phen-doped PMMA when the Eu3+ doping concentration is up to 1.0 wt.-%. At the same time, the clustering effect has not been observed by the scanning near-field optical microscopy (SNOM) in Eu(DBM)3Phen-doped PMMA with 1.0 wt.-% of Eu3+ ions. The analysis reveals that a high concentration of Eu3+ can be incorporated into polymer optical fiber (POF) without clustering effect.OCIS codes: 180.5810, 300.6280, 250.5460, 160.5690.