全文获取类型
收费全文 | 142095篇 |
免费 | 27268篇 |
国内免费 | 13281篇 |
专业分类
化学 | 111641篇 |
晶体学 | 1654篇 |
力学 | 7811篇 |
综合类 | 784篇 |
数学 | 15106篇 |
物理学 | 45648篇 |
出版年
2024年 | 243篇 |
2023年 | 2151篇 |
2022年 | 2902篇 |
2021年 | 3918篇 |
2020年 | 5355篇 |
2019年 | 6383篇 |
2018年 | 4487篇 |
2017年 | 3982篇 |
2016年 | 8206篇 |
2015年 | 8141篇 |
2014年 | 9195篇 |
2013年 | 11654篇 |
2012年 | 12441篇 |
2011年 | 12381篇 |
2010年 | 9646篇 |
2009年 | 9312篇 |
2008年 | 9375篇 |
2007年 | 8306篇 |
2006年 | 7522篇 |
2005年 | 6554篇 |
2004年 | 5161篇 |
2003年 | 4325篇 |
2002年 | 4776篇 |
2001年 | 3660篇 |
2000年 | 3251篇 |
1999年 | 2634篇 |
1998年 | 2043篇 |
1997年 | 1846篇 |
1996年 | 1997篇 |
1995年 | 1591篇 |
1994年 | 1539篇 |
1993年 | 1236篇 |
1992年 | 1124篇 |
1991年 | 1029篇 |
1990年 | 833篇 |
1989年 | 588篇 |
1988年 | 494篇 |
1987年 | 407篇 |
1986年 | 391篇 |
1985年 | 342篇 |
1984年 | 252篇 |
1983年 | 167篇 |
1982年 | 146篇 |
1981年 | 109篇 |
1980年 | 83篇 |
1979年 | 44篇 |
1978年 | 36篇 |
1976年 | 36篇 |
1975年 | 36篇 |
1974年 | 45篇 |
排序方式: 共有10000条查询结果,搜索用时 31 毫秒
941.
This paper presents the applications of digital image correlation technique to the mesoscopic damage and fracture study of
some granular based composite materials including steelfiber reinforced concrete, sandstone and crystal-polymer composite.
The deformation fields of the composite materials resulted from stress localization were obtained by the correlation computation
of the surface images with loading steps and thus the related damage prediction and fracture parameters were evaluated. The
correlation searching could be performed either directly based on the gray levels of the digital images or from the wavelet
transform (WT) coefficients of the transform spectrum. The latter was developed by the authors and showed higher resolution
and sensitivity to the singularity detection. Because the displacement components came from the rough surfaces of the composite
materials without any coats of gratings or fringes of optical interferometry, both surface profiles and the deformation fields
of the composites were visualized which was helpful to compare each other to analyze the damage of those heterogeneous materials.
The project supported by the National Natural Science Foundation of China (10125211 and 10072002), the Scientific Committee
of Yunnan Province for the Program of Steel Fiber Reinforced Concrete, and the Institute of Chemical Materials, CAEP at Mianyang 相似文献
942.
研究了非相干辐照对LiNbO3:Fe晶体中从自散焦到自聚焦的动态转换过程的影响和控制作用.无论是从前向还是从背向加入非相干辐照,都能加快自散焦、自聚焦过程以及从自散焦到自聚焦的转换过程,增大折射率的变化值.当非相干辐照以一定的时间间隔重复辐照在晶体上时,透射功率能迅速地上升和下降,具有明显的开关效应.这种在非相干辐照控制下折射率的迅速改变有望应用于全光学开关器件.
关键词:
非相干辐照
光伏效应
自散焦
自聚焦 相似文献
943.
The classes ofL
1-matrices,L
2-matrices,L
3-matrices andW-matrices are introduced to study solvability of a linear complementarity problem via solving a linear program. Three sufficient
conditions are presented to guarantee that a linear complementarity problem is solvable via a linear program. The new sufficient
conditions are weaker than the ones introduced by Mangasarian. This fact is also illustrated by an example.
Partially supported by NSFC.
This author is also with College of Business Administration of Human University as a Lotus chair professor. 相似文献
944.
The optical nonlinearities of Cu(mpo)2 [formula = C10H8N2CuO2S2] complex have firstly been investigated by using the Z-scan technique with a nanosecond-pulsed Nd:YAG laser at its second harmonic (532 nm) radiation. The nonlinear optical absorption and refraction coefficients of Cu(mpo)2 have been measured with the different on-axial peak irradiances I
0 at the waist ranging from 0.48 to 5.66 GW/cm2. The nonlinear transmittance characteristics exhibit the near resonant two-photon absorption (TPA) at 532 nm and are explained by a population redistribution model. The nonlinear absorption originates from the near resonant TPA while the mechanism of the nonlinear refraction is the near resonant TPA transition enhancement. The linear increasing dependences of the optical nonlinearities on the incident irradiance arise from the population redistribution due to the near resonant TPA. 相似文献
945.
We report on Raman scattering of VO2 films prepared by radio frequency magnetron sputtering under different conditions. Our investigations revealed that the dominated Raman peaks shift towards high frequency for both V-rich and O-rich VO2 films, compared with the stoichiometry VO2 films. The experimental evidence is presented and the cause for nonstoichiometry dependence of Raman spectra of VO2 films is discussed. 相似文献
946.
The central zinc(II) atom in the title complex is tetrahedrally coordinated by four nitrogen atoms derived from 4‐methyl‐5‐imidazolecarboxyaldehyde ligands with Zn? N in the range 2.007(3) to 2.026(4) Å. Copyright © 2003 John Wiley & Sons, Ltd. 相似文献
947.
A one‐dimensional zinc(II) coordination polymer has been constructed from zinc(II), 4,4′‐biphenyldicarboxylate and pyridine in which each zinc(II) atom is coordinated by two pyridine ligands and two monodentate 4,4′‐biphenyldicarboxylate ligands that define a distorted tetrahedral geometry. Copyright © 2003 John Wiley & Sons, Ltd. 相似文献
948.
采用PM 3半经验方法对肾上腺素和二甲亚砜与肾上腺素形成的 1∶1复合物的结构进行了几何优化 .在此基础上用密度泛函理论 (DFT)的B3LYP方法 ,分别在 6 31G、6 31G 、6 31+G 基组水平上进行了精确计算 ,并通过单点能计算考察了它们之间在形成各种复合物前后的能量和分子结构参数变化特点 .在各基组水平上所有物种的能量均进行零点振动能 (ZPVE)校正 .计算结果表明 ,二甲亚砜与肾上腺素能形成 6种稳定的复合物 ,在这些复合物中都具有较强的氢键作用 .计算结果能够解释有关实验现象 相似文献
949.
Investigation on ultrafast thrid—order optical nonlinearity of metal(dmit)2/mnt)2 Charge transfer complexes
下载免费PDF全文
![点击此处可从《中国物理》网站下载免费的PDF全文](/ch/ext_images/free.gif)
We have investigated the transient third-order optical nonlinearity of the solutions of Metal(dmit)2/(mnt)2 salts in acetone by employing femtosecond optical Kerr gate measurement at 830nm wavelength.An order of enhancement on the second-order hyperppolarizability is found for the above salts with central atoms of Cu and Ni.We have suggested an explanation for the enhancement based on the extension of electronic conjugation by the entring Cu or Ni atom. 相似文献
950.
A rapid and sensitive flow-injection spectrophotometric method is proposed for the determination of sulfadiazine and sulfamethoxazole. This method is based on the diazotization of sulfonamide with sodium nitrite, and a coupling reaction of the diazo-compound with alpha-naphthylamine. The optimum experimental conditions are obtained by using the controlled and weighted centroid simplex method. The linear ranges for the determination of sulfadiazine and sulfamethoxazole are 0.2-20 microg ml(-1) and 0.1-20 microg ml(-1), and their detection limits are 0.06 microg ml(-1) and 0.05 microg ml(-1), respectively, and the sampling frequency is 130 samples per hour. The method has been used to determine sulfadiazine and sulfamethoxazole in pharmaceuticals and urine without separation. The results are in agreement with those obtained by a high-performance liquid chromatograph technique at the 95% confidence level. 相似文献