Study of the Solid—Liquid Equilibrium in Mixed Alkaline Earth Fluorohalides

We have studied the solid-liquid equilibrium of the system Sr_1–yBa_yFCl_1–xBr_x using DTA and X-ray diffraction techniques. The entire composition range in this system yields solid solutions which crystallize in the PbFCl (Matlockite) structure type. The melting points of the entire composition range have been parametrized (within 5°C rms error) using a biquadratic fit of the available data obtained by experiment and from the literature.This revised version was published online in November 2005 with corrections to the Cover Date.     

High-K band structures in 164Er

High-spin states of the doubly-odd ¹¹²Sb were studied by in-beam spectroscopy using the ⁸⁸Sr (²⁸Si, p3n) and ⁸⁹Y (²⁹Si, α2n) fusion-evaporation reactions at beam energies of 120 and 108 MeV, respectively. γ?γ, charged particle-γ?γ coincidences, and γ?γ angular correlation analyses were employed for determining the level scheme of ¹¹²Sb. In the present work, all the levels except for low-lying states in ¹¹²Sb were newly established. Two ΔI = 1 strongly coupled bands were observed; one is a negative-parity band that is similar to those observed in the neighboring doubly-odd Sb isotopes and the other is a positive-parity band that has a new type structure not observed in the other isotopes. From the similarity of the properties of these ΔI = 1 bands to the bands built on 9/2⁺ 2p?1h states in the odd-A Sb isotopes, we suggest that these two ΔI = 1 bands should be associated with the [π(g_9/2)^?1 ? νh_11/2] and [π(g_9/2)^?1νg_7/2] configurations, respectively.     

FAB of peptides study: Deuterated glycerol matrix and selectively deuterated peptides. Part II

Abstract

Two peptides, H-Gly-Lys-Thr-Gly-Pro-Gly-OH (1) and Leu-enkephalin (2) FAB-PI spectra in normal and deuterated glycerol have been studied. Two C-deuterated and D₂O exchanged analogs have been used to compare their fragmentation to unlabelled peptides.

The mass spectrometry of peptides has become a particularly interesting field with the wide spread adoption of the FAB technique. This technique enables one to record the quasi-molecular ion (in both positive and negative modes as M+1 or M?1 respectively) and to extract from the spectrum valuable information on the peptide sequence.     

Impact of Pore Clogging by Bacteria on Underground Hydrogen Storage

The idea of underground storage of hydrogen exists today in several forms. One of the most promising methods is the option of underground methanation, which consists of injecting H₂ and CO₂ into an underground porous reservoir (aquifer) and converting them into methane by means of methanogenic bacteria that initiate the methanation reaction. However, due to their activities, the high accumulation of bacteria in the pore walls causes pore-clogging (microbial-induced clogging); one of the main problems that can become an obstacle to the implementation of this idea. In this paper, we develop a conceptual model of bio-clogging, which consists of several stages of attachment to pore walls, detachment from the walls and pore plugging by the biomass growth. This model was built into the numerical model of multicomponent two-phase flow. The effect of bio-clogging on gas movement in the storage was analyzed numerically. It has been found that bio-clogging reduces vertical rise of hydrogen and results in more uniform radial gas penetration into the reservoir.

     

Quantitative Assessment of B−B−B,B−Hb−B,and B−Ht Bonds: From BH3 to B12H122−

We report the thermodynamic stabilities and the intrinsic strengths of three-center-two-electron B−B−B and B−H_b−B bonds ( : bridging hydrogen), and two-center-two-electron B−H_t bonds ( : terminal hydrogen) which can be served as a new, effective tool to determine the decisive role of the intermediates of hydrogenation/dehydrogenation reactions of borohydride. The calculated heats of formation were obtained with the G4 composite method and the intrinsic strengths of B−B−B, B−H_b−B, and B−H_t bonds were derived from local stretching force constants obtained at the B3LYP-D2/cc-pVTZ level of theory for 21 boron-hydrogen compounds, including 19 intermediates. The Quantum Theory of Atoms in Molecules (QTAIM) was used to deepen the inside into the nature of B−B−B, B−H_b−B, and B−H_t bonds. We found that all of the experimentally identified intermediates hindering the reversibility of the decomposition reactions are thermodynamically stable and possess strong B−B−B, B−H_b−B, and B−H_t bonds. This proves that thermodynamic data and intrinsic B−B−B, B−H_b−B, and B−H_t bond strengths form a new, effective tool to characterize new (potential) intermediates and to predict their role for the reversibility of the hydrogenation/dehydrogenation reactions.     

(68)(28)Ni(40): Magicity versus superfluidity

The neutron-rich (66,68)Ni have been produced at GANIL via interactions of a 65.9A MeV 70Zn beam with a 58Ni target. Their reduced transition probability B(E2;0(+)(1)-->2+) has been measured for the first time by Coulomb excitation in a (208)Pb target at intermediate energy. The B(E2) value for (68)Ni(40) is unexpectedly small. An analysis in terms of large scale shell model calculations stresses the importance of proton core excitations to reproduce the B(E2) values and indicates the erosion of the N = 40 harmonic-oscillator subshell by neutron-pair scattering.     

Comparative quadrupole moments of triaxial superdeformed states in 163, 164, 165Lu

Average transition quadrupole moments in the yrast triaxial superdeformed bands of ¹⁶³Lu, ¹⁶⁴Lu and ¹⁶⁵Lu were determined in a Doppler-shift attenuation-method experiment. Fractional Doppler shifts were determined in γ-ray coincidence spectra measured with the Gammasphere array. The transition quadrupole moments derived from these data show a decrease from ¹⁶³Lu to ¹⁶⁵Lu which is not predicted by total-energy surface calculations. Received: 12 August 2002 / Accepted: 23 October 2002 / Published online: 10 December 2002 RID="a" ID="a"e-mail: schoenwa@iskp.uni-bonn.de Communicated by D. Schwalm     

Study of 170,171,173Ta isotopes at high spinṡ

High-spin data are presented for ¹⁷⁰Ta and ¹⁷¹Ta for the first time, and the known level scheme of ¹⁷³Ta is extended to higher spins. Anomalies found in the crossing frequencies for the alignment of a pair of neutrons are considered. At high spin a large and constant value of J⁽²⁾, with J⁽²⁾ > J⁽¹⁾, is found for two ¹⁷¹Ta bands and the implications of this are discussed. The πi_13/2 [660]1/2⁺, α = + 1/2 orbital is identified as it crosses the rotational band built on the [402]5/2⁺, α = + 1/2 orbital in ¹⁷¹Ta. Magnetic transition probabilities obtained from measured branching ratios show the effects of the aligning pair of neutrons and the spectator orbital. The data are interpreted using cranked shell-model calculations and a semiclassical vector-coupling scheme developed by Donau and Frauendorf.     

Coexisting wobbling and quasiparticle excitations in the triaxial potential well of 163 Lu

High-spin states of the nucleus ¹⁶³Lu have been populated through the fusion-evaporation reaction ¹³⁹La(²⁹Si, 5n) with a beam energy of 157 MeV. In addition to the two lowest excited triaxial strongly deformed (TSD) bands, recently interpreted as one- and two-phonon wobbling excitations, a third excited TSD band has been firmly established decaying to the yrast TSD band. The assignment of this band as a three-quasiparticle band shows together with the normal deformed (ND) level scheme the presence not only of shape coexistence between ND and TSD structures, but also an interplay of wobbling and quasiparticle excitations in the triaxial strongly deformed potential well of ¹⁶³Lu.Received: 18 July 2003, Revised: 28 August 2003, Published online: 23 December 2003PACS: 21.10.-k Properties of nuclei; nuclear energy levels - 23.20.Lv transitions and level energies - 25.70.-z Low and intermediate energy heavy-ion reactions - 27.70. + q H. Amro: Present address: Wright Nuclear Structure Laboratory, Yale University, New Haven, CT 06520-8124, USA.