Evidence for wobbling excitation in 161Lu

High-spin states in ¹⁶¹Lu were investigated using the EUROBALL spectrometer. A previously known triaxial superdeformed band has been extended to higher spins and a new band with similar characteristics has been discovered. Comparison to systematically occurring wobbling bands in Lu isotopes strongly suggests that these two bands represent the n_w = 0 and 1 wobbling excitations in ¹⁶¹Lu.     

Co-existing coupling schemes at high spin in 166Hf

The nucleus ¹⁶⁶Hf has been populated by the reaction ⁹⁶Zr(⁷⁴Ge,4n) using a beam energy of 310MeV. γ-rays were detected with the EUROBALL III detector array. Fourteen new normal-deformed rotational bands, of which six form coupled pairs, have been observed in ¹⁶⁶Hf. Four previously known bands have been extended to considerably higher spin, and configurations of the new bands are proposed. Two different bands have been assigned configurations involving the same orbitals at high spin. The two coupling schemes, deformation and rotation alignment, are discussed in connection with this new observation, which calls for a formulation of co-existing coupling schemes in six-quasiparticle structures involving the same orbitals at high spin.     

Geometric magnetic frustration in Ba(2)Sn(2)Ga(3)ZnCr(7)O(22): a two-dimensional spinel based Kagomé lattice

The properties of a two-dimensional geometrically frustrated magnetic material based on the Kagomé net, Ba(2)Sn(2)ZnGa(3)Cr(7)O(22), are reported. The Kagomé net is fully filled with magnetic ions. A Curie-Weiss theta theta(W) = -312 K is found with a spin glass transition at approximately 1.5 K, indicating strong geometrical magnetic frustration. This compound is the most two dimensional of a structural series with the geometrically frustrated materials ZnCr(2)O(4) and SrCr(8)Ga(4)O(19). The comparison of their properties tests the influence of different degrees of coupling between Kagomé layers on magnetic frustration within a single chemical and structural family.     

On the crystallochemical origin of the disordered form of Ba7(EuII)F12Cl2 and the structural changes induced at high temperature

The crystal structure of the disordered modification of Ba₇F₁₂Cl₂ has been carefully re‐examined on several new crystals prepared under different conditions of synthesis. All single crystal structure refinements reveal a residual electron density of ∼3 e^–/ų in the 0,0,0 position which is explained by the introduction of a small amount of sodium ions in the crystal. The title compound transforms from a disordered to an ordered modification at ∼800 °C. New structural data show a change in space group from P6₃/m to P6. During this process, a slight chemical change and the formation of nano‐channels in the crystals is observed by electron microscopy. These changes were further studied by electron microprobe analysis, by spectroscopic methods and thermal analysis. (© 2006 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)     

Linking Composition,Structure and Thickness of CoOOH layers to Oxygen Evolution Reaction Activity by Correlative Microscopy

The role of β-CoOOH crystallographic orientations in catalytic activity for the oxygen evolution reaction (OER) remains elusive. We combine correlative electron backscatter diffraction/scanning electrochemical cell microscopy with X-ray photoelectron spectroscopy, transmission electron microscopy, and atom probe tomography to establish the structure–activity relationships of various faceted β-CoOOH formed on a Co microelectrode under OER conditions. We reveal that ≈6 nm β-CoOOH(01 0), grown on [ 0]-oriented Co, exhibits higher OER activity than ≈3 nm β-CoOOH(10 3) or ≈6 nm β-CoOOH(0006) formed on [02 - and [0001]-oriented Co, respectively. This arises from higher amounts of incorporated hydroxyl ions and more easily reducible Co^III−O sites present in β-CoOOH(01 0) than those in the latter two oxyhydroxide facets. Our correlative multimodal approach shows great promise in linking local activity with atomic-scale details of structure, thickness and composition of active species, which opens opportunities to design pre-catalysts with preferred defects that promote the formation of the most active OER species.