全文获取类型
收费全文 | 158篇 |
免费 | 3篇 |
国内免费 | 5篇 |
专业分类
化学 | 108篇 |
晶体学 | 1篇 |
力学 | 5篇 |
数学 | 6篇 |
物理学 | 46篇 |
出版年
2024年 | 3篇 |
2023年 | 3篇 |
2022年 | 23篇 |
2021年 | 27篇 |
2020年 | 11篇 |
2019年 | 8篇 |
2018年 | 7篇 |
2016年 | 6篇 |
2015年 | 5篇 |
2014年 | 3篇 |
2013年 | 7篇 |
2012年 | 9篇 |
2011年 | 11篇 |
2010年 | 2篇 |
2009年 | 1篇 |
2008年 | 3篇 |
2007年 | 5篇 |
2006年 | 1篇 |
2005年 | 3篇 |
2002年 | 6篇 |
2001年 | 2篇 |
2000年 | 1篇 |
1999年 | 2篇 |
1998年 | 2篇 |
1996年 | 2篇 |
1995年 | 1篇 |
1994年 | 2篇 |
1993年 | 1篇 |
1992年 | 1篇 |
1990年 | 1篇 |
1989年 | 2篇 |
1987年 | 1篇 |
1984年 | 1篇 |
1983年 | 1篇 |
1980年 | 1篇 |
1957年 | 1篇 |
排序方式: 共有166条查询结果,搜索用时 15 毫秒
21.
22.
Nicolas Droushiotis Uttam Doraswami Douglas Ivey Mohd Hafiz Dzarfan Othman Kang Li Geoff Kelsall 《Electrochemistry communications》2010,12(6):792-795
A phase inversion process was used to co-extrude cerium–gadolinium oxide (Ce0.9Gd0.1O1.95)/NiO–CGO dual-layer hollow fibres (HF), which were then sintered to form, respectively, the electrolyte and high porosity anode precursor of a solid oxide fuel cell (SOFC) with anode inner diameter of 0.8 mm. Graded CGO–lanthanum strontium cobalt ferrite (La0.6Sr0.4Fe0.8Co0.2O3) cathode layers were then painted onto the CGO electrolyte to form a micro-tubular HF-SOFC. With a carefully designed anode current collector, this produced maximum power densities of 1186–5864 W m? 2 at 450–570 °C. High magnification imaging analysis revealed large three-phase boundary regions within the anode, a dense electrolyte layer and clearly highlighted the multiple CGO–LSCF cermet and pure LSCF cathode layers. The performance of the HF-SOFC with a twenty millimetre active length showed no degradation after four thermal cycles between 300 °C and 570 °C. 相似文献
23.
24.
J. Hafiz R. Mukherjee X. Wang M. Cullinan J.V.R. Heberlein P.H. McMurry S.L. Girshick 《Journal of nanoparticle research》2006,8(6):995-1002
The synthesis of silicon nanowires that are densely coated with silicon nanoparticles is reported. These structures were produced in a two-step process, using a method known as hypersonic plasma particle deposition. In the first step, a Ti–Si nanoparticle film was deposited. In the second step the Ti-source was switched off, and nanoparticle-coated nanowires grew under the simultaneous action of Si vapor deposition and bombardment by Si nanoparticles. Total process time, including both steps, equaled 5 min, and resulted in formation of a dense network of randomly oriented nanowires covering1.5 cm2 of substrate area. The nanowires are composed of single-crystal Si. The diameters of the nanowires vary over the range
100–800 nm. Each nanowire has a crystalline TiSi2 catalyst particle, believed to have been solid during nanowire growth, at its tip. 相似文献
25.
Ahmed Ahmed El‐Barbary Yehia Ahmed Hafiz Mohamed Shaker Abdel‐Wahed 《Journal of heterocyclic chemistry》2011,48(3):639-644
Thiation of 1 by LR gave the corresponding 3,5‐dithioxo derivative 2 and the trimer 3 . Methylation of 1 afforded the S‐methyl derivative 4 . Compound 1 was fused with 6‐bromo‐2‐phenyl‐benzo[1,3‐d]oxazin‐4‐one ( 5 ) and gave 6 . Condensation of 1 with some acid derivatives 7a , 7b , 7c , 7d and/or 8a , 8b , 8c yielded thiadiazolo‐triazine derivatives 9a , 9b , 9c , 9d and 10a , 10b , 10c . Compounds 9a , 9c and 10c were hydrolyzed to furnish 11a , 11b , 11c Acetylation of 14 afforded mono‐ and diacetyl‐derivatives 15 and 16 . Benzoylation of 14 afforded mono‐ and dibezoyl‐derivatives 17 and 18 . 14 with some aromatic aldehydes yielded 9a , 9b , 9c . Reacting 14 with phenyl (iso‐ and/or isothio‐) cyanate gave the urea derivatives 20a , 20b . Thiation of 14 with P4S10 furnished 21 . The newly synthesized compounds were tested as antimicrobial agents. J. Heterocyclic Chem., (2011) 相似文献
26.
We discuss the notion of spin squeezing considering two mutually exclusive classes of spin-s states, namely, oriented and non-oriented states. Our analysis shows that the oriented states are not squeezed while non-oriented
states exhibit squeezing. We also present a new scheme for construction of spin-s states using 2s spinors oriented along different axes. Taking the case of s=1, we show that the ‘non-oriented’ nature and hence squeezing arise from the intrinsic quantum correlations that exist among
the spinors in the coupled state. 相似文献
27.
Jawali C. Umavathi Hafiz Muhammad Ali Sapnali Limbaraj Patil 《Mathematical Methods in the Applied Sciences》2020,43(15):9223-9244
The motivation of the current article is to explore a numerical investigation on steady triply diffusive convection in a vertical channel. Heat is exchanged from the external fluid with the plates. The reference temperature is taken as equal and also as different for the external fluid. Solutions in the absence of viscous dissipation and buoyancy forces are also obtained as special cases. General solutions including the effects of viscous dissipation and buoyancy forces are obtained analytically using the method of perturbation. The analytical solutions can be used only if the Brinkman number is small. Hence to know the flow properties for all values of Brinkman number, we resort to numerical solutions. The effects of thermal Grashof number, solutal Grashof number, and the chemical reaction parameter on the flow field are evaluated numerically. The obtained results are validated against previously published results for special case of the problems. 相似文献
28.
Fatima Ijaz Syed Salman Shafqat Hafiz Adnan Ahamd Munawar Ali Munawar Misbahul Ain Khan 《Journal of heterocyclic chemistry》2019,56(4):1231-1238
Derivatives of ninhydrin are extensively used in the field of forensic sciences as important latent fingerprint reagents. Many works have been performed upon their synthesis and reactivity, but there are many spaces to work on the compounds of quinoline‐2,3,4(1H)‐triones—analogues of ninhydrin, in both dimensions: synthesis and reactivity, and according to the best of our knowledge, not a single detailed or short compiled article has been published for these compounds. This review briefly summarizes the chemistry of quinoline‐2,3,4(1H)‐triones. 相似文献
29.
The fabrication of nanoparticles has been perused as a topic of critical importance in the present decades. Biosynthesis of nanoparticles employs plants extract instead of harmful chemicals. These plant extracts act as reducing and capping agents which is the most appropriate and eco-friendly method among all the preparative routs. In present study, the magnetite nanoparticles (Fe3O4-NPs) were fabricated using rapid, single step and benign biosynthetic rout by reduction of ferric nitrate nonahydrate solution with Ferocactus echidne aqueous extract containing ascorbic acid as a main reducing and capping agent. The structural and morphological properties of prepared iron oxide nanoparticles were investigated by Powder X-ray diffraction and scanning electron microscopy. The size of the synthesized nanoparticles was approximately 15 ± 2 nm as determined by Scherrer equation. The biosynthetically fabricated nanoparticles were employed as catalyst for pyrolysis of nutshells to produce biofuel. Catalytic pyrolysis of biomass yields biofuel as an alternative source of energy and chemical feed stock. Effect of temperature, heating rate, and amount of catalyst were investigated on conversion percentage and product yields. Aniline point, carbon residue, and cetane number of prepared bio-oil were also determined. 相似文献
30.
Hafiz Ejaz Ahmed Yasir Iqbal Muhammad Hammad Aziz Muhammad Atif Zahida Batool Atif Hanif Nafeesah Yaqub W. A. Farooq Shafiq Ahmad Amanullah Fatehmulla Hijaz Ahmad 《Molecules (Basel, Switzerland)》2021,26(15)
Metal oxide nanoparticles synthesized by the biological method represent the most recent research in nanotechnology. This study reports the rapid and ecofriendly approach for the synthesis of CeO2 nanoparticles mediated using the Abelmoschus esculentus extract. The medicinal plant extract acts as both a reducing and stabilizing agent. The characterization of CeO2 NPs was performed by scanning electron microscopy (SEM), X-ray diffraction (XRD), ultraviolet-visible spectroscopy (UV-Vis), and Fourier transform infrared spectroscopy (FTIR). The in vitro cytotoxicity of green synthesized CeO2 was assessed against cervical cancerous cells (HeLa). The exposure of CeO2 to HeLa cells at 10–125 µg/mL caused a loss in cellular viability against cervical cancerous cells in a dose-dependent manner. The antibacterial activity of the CeO2 was assessed against S. aureus and K. pneumonia. A significant improvement in wound-healing progression was observed when cerium oxide nanoparticles were incorporated into the chitosan hydrogel membrane as a wound dressing. 相似文献