Characteristics of the preplasma formation using an uncompressed picosecond-long laser pulse with a large spot size on Al and mylar targets

A preplasma plays a very important role in laser-driven proton acceleration, where it can increase the proton energy significantly. In this research, we generated a nearly planar preplasma intentionally by sending an uncompressed picosecond-long Ti:sapphire laser pulse with a large spot size onto a thin foil target (Al and mylar) and investigated the characteristics of the preplasma by using a space-time-resolved Nomarski interferometer. In this paper, a simple analytical approach employing the one-dimensional collisional plasma concept was also developed and its result is compared with the experimental results. This work reveals the detailed characteristics of the behavior of the planar preplasma, which is very important in laser-driven proton acceleration, X-ray laser, etc., employing laser-solid interactions.     

Effect of pre-treatment on the surface and electrochemical properties of screen-printed carbon paste electrodes

The effect of various electrochemical pre-treatment methods on the surface and electrochemical properties of screen-printed carbon paste electrodes (SPCE) prepared with three different commercial products was examined. It was observed that a positively charged redox couple, e.g., hexaammineruthenium(III), exhibited quasi-reversible behavior at the untreated SPCE. However, the cyclic voltammograms (CVs) of the SPCE prepared with general-purpose carbon inks did not exhibit clear redox peaks to other representative redox couples [e.g., hexacyanoferrate(III), hexachloroiridate(IV), dopamine, and hydroquinone] without activation. Electrochemical pre-treatment methods were sought in four different aqueous solutions, i.e., sulfuric acid, potassium chloride, sodium hydrogencarbonate, and sodium carbonate, applying various activation potentials. It was found that the pre-treatment procedure in saturated Na2CO3 solution at 1.2 V provides a mild and effective condition for activating the SPCE. By measuring the water contact angles at the SPCE surfaces and recording their SEM images, it was confirmed that the electrochemical pre-treatment effectively removes the organic binders from the surface carbon particles. A prolonged period of activation (> 5 min) or the use of high potentials (> 1.2 V) increased the capacitance of the electrode over 20 microF cm(-2). The pre-treated SPCE behaved like a random array microelectrode, exhibiting a sigmoidal-shaped CV at a slow scan rate. The short pre-anodization method in Na2CO3 solution was generally applicable to most SPCE prepared with general-purpose carbon inks.     

Response to comment on “Magnetic and chemical characterization of black pottery from Hanseong Baekje archaeological site,South Korea”

Journal of Radioanalytical and Nuclear Chemistry -