Energy and Acid-Base Characteristics of the Surface of Nitramine Fillers for Polymeric Composites

Single crystals of nitramine fillers for special-purpose polymeric composites are characterized by the surface energy and its constituents and also by the acidity of their surface.     

Thiol–norbornene materials: Approaches to develop high Tg thiol–ene polymers

The ability to prepare high T_g low shrinkage thiol–ene materials is attractive for applications such as coatings and dental restoratives. However, thiol and nonacrylated vinyl materials typically consist of a flexible backbone, limiting the utility of these polymers. Hence, it is of importance to synthesize and investigate thiol and vinyl materials of varying backbone chemistry and stiffness. Here, we investigate the effect of backbone chemistry and functionality of norbornene resins on polymerization kinetics and glass transition temperature (T_g) for several thiol–norbornene materials. Results indicate that T_gs as high as 94 °C are achievable in thiol–norbornene resins of appropriately controlled chemistry. Furthermore, both the backbone chemistry and the norbornene moiety are important factors in the development of high T_g materials. In particular, as much as a 70 °C increase in T_g was observed in a norbornene–thiol specimen when compared with a sample prepared using allyl ether monomer of analogous backbone chemistry. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 5686–5696, 2007     

Triple differential cross sections for ionization of hydrogen atoms by positrons in a Schwinger variational calculation

Schwinger variational principle has been used to calculate triple differential cross-sections for ionization of hydrogen atoms by positrons at intermediate and high energies for Ehrhardt type asymmetric geometry. The results agree in general with the calculations of Brauneret al [8] and with the second Born calculation.     

Fluid-fluid phase separation in colloid-polymer mixtures studied with small angle light scattering and light microscopy

Mixtures of colloidal silica spheres and polydimethylsiloxane in cyclohexane with a colloid-polymer size ratio of about one were found to phase separate into two fluid phases, one which is colloid-rich and one which is colloid-poor. In this work the phase separation kinetics of this fluid-fluid phase separation is studied for different compositions of the colloid-polymer mixtures, and at several degrees of supersaturation, with small angle light scattering and with light microscopy. The small angle light scattering curve exhibits a peak that grows in intensity and that shifts to smaller wave vector with time. The characteristic length scale that is obtained from the scattering peak is of the order of a few μm, in agreement with observations by light microscopy. The domain size increases with time as , which might be an indication of coarsening by diffusion and coalescence, like in the case of binary liquid mixtures and polymer blends. For sufficiently low degrees of supersaturation the angular scattering intensity curves satisfy dynamical scaling behavior.     

Compact Lie groups and factor spaces with respect to tori

Translated from Matematicheskie Zametki, Vol. 54, No. 7, pp. 124–135, July, 1993.     

Extension of multigrid methodology to supersonic/hypersonic 3-D viscous flows

A multigrid acceleration technique developed for solving the three-dimensional Navier–Stokes equations for subsonic/transonic flows has been extended to supersonic/hypersonic flows. An explicit multistage Runge–Kutta type of time-stepping scheme is used as the basic algorithm in conjunction with the multigrid scheme. Solutions have been obtained for a blunt conical frustum at Mach 6 to demonstrate the applicability of the multigrid scheme to high-speed flows. Computations have also been performed for a generic High-Speed Civil Transport configuration designed to cruise at Mach 3. These solutions demonstrate both the efficiency and accuracy of the present scheme for computing high-speed viscous flows over configurations of practical interest.     

TheA 1-and the ϕ-meson in QCD

Recently we used a method of stable analytic extrapolation to test whether strictly local duality between the asymptotic and the resonance region, which is believed to be valid in QCD, appears already at the present stage of QCD calculations. Probing the QCD ?-amplitude, we found a prominent bump structure in the resonance region, i.e. a rather direct evidence for the validity of local duality. In the present paper we confirm and extend this result by giving two further applications, theA ₁-meson and the ?-meson. While we do not meet theA ₁, as was to be expected since other sum rules can not separate it from the continuum, too, the extrapolation of the ?-amplitude leads to an enormous bump. Comparing this ?-bump with our ?-bump, we recover at least qualitatively the real proportions.     

Oxidative dehydrogenation of alkylheteroaromatic compounds 1. Catalysts containing vanadium and molybdenum for the oxidative dehydrogenation of alkylpyridines

The dehydrogenation of a series of alkylpyrïdines has been studied on vanadium and molybdenum oxide-containing catalysts in the presence of oxygen of the air and sulfur dioxide gas. A dependence was shown of the catalytic and physicochemical properties of the catalysts indicated on their composition and method of preparation. The optimum catalyst composition and the conditions of carrying out the reaction to provide high activity and selectivity when making vinylpyridines were determined. The relative reactivity of the alkylpyridines investigated on dehydrogenation and further oxidation was determined.N. D. Zelinskii Institute of Organic Chemistry, Russian Academy of Sciences, Moscow 117913. Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 6, pp. 802–811, June, 1994. Original article submitted April 19, 1994.