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101.
Could simple intraannular-arm macrocyclic systems exist in enantiopure stable forms? The effective synthesis of two representative compounds of such a class, their resolution into enantiomers, and experiments justifying their stability toward racemization are presented. 相似文献
102.
A T Brint 《The Journal of the Operational Research Society》2003,54(11):1177-1188
The annual turnover of online auctions is already in tens of billions of dollars and this amount is predicted to grow substantially over the next few years. Hence, it is important to know how buyers and sellers can influence their chances of success. Therefore, data were collected from eBay auctions for three different categories of collectible items, namely those with a published guide price, those with a rough guide price and those having no easily obtainable guide price. The options available to buyers and sellers of items were then analysed. It was found that it was hard for the seller to influence an item's achieved price significantly, apart from items with no guide price where the starting price could have an effect. Most bidders bid close to the current value and so there were insufficient data to determine the consequences of timing on the placing of high bids. For low bids, delaying a bid was found to improve significantly the chances of winning for one of the data sets. 相似文献
103.
Chin-Tsang Chiang Mei-Cheng Wang 《Annals of the Institute of Statistical Mathematics》2004,56(1):87-100
This paper proposes kernel estimation of the occurrence rate function for recurrent event data with informative censoring.
An informative censoring model is considered with assumptions made on the joint distribution of the recurrent event process
and the censoring time without modeling the censoring distribution. Under the validity of the informative censoring model,
we also show that an estimator based on the assumption of independent censoring becomes inappropriate and is generally asymptotically
biased. To investigate the asymptotic properties of the proposed estimator, the explicit form of its asymptotic mean squared
risk and the asymptotic normality are derived. Meanwhile, the empirical consistent smoothing estimator for the variance function
of the estimator is suggested. The performance of the estimators are also studied through Monte Carlo simulations. An epidemiological
example of intravenous drug user data is used to show the influence of informative censoring in the estimation of the occurrence
rate functions for inpatient cares over time. 相似文献
104.
András Vasy 《Journal of Functional Analysis》2004,209(2):468-492
We show the exponential decay of eigenfunctions of second-order geometric many-body type Hamiltonians at non-threshold energies. Moreover, in the case of first-order and small second-order perturbations we show that there are no eigenfunctions with positive energy. 相似文献
105.
In order to reduce infant mortality in the municipality of Rio de Janeiro it is desired to encourage all mothers-to-be to attend the appropriate health care facilities. A 3-level hierarchical prenatal–neonatal health care system is described together with a basic model for optimising accessibility to facilities. A genetic algorithm to solve the basic model is developed and some numerical experience reported. Extensions to the basic model and planned future research are briefly indicated. 相似文献
106.
Florin Ambro 《manuscripta mathematica》2003,111(1):43-49
We prove a precise inversion of adjunction formula for the log variety (ℂ
d
+1,X), where X is a non-degenerate hypersurface. As a corollary, the minimal log discrepancies of non-degenerate normal hypersurface singularities
are bounded by dimension.
Received: 17 September 2002 / Revised version: 22 November 2002
Published online: 14 February 2003
Current address: DPMMS, CMS, University of Cambridge, Wilberforce Road, Cambridge CB3 0WB, England. e-mail: f.ambro@dpmms.cam.ac.uk
Mathematics Subject Classification (2000): Primary 14B05; Secondary 14M25, 52B20 相似文献
107.
In this paper, we use weighted modules ω(?)(f,t)w to study the pointwise approximation on Szasz-type operators, and obtain the direct and converse theorem, as well as characterizations of the pointwise approximation of Jacobi-weighted Szasz-type operators. 相似文献
108.
Hana Macková Daniela Králová Daniel Horák 《Journal of polymer science. Part A, Polymer chemistry》2007,45(24):5884-5898
The aim of this study was to develop novel thermally responsive polymer microspheres with magnetic properties. Dispersion and inverse emulsion copolymerization of N‐isopropylacrylamide (NIPAAm) and N,N′‐methylenebisacrylamide (MBAAm) was investigated in the presence of γ‐Fe2O3 nanoparticles. The resulting microspheres were characterized in terms of morphology, size, polydispersity, iron content, and temperature‐dependent swelling using optical microscopy, transmission electron microscopy, scanning electron microscopy, QELS, and AAS. The effects of several variables, such as the concentration of γ‐Fe2O3, MBAAm crosslinking agent, Span 80 surfactant, 2,2′‐azobis(2‐methyloctanenitrile) (AMON) initiator, and polymerization temperature on the properties of the microspheres were studied. Swelling and thermoresponsive behavior of the microspheres containing γ‐Fe2O3 nanoparticles were also investigated. The microspheres contained about 8 wt % of iron. The presence of magnetic nanoparticles and their concentration changes did not have any significant effect on the temperature sensitivity of the composites. The particles gradually shrink into an increasingly collapsed state when the temperature is raised to 40 °C since the increase in temperature weakens the hydration and PNIPAAm chains gradually become more hydrophobic, which leads to the collapse of the particles. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 5884–5898, 2007 相似文献
109.
Christiane Albrecht 《Analytical and bioanalytical chemistry》2008,390(5):1223-1224
110.