全文获取类型
收费全文 | 352篇 |
免费 | 40篇 |
国内免费 | 37篇 |
专业分类
化学 | 279篇 |
晶体学 | 1篇 |
力学 | 6篇 |
综合类 | 12篇 |
数学 | 19篇 |
物理学 | 112篇 |
出版年
2023年 | 4篇 |
2022年 | 3篇 |
2021年 | 3篇 |
2020年 | 8篇 |
2019年 | 7篇 |
2018年 | 6篇 |
2017年 | 14篇 |
2016年 | 7篇 |
2015年 | 11篇 |
2014年 | 20篇 |
2013年 | 21篇 |
2012年 | 19篇 |
2011年 | 27篇 |
2010年 | 15篇 |
2009年 | 14篇 |
2008年 | 19篇 |
2007年 | 21篇 |
2006年 | 13篇 |
2005年 | 11篇 |
2004年 | 16篇 |
2003年 | 3篇 |
2002年 | 15篇 |
2001年 | 12篇 |
2000年 | 15篇 |
1999年 | 6篇 |
1997年 | 4篇 |
1996年 | 8篇 |
1995年 | 7篇 |
1994年 | 6篇 |
1993年 | 8篇 |
1991年 | 10篇 |
1990年 | 7篇 |
1988年 | 3篇 |
1987年 | 3篇 |
1986年 | 4篇 |
1984年 | 5篇 |
1983年 | 2篇 |
1982年 | 3篇 |
1980年 | 7篇 |
1979年 | 2篇 |
1978年 | 2篇 |
1977年 | 4篇 |
1975年 | 2篇 |
1974年 | 4篇 |
1973年 | 4篇 |
1970年 | 3篇 |
1969年 | 3篇 |
1967年 | 2篇 |
1963年 | 2篇 |
1880年 | 2篇 |
排序方式: 共有429条查询结果,搜索用时 15 毫秒
1.
基于MATLAB的异步电动机线性化控制系统的仿真 总被引:1,自引:0,他引:1
从异步电动机在同步旋转坐标系下的状态方程出发,在一定的条件下,对其系数矩阵简化.推出异步电动机的线性化控制模型.并基于该模型得出异步电动机的线性化控制系统.以给定电机为例,对该模型的有效性、响应用MATLAB进行仿真分析.验证的结果说明上述模型具有实用价值. 相似文献
2.
CHEN Zhi-hong XU Li BA Xue-qing ZENG Xian-lu 《高等学校化学研究》2006,22(3):302-307
Introduction Migrationandrecruitmentofleukocytesfromblood toinflammatorylesionsitesaresequentiallyregulated byadhesionmoleculesandtheirreceptors[1].These lectinfamilyplaysamajorroleininitiatingattachement ofneutrophilstotheactivatedendothelium.P selectin,… 相似文献
3.
Tracy Huziak‐Clark Stephen J. Van Hook Julie Nurnberger‐Haag Lena Ballone‐Duran 《School science and mathematics》2007,107(8):311-324
This article focuses on the impact a collaborative project between university graduate fellows and K‐12 classroom teachers had on improved pedagogy in the classroom and in the future at the university. Nine teams participated in a yearlong professional development project to improve pedagogy and communication skills of the participants. This study shows that the participants, the fellows and the K‐12 teacher partners, made changes in planning, implementation, and even motivation for using inquiry‐based methods in their classroom. External observations of the teams further support the individuals' claims of improved pedagogy using inquiry and impact on student conceptual understanding. The Horizon Classroom Observation instrument was used for these observations. The teams showed an overall increase in scores, as well as overall effective and exemplarily implementation of their planning. The program design, the implementation, and the results of this three‐year study will be elaborated in this article. 相似文献
4.
5.
Held GA Solina DH Solina H Keane DT Haag WJ Horn PM Grinstein G 《Physical review letters》1990,65(9):1120-1123
6.
7.
8.
Siegers C Biesalski M Haag R 《Chemistry (Weinheim an der Bergstrasse, Germany)》2004,10(11):2831-2838
Highly protein-resistant, self-assembled monolayers (SAMs) of dendritic polyglycerols (PGs) on gold can easily be obtained by simple chemical modification of these readily available polymers with a surface-active disulfide linker group. Several disulfide-functionalized PGs were synthesized by N,N'-dicyclohexylcarbodiimide-mediated ester coupling of thioctic acid. Monolayers of the disulfide-functionalized PG derivatives spontaneously form on a semitransparent gold surface and effectively prevent the adsorption of proteins, as demonstrated by surface plasmon resonance (SPR) kinetic measurements. A structure-activity relationship relating the polymer architecture to its ability to effectuate protein resistance has been derived from results of different surface characterization techniques (SPR, attenuated total reflectance infrared (ATR-IR), and contact-angle measurements). Dendritic PGs combine the characteristic structural features of several highly protein-resistant surfaces: a highly flexible aliphatic polyether, hydrophilic surface groups, and a highly branched architecture. PG monolayers are as protein resistant as poly(ethylene glycol) (PEG) SAMs and are significantly better than dextran-coated surfaces, which are currently used as the background for SPR spectroscopy. Due to the higher thermal and oxidative stability of the bulk PG as compared to the PEG and the easy accessibility of these materials, dendritic polyglycerols are novel and promising candidates as surface coatings for biomedical applications. 相似文献
9.
A reinvestigation of 2-methylacetophenone ( 1 ) by ns flash photolysis has provided detailed evidence for the reaction sequence of photoenolization. The triplet reaction proceeds adiabatically from the lowest excited triplet state of the ketone, 3 K (1) , to the enol excited triplet state, 3 E (1) , which decays both to enol and ketone ground state. The Z- and E-isomers of the photoenol, Z- E (1) and E- E (1) are formed in about equal yield by the triplet pathway, while direct enolization from the lowest excited singlet state of 1 yields (predominantly) the Z-isomer. Intramolecular reketonization from Z- E (1) to 1 proceeds at a rate of ca. 108s?1 in cyclohexane, but can be retarded to ca. 104s?1 in hydrogen-bond-acceptor solvents. The proposed mechanism is summarized in Scheme 1 and rationalized on the basis of a state correlation diagram, Scheme 2. 3,3,6,8-Tetramethyl-1-tetralone ( 2 ) was used as a reference compound with fixed conformational position of the carbonyl group, and some results from a brief investigation of 2,4-dimethylbenzophenone ( 3 ) are also reported. 相似文献
10.
Gianini M Forster A Haag P von Zelewsky A Stoeckli-Evans H 《Inorganic chemistry》1996,35(17):4889-4895
cis-Bis-homoleptic platinum(II) complexes, with predetermined helical chirality at the metal center, can be obtained by using strongly sterically interacting ligands. With this aim, two new ligands, (8R,10R)-2-(2'-thienyl)-4,5-pinenopyridine, th4,5ppy (2), and (8R,10R)-2-(2'-thienyl)-5,6-pinenopyridine, th5,6ppy (4), were synthesized and coordinated to platinum. The structures of the resulting complexes, Pt(th4,5ppy)(2) (5) and Pt(th5,6ppy)(2) (6), were determined by X-ray diffraction, and it was found that they both crystallize with a Delta-cis configuration. Thermal oxidative additions (TOA) of alkyl halides were performed with both complexes leading, in the case of 5, to a mixture of isomers and, in the case of 6, to isomerically pure products. The predetermination of chirality at the metal center is therefore preserved in the octahedral (OC-6) platinum(IV) complexes. Crystals of Pt(th4,5ppy)(2) (5) are orthorhombic, of space group P2(1)2(1)2(1), with a = 12.973(1) ?, b = 13.619(2) ?, c = 17.665(2) ?, alpha = beta = gamma = 90 degrees, and Z = 4. Final R = 0.0268 and R(w) = 0.0424 for 3101 observed reflections. Crystals of Pt(th5,6ppy)(2) (6) are hexagonal, of space group P6(1), with a = 11.5465(4) ?, b = 11.5465(4) ?, c = 35.356(3) ?, alpha = beta = 90 degrees, gamma = 120 degrees, and Z = 6. Final R = 0.0424 and R(w) = 0.0845 for 2660 observed reflections. Neither molecule possesses a crystallographic C(2) symmetry. 相似文献