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191.
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Meinke MC Haag SF Schanzer S Groth N Gersonde I Lademann J 《Photochemistry and photobiology》2011,87(2):452-456
One essential reason for skin ageing is the formation of free radicals by excessive or unprotected sun exposure. Recently, free radical generation in skin has been shown to appear not only after irradiation in the UV wavelength range but also in the infrared (IR) spectral range. Sunscreens are known to protect against radicals generated by UV radiation; however, no data exist for those generated by IR radiation. This paper has investigated four different, commercially available sunscreens and one COLIPA standard with regard to radical formation in the skin after IR irradiation, using electron paramagnetic resonance spectroscopy. The use of sunscreens has led to reduced amounts of radicals compared to untreated skin. Furthermore, absorption and scattering properties and the radical protection factor of the formulations were determined to investigate their influence on the radical protection of the skin. None of these formulations contained an optical absorber in the IR range. The protection efficiency of the sunscreens was shown as being induced by the high scattering properties of the sunscreens, as well as the antioxidants contained in the formulations. 相似文献
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The synthesis and aggregation behavior of photo-switchable, nonionic dendritic amphiphiles was investigated with regard to transport and release of guest molecules. The correlation between the critical micelle concentration and the switching ability is shown. 相似文献
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Introducing Chirality into Nonionic Dendritic Amphiphiles and Studying Their Supramolecular Assembly
Dr. Sumit Kumar Dr. Kai Ludwig Dr. Boris Schade Dr. Hans von Berlepsch Dr. Ilona Papp Dr. Rahul Tyagi Monika Gulia Prof. Dr. Rainer Haag Priv.‐Doz. Dr. Christoph Böttcher 《Chemistry (Weinheim an der Bergstrasse, Germany)》2016,22(16):5629-5636
Chiral head groups have been introduced into water‐soluble hydroxyl‐terminated nonionic amphiphiles and the impact of the head group stereochemistry on the supramolecular ultrastructures has been studied. Enantiomeric isomers were compared with the achiral meso form and the racemic mixture by means of cryogenic transmission electron microscopy and circular dichroism spectroscopy. Structurally, all amphiphiles are composed of the first‐generation hydrophilic polyglycerol head group coupled to a single hydrophobic hexadecyl chain through an amide linkage and diaromatic spacer. The enantiomers aggregate to form twisted ribbons with uniform handedness, whereas the meso stereoisomer and racemic mixture produce elongated assemblies, namely, tubules and platelets, but without a chiral ultrastructure. Simulations on the molecular packing geometries of the stereoisomers indicate different preferential assembly routes that explain the individual supramolecular aggregation behavior. 相似文献
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Rudolf Haag 《Foundations of Physics》2013,43(11):1295-1313
The concept of event provides the essential bridge from the realm of virtuality of the quantum state to real phenomena in space and time. We ask how much we can gather from existing theory about the localization of an event and point out that decoherence and coarse graining—though important—do not suffice for a consistent interpretation without the additional principle of random realization. 相似文献
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A simple general synthetic concept to build dendritic core-shell architectures with pH-labile linkers based on hyperbranched PEI cores and biocompatible PEG shells is presented. Using these dendritic core-shell architectures as nanocarriers, the encapsulation and transport of polar dyes of different sizes is studied. The results show that the acid-labile nanocarriers exhibit much higher transport capacities for dyes than unfunctionalized hyperbranched PEI. The cleavage of imine bonds and controlled release of the polar dyes revealed that weak acidic condition (pH approximately 5.0) could cleave the imine bonds linker and release the dyes up to five times faster than neutral conditions (pH = 7.4). 相似文献