停流—荧光动力学分析法测定痕量钛的研究

利用自行组装的停流-荧光动力学分析仪,采用停流法汇合流体动力注入技术,研究了钛与3.5-二溴水杨基荧光酮的荧光增强动力学反应性质,讨论了流速、进样时间对方法灵敏度和精密度的影响,提出了一个快速、简便、精确测定钛的分析方法,并用于稀土样品及合成样品中痕量钛的测定.方法检测限为8×10~(-3)ppm,大多数元素的干扰均可用动力学方法消除.     

脱镁叶绿素a和脱镁叶绿素b的联合同步荧光分析法

建立了脱镁叶绿素a和脱镁叶绿素b的联合同步荧光分析法。方法简便快速。脱镁叶绿素a和脱镁叶绿素b的线性范围分别为0～400ng/ml和0～200ng/ml,检出限分别为1ng/ml和0.5ng/ml。     

排球比赛中的二传最优过程

为了研究排球比赛中的二传最优过程 ,本文基于决策论的理论和方法建立了排球二传最优过程的数学模型 .通过对模型的分析研究分别给出了最大概率准则和最大期望准则下的最优传球方式 .本文所得到的结果对排球队的训练和比赛有一定的指导意义 .     

Expert systems for HPLC in biochemistry—The knowledge base for selection of HPLC column system in the separation of amino acids,peptides and proteins

The strategy of expert system for high performance liquid chromatography was discussed, the attentions are mainly placed on the knowledge base for selection of column system, separation modes and detection modes in the analysis of amino acids, peptides and proteins.     

All solid-state sum-frequency generation of 1.12-W continuous-wave laser at 588 nm

A new resonator design for doubly resonant continuous-wave (CW) intracavity sum-frequency mixing (SFM) is reported. 1.12 W of coherent radiation at 588 nm is generated by mixing 1062-nm Nd:GdVO4laser and 1319-nm Nd:YAG laser. The optical-to-optical conversion efficiency is up to 3.7%.     

反向驱动的异质结有机薄膜电致发光

成功制备了结构为ITO／PDDOPV／PPQ／Al的异质结聚合物发光二极管。该器件在正反向偏压下均可发光。在正向偏压下的光发射主要来自PDDOPV，但在反向偏压下的光发射则包括来自PPQ的蓝光发射和PDDOPV的黄光发射。蓝光强度与黄光强度的比值随着反向偏压的增加而增加，当反向直流电压分别为22V、24V、26V、28V时，其电致发光光谱中PPQ与PDDOPV的峰高比IPPQ／IPDDOPV分别为1．092、1．329、1．605、2．046。换句话说，该器件的发光颜色是压控可调的，这对实现彩色显示是极为有利的。分析了在反向偏压下的发光机理以及IPPQ／IPDDOPV受电压控制的原因。     

有效点、弱有效点和真有效点的锥刻画

利用集合在某点的相依切锥、法向锥和可行方向锥等研究向量优化问题的有效点、 弱有效点和真有效点的特征,对局部有效点、局部弱有效点和局部真有效点与集合的各 锥之间的关系作了刻画.     

有限混合Gamma分布的拓扑稠密性证明

首先给出了有限混合Erlang分布在正实数轴上所有概率分布中稠密的理论证明,进而给出了混合Gamma分布具有稠密性的结论,说明有限混合Gamma分布具有广泛的适用性,可以用来刻画正实数轴上的任意随机变量.     

Characterization of ceramic PVD thin films on AZ31 magnesium alloys

Ceramic thin films have been widely used to protect the metal substrate as coatings in the past years. In order to improve the poor corrosion resistance of AZ31 magnesium alloy, the study in this paper used the electron beam evaporation method to prepare ceramic PVD films on its surface with TiO₂ and Al₂O₃ as donors, respectively. Atomic force microscopy (AFM), scanning electron microscope (SEM), energy dispersive X-ray spectrometer (EDS), Auger electron spectroscopy (AES) and X-ray diffraction (XRD) were used to investigate the surface morphology, composition and microstructure of the thin films. Both films deposited on AZ31 took on compact top surface morphologies and grew as amorphous structures on substrate. AES test not only showed that films compositions deviated the standard stoichiometric ratios, but also found that element Mg diffused into films and existed as magnesium oxide in the TiO_x film as well as the AlO_x film. In the electrochemical corrosion test, the AlO_x coating on AZ31 exhibited the largest electrochemical impedance in a 3.5% NaCl solution. But it did not show better corrosion resistance than others for the poorer adhesion. Even if its thickness was small, the TiO_x coating on AZ31 exhibited the best corrosion resistance in this study. According to the observation and analysis, the damage of these films on AZ31 in aggressive solutions was mainly due to the existence of pores, microcracks, vacancies and poor adhesion between coating and substrate.     

LD端抽运平直腔Nd:YVO4固态激光器的输出功率特性研究

对LD端抽运平直腔Nd:YVO₄固态激光器输出功率特性受激光器内在诸因素(热透镜效应、腔长、激活孔径等)的制约关系进行了研究.并用传播圆-变换圆图解分析方法给出了合理的解释，同时，对进一步提高其输出功率特性指出了方向. 关键词： 固体激光器 热透镜 变换圆 平直腔