全文获取类型
收费全文 | 39770篇 |
免费 | 6710篇 |
国内免费 | 8916篇 |
专业分类
化学 | 30360篇 |
晶体学 | 961篇 |
力学 | 2343篇 |
综合类 | 943篇 |
数学 | 4816篇 |
物理学 | 15973篇 |
出版年
2024年 | 129篇 |
2023年 | 606篇 |
2022年 | 1387篇 |
2021年 | 1448篇 |
2020年 | 1496篇 |
2019年 | 1527篇 |
2018年 | 1330篇 |
2017年 | 1593篇 |
2016年 | 1695篇 |
2015年 | 1920篇 |
2014年 | 2425篇 |
2013年 | 3075篇 |
2012年 | 3486篇 |
2011年 | 3563篇 |
2010年 | 2957篇 |
2009年 | 2961篇 |
2008年 | 3277篇 |
2007年 | 2997篇 |
2006年 | 2783篇 |
2005年 | 2373篇 |
2004年 | 1852篇 |
2003年 | 1376篇 |
2002年 | 1363篇 |
2001年 | 1192篇 |
2000年 | 1240篇 |
1999年 | 943篇 |
1998年 | 573篇 |
1997年 | 483篇 |
1996年 | 426篇 |
1995年 | 399篇 |
1994年 | 374篇 |
1993年 | 325篇 |
1992年 | 277篇 |
1991年 | 227篇 |
1990年 | 216篇 |
1989年 | 214篇 |
1988年 | 169篇 |
1987年 | 132篇 |
1986年 | 115篇 |
1985年 | 89篇 |
1984年 | 70篇 |
1983年 | 53篇 |
1982年 | 54篇 |
1981年 | 38篇 |
1980年 | 33篇 |
1979年 | 25篇 |
1978年 | 9篇 |
1971年 | 9篇 |
1965年 | 20篇 |
1964年 | 10篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
111.
Yan Zhao Xingbin Yang Ru Jiang Xiaoli Sun Wenmin Liu Shengyong Zhang 《Analytical sciences》2006,22(5):747-751
The investigation on capillary electrophoretic enantioseparation of six synthetic compounds containing vicinal diol groups has been undertaken to acquire the optimum conditions using native beta-cyclodextrin (beta-CD) as chiral selector and borate as a background electrolyte. The separation was carried out in an uncoated capillary (58.5 cm x 75 microm i.d., effective length 48.5 cm) and the effects of several important factors were investigated in detail. The results showed that beta-CD as a chiral selector exhibited good enantioselectivity and that the enantioseparation was greatly influenced by the structure of the diols, the borate concentration and the buffer pH. The optimum performance was obtained for the chiral vicinal diols under the conditions of 200 mM borate buffer of pH 9.8 containing 1.7% beta-CD at an applied voltage of 15 kV and a capillary temperature of 20 degrees C. Under the conditions, four diols were baseline separated with fast analysis time and the good theoretical plate numbers (above 10 x 10(4)) and favorable migration-time reproducibilities (RSDs below 3.0%) were obtained. The separation results were satisfactory. 相似文献
112.
A simple and sensitive method was conducted for the determination of trace amounts of proteins with benzeneazo-8-acetylamino-1-naphthol-3,6-disulfonic acid sodium salt (azophloxine, AP) using a Rayleigh light-scattering (RLS) technique. At pH 2.60 and in the presence of an emulsifier OP microemulsion, the RLS of AP can be greatly enhanced by proteins, owing to the interaction between AP and protein. The enhanced intensity is proportional to the concentration of proteins. Four proteins, including bovine serum albumin (BSA), human serum albumin (HSA), lysozyme (Lys) and gamma globulin (gamma-G) have been tested. For example, the linear range of BSA was 0 - 0.06 microg mL(-1) with detection limits of 2.38 ng mL(-1). The method was applied to the analysis of protein in human urine and penicillin samples with satisfactory results. The relative standard deviation was in all instances less than 4.0%, and the recovery was in the range of 97.5 - 104%. 相似文献
113.
Simulation of Patterns and Qualitative Analysis of Pattern Rotation in an End-Pumped Nd:YVO4 Laser 下载免费PDF全文
We simulate some laser output patterns observed in our previous experiment employing superposition of Laguerre- Gaussian modes. The rotating pattern is qualitatively analysed from the point of contemporary spatial burning hole effect of the lasing crystal. 相似文献
114.
In the present work, ferrites with compositions of (Ni0.27Zn0.64Cux)Fe1.98O4 (x=0.1, 0.2) were prepared by conventional ceramic methods. The relationship between the microstructure and the temperature dependence of relative initial permeability was investigated. It was found that intergranular pores in the ferrites generate large demagnetizing fields, reducing the temperature dependence of the effective anisotropy field Heff, and decreasing the temperature dependence of the relative initial permeability accordingly. However, intragranular pores pin the movement of domain walls. Compared with the permeability induced by domain wall motion, the permeability that resulted from the spin rotation is more sensitive to temperature. As a result, the relative initial permeability of ferrites becomes more sensitive to temperature with increasing micropores within grains. 相似文献
115.
绕圆柱体自由表面磁流体流动和传热的研究 总被引:1,自引:0,他引:1
本文对在不同雷诺数下,绕圆柱体的磁流体自由表面流动及传热进行了模拟,分析了磁场对绕流圆柱尾迹和涡分离的影响,获得了两种雷诺数下的电磁力密度、流场和温度场分布。结果表明,磁场不仅影响了流动的形态,而且对湍流有抑制作用,降低了自由表面的更新机制,从而减少了传热能力;在相同的Hartmann数下,相比低雷诺数下的流动换热情况,高雷诺数下的湍流不能被完全抑制,自由表面与尾迹的相互作用也较强,因而自由表面换热也较强。 相似文献
116.
Differentkindsofopenchaincrownethershavebeensynthesizedasthemodelcompoundsofionophoresandtheirinteractionswithsodium,potassiumandrareearthionshavealsobeenstudiedl'z.PanshowedCe(III)yieldedalf1complexwithl,8-bis(8'-quinolyloxy)-3,6-dioxaandtheCe(IIl)ioncoordinatedbothtoetheroxygenandquinolinenitrogenatoms3.TUmInleridentifiedtwolanthanidenitratecomplexeshavingastoichiometryof3:2(3RE:2L)'.InordertostUdythefunctionsofbothquinolineandbenzenering,introducedintothepolyetherchain,a1inearpolyether… 相似文献
117.
本文介绍了我们研制的“运动粒子瞬态激光全息测试仪”电子线路.该电路经严格的逻辑设计及计算,采用了10MHz时钟电路,并将1MHz的时钟信号巧妙地引入门控电路中,同时在技术上采用了行之有效的措施,消除了可能产生0.1μs的随机误差,时间间隔达到了(1~9)±0.1μs的精度,所输出的激光双脉冲能量接近,整机抗干抗能力强,一次性试验成功率高,可精确地测量雾化粒子场中的微粒的速度、形状、大小及其分布,收到了良好的使用效果. 相似文献
118.
<正> 四氢呋喃的阳离子型聚合反应和α-甲基苯乙烯的阴离子型聚合反应都是平衡聚合反应。Tobolsky等已经对平衡聚合反应动力学作了很多研究,认为该反应的产物具有Flory分布。但尚未确定上述分子量分布函数的参变数与哪些因素有关,因此该公式的应用受到限制。近年来,平衡聚合反应的研究蓬勃展开,其反应动力学理论显然也须进一步完善,以便可以通过反应条件来预测,调节和控制反应产物的平均分子量和分散 相似文献
119.
XinMeiZHENG YanXingQI XiaoMingZHANG JiShuanSUO 《中国化学快报》2004,15(6):655-658
Jacobsen‘s catalyst was immobilized onto SBA-15 by multi-step grafting, and this heterogenized catalyst exhibited comparable catalytic performance with the corresponding homogeneous counterpart for the epoxidation of alkenes, and the catalyst could be recycled effectively several times. 相似文献
120.