改性浇铸尼龙的研究进展

立足于浇铸尼龙的反应机理,结合对其在实际应用中的改性要求,阐述了改性浇铸尼龙的研究进展.尤其以聚合物改性浇铸尼龙为重点,从改性的机理和相形态等方面详细地介绍了其的研究情况,总结了最新的工作以及将来的发展方向,为尼龙材料的更加广泛应用提供一定的参考.     

Two Novel Myrinsol Diterpenes from Euphorbia prolifera

Two novel diterpenes,Euphorprolitherin A(1) and Euphorprolitherin B(2), were isolated from the roots of Euphorbia prolifera. Their structures were elucidated on the basis of spectroscopic methods.     

Intrinsic Surface Reaction Constant in 1-pK Model of Mg-Fe Hydrotalcite-like Compounds

The relationship among intrinsic surface reaction constant (K) in 1-pK model, point of zero net charge (PZNC) and structural charge density (σst) for amphoteric solid with structural charges was established in order to investigate the effect of σst on pK. The theoretical analysis based on 1-pK model indicates that the independent PZNC of electrolyte concentration (c) exists for amphoteric solid with structural charges. A common intersection point (CIP) should appear on the acid-base titration curves at different c, and the pH at the CIP is pHPZNC. The pK can be expressed as pK=-pHPZNC log[(1 2αPZNC)/(1-2αPZNC)], where αPZNC≡σst/eNANs, in which e is the elementary charge, NA the Avogadro‘s constant and Ns the total density of surface sites. For solids without structural charges, pK=-pHPZNC. The pK values of hydrotalcite-like compounds (HTlc) with general formula of [Mg1-xFex(OH)2](Cl,OH)x were evaluated. With increasing x, the pK increases, which can be explained based on the affinity of metal cations for H^- or OH^- and the electrostatic interaction between charging surface and H^- or OH^-.     

一个新的噻二唑衍生物H2ADTZ与锰的二维聚合物的合成与晶体结构(英)

A new 1,3,4 thiadiazole-derivative ligand 2,5-(s-acetic acid) dimercapto-1,3,4 thiadiazole (H₂ADTZ) and its one-dimensional manganese polymer Mn(ADTZ)·4H₂O had been synthesized and structurally characterized by X-ray single crystal diffraction in this paper. The Mn(Ⅱ) ion is coordinated with a distorted octahedron by two oxygen atoms from neighboring two deprotonated ligands ADTZ^2- and other four oxygen atoms from four coordinated water molecules. The structural feature of the title compound is the formation of one-dimensional manganese chains polymer through the bridging of dioxygen O-O units. In the solid state structure of the complex, one-dimensional manganese chains are joined together by the weak intermolecular hydrogen bonds and vander Waals interactions forming a two-dimensional supramolecular compound. Furthermore, the UV spectra and electro-chemical properties of the title compound were also investigated. CCDC: 260532.     

The Synthesis of Gracillin and Dioscin：TWO Typical Representatives of Spirostanol Glycosides

Two spirostanol saponins(gracillin and dioscin)which have the typical sugar moieties were synthesized facilely by a general approach.     

2003～2011年中国科普法规政策与化学普及书籍关系研究

2002年中国颁布科普法后,2003至2011年出版的化学普及书籍种数总体呈上升趋势。出版地和出版社总体上较为分散,局部集中度高。主题上基础知识类化学普及书籍最多,科学文化类次之,实用知识类较少,化学前沿类最少。涉及科普的一般法律、法规和政策对化学普及书籍的创作影响甚微。只有与国家约束性社会发展指标相关,发生涉及公民生命安全的重大社会事件,针对特定人群的具体实施政策出台,科普法规和政策才对化学普及书籍的出版起到推动作用。     

Syntheses and Crystal Structures of Mono-and Binuclear Copper(Ⅱ) Mixed-ligand Complexes Involving Schiff Base

1 INTRODUCTION The chemistry of copper compounds has been extensively investigated and the relationship be- tween structure and reactivity, ranging from indus- trial catalysis to biochemistry activity, is of major importance. For binuclear copper(II) complexes equa- torially bridged by pair of hydroxide[1] or alkoxide[2, 3] groups, satisfactory linear correlation is found be- tween the Cu–O–Cu bridging angle and spin coupling between the metal centers. However, for binuclear copper(I…     

基于时域约束的卷帘曝光星敏感器星点校正方法

针对卷帘曝光模式星敏感器动态星点成像形状畸变和成像位置误差导致的导航星点定位精度降低、测姿误差增大的问题,提出了一种基于时域约束的导航星点校正方法.基于卷帘曝光的时间异步性特点,结合基于卡尔曼滤波的导航星点位置和帧间速度最优估计,将时域中不同时刻的导航星点校正到相同时刻,从而有效地解决星点畸变与位置偏移问题.展开了不同...     

Zn-Al类水滑石的荧光性质

报道了一种新的Zn-Al类水滑石的荧光现象, 即在没有任何荧光物质插层的情况下, Zn-Al类水滑石本身就具有荧光性质, 其最大激发波长位于375 nm, 最大发射波长处于443 nm, 显示的荧光为蓝色可见光. 这一光学功能的发现将有助于类水滑石在光学材料领域中的进一步应用.     

氨基酸的光辅助氧化化学发光及其分析应用

氨基酸与溴酸钾混合液经紫外光照射后与鲁米诺反应产生较强的发光信号,且在一定条件下氨基酸浓度与发光强度成线性关系,据此建立了一种氨基酸测定方法。在优化的条件下,该方法对五种氨基酸的检出限在0.004μg/mL~0.06μg/mL范围内;分别对0.5μg/mL的五种氨基酸平行测定7次,其相对标准偏差在2·3%~4.2%范围内。初步考察了该方法与液相色谱联用测定氨基酸的可行性。