以纯硅silicalite-1为晶种制备空心结构ZSM-5沸石分子筛

微孔分子筛在实际应用过程中常常受到扩散限制的影响,分子筛内部的利用率不高.制备空心结构分子筛对于改善分子筛扩散传质、提高分子筛利用率具有重要意义.以纯硅silicalite-1为晶种,以四丙基氢氧化铵(TPAOH)为结构导向剂制备ZSM-5分子筛,无定型硅铝物种首先在晶种表面晶化生长,同时碱性合成体系的碱度则可以溶解不...     

Synthesis of ratiometric fluorescent nanoparticles for sensing oxygen

A facile reprecipitation-encapsulation method is used for the preparation of ratiometric fluorescent nanoparticles (NPs) for sensing intracellular oxygen. The surface of the NPs is modified in-situ with poly-L-lysine, which renders good biocompatibility and enables easy internalization into living cells. The sensor NPs contain a red fluorescent probe whose fluorescence is sensitive to oxygen with a quenching response of 77 % on going from nitrogen saturation to oxygen saturation, and a reference dye giving a green signal that acts as an oxygen-independent reference. The ratio of the two emissions serves as the analytical information and is sensitive to dissolved oxygen in the 0–43?ppm concentration range. When incorporated into cells, the ratio of the signals increases by 400?% on going from oxygen-saturated to oxygen-free environment.

分子印迹固相萃取/超高效液相色谱-串联质谱法同时测定动物源性食品中11种β-受体阻断剂残留

建立了一种分子印迹固相萃取/超高效液相色谱-串联四极杆质谱法同时测定动物源性食品中11种β-受体阻断剂残留量的方法。样品经β-葡萄糖醛苷酶/芳基硫酸酯酶酶解后,上清液调节p H值,以异丙醇-乙酸乙酯(5∶5,体积比)萃取,有机相吹干后复溶过分子印迹固相萃取柱净化。样品经BEH C_(18)色谱柱分离,以甲醇-5 mmol/L乙酸铵水溶液(含0.1%甲酸)进行梯度洗脱,电喷雾电离正离子模式下采用多反应监测,基质加标曲线定量。11种β-受体阻断剂在0.05~10μg/kg范围内线性关系良好,相关系数均不小于0.991,方法检出限和定量下限分别为0.02~0.1μg/kg和0.05~0.25μg/kg。在猪肉、猪肝基质中3个添加水平下,平均回收率分别为73.2%~108.3%及70.2%~98.2%,相对标准偏差分别为1.3%~9.5%及3.7%~9.8%。该方法快速、灵敏、准确,适用于β-受体阻断剂多组分残留的测定。     

Cl-ClO催化循环圈的从头算研究

采用分子轨道从头算方法,在B3LYP/6-311 G(3df)和G2水平上研究了极地平流层臭氧损耗的一个基本过程.计算结果明显支持Cl-ClO催化循环圈机理,并且从能量角度解释了了臭氧破坏的基本原因.还对循环圈中各个反应的反应能,生成焓,相对吉布斯自由能做了计算,计算结果相互协调都说明了Cl-ClO催化循环圈破坏臭氧机理的正确性.     

Yb3+,Er3+掺杂的SrAl2O4:Eu2+,Dy3+长余辉材料的发光特性

根据Dorenbos能级模型的推论,利用掺杂Yb3+和Er3+对典型的长余辉材料SrAl2O4:Eu2+,Dy3+(简称SAO:ED)的发光特性(发光强度和余辉时间)进行调制.在发光特性分析中,发展并使用了一种简便易行的解析模型,而不是常用的多项e指数衰减函数的经验模型.研究发现,正如Dorenbos所预言的,Yb+3...     

Dark fringe operation and noise reduction with optical subtraction approach and power allocation

We demonstrate a technique to achieve the reduction of excess noise with dark fringe operation by optical subtraction and power allocation strategy. By performing the subtraction in optical way, the excess noise resulted from the photocurrent is eliminated and the phase information can be extracted with single photoreceiver. Meanwhile, by allocating more optical power to the probe beam, the DC background and the signal amplitude of the photocurrent become very small simultaneously so that the dark fringe operation is achieved. We compare the spectral distributions resulted from the proposed technique with that from the widely employed balanced detection and the modified balanced detection techniques which both are based on electronic subtraction. It is found that the experimental results closely agree to the theoretical predictions.     

SOME RESULTS ABOUT COVERING PROPERTIES OF PRODUCTS

ＳＯＭＥ ＲＥＳＵＬＴＳ ＡＢＯＵＴ ＣＯＶＥＲＩＮＧ ＰＲＯＰＥＲＴＩＥＳ ＯＦ ＰＲＯＤＵＣＴＳ ￥ＪＩＡＮＧＪＩＧＵＡＮＧ;ＴＥＮＧＨＵＩＡｂｓｔｒａｃｔ：Ｔｈｅｆｏｌｌｏｗｉｎｇｒｅｓｕｌｔｓａｒｅｐｒｏｖｅｄ：１．ＬｅｔＸｂｅａｓｃｒｅｅｎ...     

氧分子和苯酚自由基反应机理的理论研究

用密度泛函理论B3LYP方法对氧分子和苯酚自由基反应机理进行了研究.在B3LYP/6-31G(d,p)水平上优化得到了反应路径上的反应物、中间体、过渡态和产物的几何构型和谐振频率;并在B3LYP/6-311 G(2df,2pd)水平上进行了单点能计算.计算结果表明,苯酚是O2同苯酚自由基Ⅰ反应的主要产物,苯酚过氧自由基Ⅴ和Ⅵ是此反应的次要产物.苯酚过氧自由基Ⅴ的主要后继反应中,环化形成[3.2.1]双环氧桥自由基Ⅶ是主要的反应路径,Ⅶ可以进一步开环反应,形成环裂解产物1,2和1,4二醛.     

光晶格中双组分玻色-爱因斯坦凝聚系统的调制不稳定性

利用线性稳定分析的方法,在不满足原子流相等的条件下,对光晶格中双组分玻色-爱因斯坦凝聚原子(BEC)系统的调制不稳定性区域与不同BEC组分的波长和不同的调制波长,以及两组分BEC间相互作用大小之间的关系进行了研究.结果显示,光晶格中双组分BEC系统的调制稳定性的区域在不满足原子流相等的条件下,随不同的波长,不同的调制和相互作用之间的大小会出现了较大的变化.相应结果可为实际应用中如何操控双组分BEC提供有用的信息.     

液体表面低频声波的非线性声光效应

实现了液体表面上低频声波的光衍射,得到了稳定的、具有高阶衍射的高反衬衍射图样.理论上首次考虑到表面声波中的高次谐波,得到了相应的非线性条件下衍射强度分布的解析表达式,并将这种非线性理论与实验结果进行对比.对比结果表明,非线性理论与实验结果有更高的吻合程度.