A Novel Asymmetric Synthesis of （-）-cis-1, 3-Dibenzylhexahydrofuro[3, 4-d]imidazole-2,4-dione

(-)-cis-1, 3-Dibenzyl-hexahydrofuro[3, 4-d]imidazole-2, 4-dione was prepared by a new synthesis method from meso dicarboxylic acid and dehydroabietylamine by asymmetric reduction in good yield with up to 91.6% e.e. value.     

聚偶氮酯的合成及用于乳液聚合

<正> 偶氮二异丁腈(AIBN)与二元醇反应得到聚偶氮酯(polyazoester),进而可按自由基反应引发单体聚合制备嵌段共聚物,近年来国外已有研究,其所用单体多为1,6-己二醇等低分子二元醇。本实验选用AIBN和PEG 400,用Pinner合成法经改进后制得了聚偶氮酯,分析了该产物的结构和热分解动力学,并使之部分分解引发丙烯酰胺得到了兼具表面活性和引发活性的预聚物。结果表明,这种预聚物用于醋酸乙烯聚合、苯乙烯和     

Intrinsic Surface Reaction Constant in 1-pK Model of Mg-Fe Hydrotalcite-like Compounds

The relationship among intrinsic surface reaction constant (K) in 1-pK model, point of zero net charge (PZNC) and structural charge density (σst) for amphoteric solid with structural charges was established in order to investigate the effect of σst on pK. The theoretical analysis based on 1-pK model indicates that the independent PZNC of electrolyte concentration (c) exists for amphoteric solid with structural charges. A common intersection point (CIP) should appear on the acid-base titration curves at different c, and the pH at the CIP is pHPZNC. The pK can be expressed as pK=-pHPZNC log[(1 2αPZNC)/(1-2αPZNC)], where αPZNC≡σst/eNANs, in which e is the elementary charge, NA the Avogadro‘s constant and Ns the total density of surface sites. For solids without structural charges, pK=-pHPZNC. The pK values of hydrotalcite-like compounds (HTlc) with general formula of [Mg1-xFex(OH)2](Cl,OH)x were evaluated. With increasing x, the pK increases, which can be explained based on the affinity of metal cations for H^- or OH^- and the electrostatic interaction between charging surface and H^- or OH^-.     

Synthesis and Liquid Crystalline Properties of 3-Substituted Pentane-2,4-dione, Pyrazole and Isoxazole Derivatives

The γ-substituted β-diketonate 2,4-dioxo-3-pentyl 4-[4-（n-octyloxy）cinnamoyl]oxybenzoate 1 and its pyrazole and isoxazole derivatives （2 and 3 respectively） have been synthesized and characterized by the spectroscopic methods and elemental analysis. The mesogenic properties of these compounds have been studied by polarizing optical microscopy （POM） and differential scanning calorimetry （DSC）. A monotropic nematic mesophase was observed for the β-diketonate 1, in contrast, the pyrazole 2 displays an enantiotropic smectic A and isoxazole 3 exhibits an enantiotropic nematic mesophase. The relationship between the structure and liquid crystalline properties has also been discussed.     

DFT Investigations About Pyrazine Molecules on Si(100)-2×1 Surface

It is important to understand the interface of aromatic molecules on semiconductor surfaces because of the rich functionality of such molecules on semiconductor surfaces. The chemisorption of pyrazine molecules on the Si( 100)-2×1 surface has been investigated using the B3LYP density functional theory with Si9H12 one-dimer and Si15H16 twodimer cluster models. The calculated results predict that N-dative bonded-state, C2= C5 [ 4 2 ] and the tightbridge1, 2, 5,6 products may coexist on the Si(100)-2×1 surface.     

SiHCl3-H2气相外延生长Si单晶反应机理的理论研究

采用密度泛函理论计算方法, 在B3LYP/6-311G*水平下, 计算并得到了SiHCl3与H2反应各反应通道上各驻点的构型、振动频率和能量. 结果表明, 在气相中SiHCl3分解的通道d和SiHCl3与H2反应的通道c为竞争反应, 但其均未还原出Si原子, 只有衬底Si参与SiHCl3-H2的反应, Si原子才淀积在Si衬底上.     

新型单膦配位羧酸银配合物的合成、表征及其热稳定性的研究(英)

0 IntroductionIn recent years, silver carboxylates have attractedmany interests, mostly because they are promisingcandidates in the growth of metal thin films via metal-organic chemical vapor deposition (MOCVD) tech-niques. These sliver compounds show low light sensi-tivity and relatively high thermal stability. Several ex-amples of bisphosphine ligands coordinated silver car-boxlylates have been reported[1￣4].Monophosphine coordinated silver complexes areexpected to have better volatility,…     

野生与种植青海川西獐牙菜中微量元素的测定

为了对比野生与种植青海川西獐牙菜中微量元素的变化,分别采集野生川西獐牙菜与种植青海川西獐牙菜种子采收前后的全植株,采用原子吸收光谱仪测定了其铜、锌、铁、锰、钴等微量元素含量。结果表明,野生川西獐牙菜较种植青海川西獐牙菜中微量元素含量高,种植川西獐牙菜在成熟种子采收后较采收前(花果期)铁、锰、钴、锌等元素含量高。     

d9配合物MOSE曲面和几何构型的研究

d~9电子构型的金属离子所形成的配合物几何构型一般为拉长八面体或平面正方形,晶体场理论和角重叠模型都对此作出了较满意的描述,但就该电子构型的中心离子与指定配体配位时易形成配合物的配位数、配体所处的位置等问题,至今尚无满意解释.本文通过分子轨道稳定化能(MOSE)的计算及其曲面的绘制,形象地解释了上述问题.     

含吗啉基片段的水杨醛席夫碱类化合物的合成及其淬灭1,1-二苯基-2-三硝基苯肼自由基性能

通过3-氟-4-吗啉基苯胺和取代水杨醛缩合反应,合成了14个含吗啉基片段水杨醛席夫碱类化合物(Ⅰa-Ⅰn)。通过核磁共振波谱仪(NMR)、傅里叶变换红外光谱仪(FTIR)、液相色谱-质谱联用仪(LC-MS)和元素分析等技术手段研究了产物的结构和淬灭1,1-二苯基-2-三硝基苯肼(DPPH)自由基的活性。 结果表明,在0.02~0.10 g/L,所有化合物均表现出一定的淬灭DPPH自由基活性。 其中,化合物Ⅰd和Ⅰf表现出较为优异的性能,化合物Ⅰd的活性在30%~55%,化合物Ⅰf的活性则大于50%。 随着化合物Ⅰd、Ⅰh、Ⅰj和Ⅰn质量浓度的增大,其淬灭DPPH自由基的活性均呈现增强趋势。