Observation of a new metastable liquid-crystalline phase in supercooled blue phase systems

A new metastable liquid-crystalline phase BPS was observed in pure chiral compounds. The BPS is transformed reversibly from the supercooled BPI and is thermodynamically stable with respect to the BPI and metastable to the cholesteric phase. Rhombic single crystals of the BPS probably indicate a cubic lattice structure as in other BPs, but the lattice constant exhibits an anomalous temperature dependence.     

μSR at new accelerators

In this paper I speculate upon the potential of muon spin rotation/relaxation/resonance (μSR) for future refinement and/or exploitation at large accelerators like KAON, which might generate muon beams a hundred times more intense than today's best. Several schemes for efficient utilisation of such beams might be well worth implementing on existing muon channels. Work supported by NRC and NSERC.     

A numerical study of an unsteady laminar flow in a doubly constricted 3D vessel

Unsteady flow dynamics in doubly constricted 3D vessels have been investigated under pulsatile flow conditions for a full cycle of period T. The coupled non‐linear partial differential equations governing the mass and momentum of a viscous incompressible fluid has been numerically analyzed by a time accurate Finite Volume Scheme in an implicit Euler time marching setting. Roe's flux difference splitting of non‐linear terms and the pseudo‐compressibility technique employed in the current numerical scheme makes it robust both in space and time. Computational experiments are carried out to assess the influence of Reynolds' number and the spacing between two mild constrictions on the pressure drop across the constrictions. The study reveals that the pressure drop across a series of mild constrictions can get physiologically critical and is also found to be sensitive both to the spacing between the constrictions and the oscillatory nature of the inflow profile. The flow separation zone on the downstream constriction is seen to detach from the diverging wall of the constriction leading to vortex shedding with 3D features earlier than that on the wall in the spacing between the two constrictions. Copyright © 2002 John Wiley & Sons, Ltd.     

Intercalated smectic-A structures in a new class of laterally branched substances

X-ray, DSC and optical studies of a new class of substances with aromatic rings in the lateral branches are reported. The thermal behaviour of the substances is discussed. The X-ray measurements lead to a structural model of the SA phases consisting of layer structures with intercalating molecules.     

Comparison of four quantification methods for the determination of PCB in transformer oils

The analysis of PCB in transformer oils has been achieved with three HRGC/ECD based methods, proposed by the International Electrotechnical Commission (IEC/TC 10), by the Comité Européen de Normalisation (CEN/TC 19/WG 22) and by the Deutsches Institut für Normung (DIN 51 527). The same clean-up, described in the CEN/TC 19/WG 22, has been used for all the samples, allowing a comparison of the quantification procedure only. The total chlorine content has also been determined with X-ray fluorescence. These different methods of quantification are compared and their application for legislative purposes is discussed.Dedicated to Professor Dr Dieter Klockow on the occasion of his 60th birthday     

Raman spectroscopic investigations of the structure and phase transitions of liquid crystalline lead(II) alkanoates

Lead(II) alkanoates with even chain lengths from octanoate to octadecanoate have been investigated by Raman spectroscopy. In the low frequency region, transverse and longitudinal acoustical modes (TAM, LAM) have been assigned. It was shown that LAM-1 is the vibration of the double chain with the node of the vibration in the Pb²⁺ layer. A fully extended conformation of the chains in the low temperature phase was confirmed. The frequencies and intensities of the LAMs as compared with those of the alkanes and the fatty acids led to an estimate of the force constant and polarizability of the Pb²⁺ -COO^- bond relative to the C-C bond. The defects at the chain ends were investigated in the ρ(CH₃) and v(CC) region. For the intermediate (CM) phase, both the Pb²⁺ layer distance reduction and the chain length independent enthalpy contributions can be attributed mainly to defects at the chain ends.     

Photoinduced electron transfer variables: rigidity or orientation?

The relatives photoreactives of bridged-ring systems 1, 3, 5-X and 6-X (X ≡ Cl or Br) have been studied at 254 nm in acetic acid. The formation of photosolvolysis product was rationalized in terms of photoinduced intramolecular electron transfer (ET) processes. The relative ease of ET in these donor—bridge—acceptor model system was analyzed in terms of known ET variables including free-energy changes, orientation effects and ridigity effects. The observed relative photoreactivities agreed better with the calculated free-energy changes when relative rigidities of the electron acceptor termini were evaluated. In general, the more rigid system were more photoreactive.