Curcumin: A naturally occurring long‐wavelength photosensitizer for diaryliodonium salts

Curcumin, a naturally occurring, intensely yellow dye extracted from the spice turmeric, is an efficient photosensitizer for diaryliodonium salt photoinitiators at wavelengths ranging from 340 to 535 nm. With curcumin as a photosensitizer, it is possible to carry out the cationic photopolymerization of a wide variety of epoxide, oxetane, and vinyl monomers with long‐wavelength UV and visible light. An example of the photopolymerization of an epoxide monomer with ambient solar irradiation is provided. Several other curcumin analogues were synthesized, and their use as photosensitizers is examined. With such photosensitizers, the range of spectral sensitivity can be extended well into the visible region of the electromagnetic spectrum. © 2005 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 43: 5217–5231, 2005     

Pressure effects in a plastic columnar discotic triphenylene

The effect of hydrostatic pressure on the structure of a plastic columnar discotic triphenylene has been investigated. The goal was to determine whether pressure can be used to modify electronic properties via changes in structural properties of columnar discotics to any significant extent. The findings are that (i) the intra- and inter-columnar distances are reduced in a nearly isotropic fashion, (ii) that the crystal sizes are reduced and (iii) that a transition takes place from a more highly ordered plastic columnar to a less ordered hexagonal columnar state with increasing pressure. The induced decrease of the molecular distances, amounting to 6% for pressures up to 17 kbar, are clearly too small to induce an appreciable modification of the electronic structure and thus opto-electronic properties.     

Control of a liquid–liquid heat exchanger

 The analytical solutions of equations describing the dynamics of distributed parameter systems are usually complicated in form and derivations and inconvenient to use for simulation and control system design. The liquid–liquid counter flow heat exchanger is an example of these disturbed parameter systems. An analytical solution of the dynamics of a symmetrically operated counter flow heat exchanger in the form of transfer function matrix is investigated in open-loop and close-loop conditions. The resulting non-linear model was linearized using perturbation approach. A feed-forward path controller to counteract at any disturbances in the boundary temperature and a non-interactive controller to decouple the outputs were implemented. Received on 22 February 2001 / Published online: 29 November 2001     

On Critical Stability of Three Quantum Charges Interacting Through Delta Potentials

We consider three one-dimensional quantum, charged and spinless particles interacting through delta potentials. We derive sufficient conditions which guarantee the existence of at least one bound state.     

Asymptotic integration of a problem of convection

Rostov-on-Don. Translated from Sibirskii Matematicheskii Zhurnal, Vol. 30, No. 4, pp. 69–75, July–August, 1989.     

Method of linear prediction in the ultrasonic spectroscopy of rock

The possibility of using the resonant acoustic spectroscopy method for testing the internal state of rock is considered. This method can be used for the determination of the concentration of defects and their spatial distribution. A rock specimen with defects is characterized by a high loss of vibrational energy, which leads to the overlapping of the resonant responses. In this case, the complex resonant frequencies are determined as the parameters of a model that describes the measured transfer function of the response of the mechanical system. The linearity of the vibratory system is used as the a priori information for presetting the functional dependences of the model. An algorithm is developed for the determination of the parameters of the resonances in conditions of their partial overlapping. Examples are presented to demonstrate the possibility of analyzing the complex elastic constant tensor of rock by the acoustic spectroscopy method. The proposed method of experimental data processing provides the possibility for the determination of the weak anisotropy that occurs in the velocity of sound because of a partial fracture of rock.     

Conditional Time Before Ruin of an Insurance Company

The statistical characteristics of conditional time before ruin of an insurance company, including the distribution function of conditional time and its moments are examined.     

The Universe in the Logunov Metric

Exact solutions of the Lagrange equations in the Logunov metric are found in the context of classical gravitation theory.