Enumeration of wurtzite derivatives and related dipolar tetrahedral structures

Pólya's theorem and related results are used to count and classify by space group all possible wurtzite derivatives with small unit cells having composition ABX₂, AB₂X₃, AB₃X₄, or ABC₂X₄. The same arguments are applied to the dipolar tetrahedral structures, which resemble wurtzite but have a different pattern of occupancy of the tetrahedral voids in the hcp anion framework. Covalent molecular orbital and electrostatic calculations are used to study the two real and eight hypothetical structures for Li₃PO₄. Both predict shared edges to be destabilizing, in keeping with Pauling's rules.     

Weak transverse magnetic field effect on the viscosity of Ni(NO3)2H2O solution

Experiments performed at 25°C show that transversally applied magnetic field H of strength of 12 kG; at high concentrations decreases the viscosity of Ni(NO₃)₂H₂O solution. At low concentrations, however, the applied magnetic field increases the viscosity of Ni(NO₃)₂H₂O solution in such a way as the observed effect value approaches the already measured viscosity increase of the pure water at the same magnetic field and temperature conditions.     

Normal coordinate ab initio force relaxation

A procedure for optimization of molecular geometries is presented, combining ab initio calculations with vibrational molecular data from spectroscopy or empirical force fields. Theoretical cartesian forces are transformed to vibrational normal coordinate forces from which geometry increments are calculated. Test results indicate that the method saves considerable effort compared to other optimization schemes.     

An automated procedure for the simultaneous determination of specific conductance and pH in natural water samples

An automated, continuous-flow system is utilized to determine specific conductance and pH simultaneously in natural waters. A direct electrometric procedure is used to determine values in the range pH 4–9. The specific conductance measurements are made with an electronically modified, commercially available conductivity meter interfaced to a separate module containing the readout control devices and printer. The system is designed to switch ranges automatically to accommodate optimum analysis of widely varying conductances ranging from a few μmhos cm^-1 to 15,000 μmho cm^-1. Thirty samples per hour can be analyzed. Comparison of manual and automated procedures for 40 samples showed that the average differences were 1.3% for specific conductance and 0.07 units for pH. The relative standard deviation for 25 replicate values for each of five samples was significantly less than 1% for the specific conductance determination; the standard deviation for the pH determination was ? 0.06 pH units.     

Photoassociative spectroscopy of pure long-range molecules

We have experimentally studied the “pure long-range” state, 0 _g ^? , of³⁹K₂ for the first time by high resolution photoassociative spectroscopy of ultracold potassium atoms. Well-resolved vibrational levels have yielded molecular constants for this state. Analytical expressions for the potential energy curves of the two pure long-range states, 0 _g ^? and 1 _u , are obtained. All the available theoretical and experimental molecular constants of the three special long-range potentials with extrema for all the alkali metals are summarized.     

Determination of total sulphur in coal by x-ray fluorescence spectrometry

A precise x-ray fluorescence method for the determination of sulphur in coat. The sample is mixed with calcium oxide and active carbon and is gradually heated to 900°C. After coding, lithium tetraborate and lead oxide are added and a prepared. The Pb M_α line is used as an internal standard for the KK_α line. The results for coal have a relative standard deviation of approximately 1% and exhibit.     

Untersuchungen zur thermischen Zersetzung von Boraten

In spite of numerous investigations the literature data on the thermal decomposition of borax are contradictory. On the basis of thermal, X-ray, gas analytical and optical investigations this fact can be attributed to the complex decomposition mechanism. After the release of about 8 mole water the reaction product is an X-ray amorphous phase, having the thermal behaviour of glass. From this glass sodium diborate (Na₂O.2B₂O₃) crystallizes between 500–600? with further mass loss. Sodium diborate decomposes from about 700? incongruently yielding NaBO₂ vapor and B₂O₃ glass phase. After evaporation of NaBO₂ is completed the rate of evaporation of B₂O₃ increases considerably.     

A theory of glass electrode response

Summary The response of glass electrodes to rapid changes in ion concentrations is considered from a theoretieal viewpoint. An expression is derived which describes the potential vs. time behavior of glass eleotrodes in terms of a new constant which may be useful in the characterization and selection of glass compositions. Agreement between glass electrode response predicted by the theory and available experimental data is excellent.

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Zusammenfassung Die Ansprechbarkeit von Glaselektroden auf rasche Änderungen der Ionenkonzentration wird vom theoretischen Standpunkt aus erörtert. Eine Gleichung wird abgeleitet, die das Elektrodenpotential als Funktion der Zeit erfaßt und eine neue Konstante enthält, die zur Beurteilung und zur Auswahl der Zusammensetzung von Gläsern dienen kann. Es besteht eine sehr gute Übereinstimmung zwischen theoretisch vorausgesagter und experimentell geprüfter Ansprechbarkeit von Glaselektroden.

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The financial support of NIH Grant GM-10086-03 and NSF Grant GP-1093 is gratefully acknowledged.

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Alfred P. Sloan Research Fellow.     

Spectrometric determination of the fineness of gold

The use of the glow discharge source has been tested for the analysis of refined gold by direct reading emission spectrometry. Careful investigations of the discharge parameters and the introduction of the sputtering rate as internal standard led to a very precise and accurate analytical procedure which has been proved by analysing 100 unknown samples of refined gold. The proposed spectrometric analysis is at least as accurate as the conventional fire assay method and is much faster and laboursaving.     

Electronic structure of octacyanides of molybdenum IV and V according to the SCCC MO method

The SCCC MO method has been used to calculate the electronic structure and spectrum of Mo(CN) ₈ ^4– and Mo(CN) ₈ ^3– ions of a D _4d symmetry. All metal-ligand and ligand-ligand interactions and all overlap integrals (over products of HF atomic orbitals) have been included within the SCCC MO scheme. Basing on these calculations a new assignment of some absorption bands is proposed. The overall agreement between the calculated and observed electronic spectrum is satisfactory.

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Zusammenfassung Elektronenstruktur und Spektrum der [Mo(CN)₈]^–4- und [Mo(CN)₈]^–3-Ionen in D _4d -Symmetrie wurden mit der SCCC-MO-Methode berechnet. Alle Metall-Ligand- und Ligand-Ligand-Wechsel-wirkungen und Überlappungsintegrale wurden berücksichtigt. Die Bandenzuordnung wurde neu vorgenommen. Die Übereinstimmung der berechneten und gemessenen Spektren ist befriedigend.

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Résumé Application à Mo(CN) ₈ ^4– et Mo(CN) ₈ ^3– de la méthode SCCC MO basée sur des orbitales atomiques HF approchées, en tenant compte du recouvrement et de toutes les interactions ligand-ligand. Dans la partie I on discute le cas de la symétrie D _4d . L'accord global avec l'expérience est satisfaisant en ce qui concerne les spectres. On montre aussi que toutes les attributions antérieures basées sur la théorie du champ cristallin semblent inadéquates.

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The authors are grateful to Prof. W. Jakób, Dr. Z. Stasicka and Dr. A. Samotus for many interesting discussions, to Prof. J. Chojnacki for providing us with new X-ray results before publication and to Dr. A. J. Sadlej for a help in dealing with the computer.