排序方式: 共有206条查询结果,搜索用时 15 毫秒
31.
Löffler D Uhlrich JJ Baron M Yang B Yu X Lichtenstein L Heinke L Büchner C Heyde M Shaikhutdinov S Freund HJ Włodarczyk R Sierka M Sauer J 《Physical review letters》2010,105(14):146104
Thin SiO? films were grown on a Ru(0001) single crystal and studied by photoelectron spectroscopy, infrared spectroscopy and scanning probe microscopy. The experimental results in combination with density functional theory calculations provide compelling evidence for the formation of crystalline, double-layer sheet silica weakly bound to a metal substrate. 相似文献
32.
Schmid M Shishkin M Kresse G Napetschnig E Varga P Kulawik M Nilius N Rust HP Freund HJ 《Physical review letters》2006,97(4):046101
A model for the straight antiphase domain boundary of the ultrathin aluminum oxide film on the NiAl(110) substrate is derived from scanning tunneling microscopy measurements and density-functional theory calculations. Although the local bonding environment of the perfect film is maintained, the structure is oxygen deficient and possesses a favorable adsorption site. The domain boundary exhibits a downwards band bending and three characteristic unoccupied electronic states, in excellent agreement with scanning tunneling spectroscopy measurements. 相似文献
33.
Shi DX Ji W Lin X He XB Lian JC Gao L Cai JM Lin H Du SX Lin F Seidel C Chi LF Hofer WA Fuchs H Gao HJ 《Physical review letters》2006,96(22):226101
We use low energy electron diffraction, scanning tunneling microscopy, first-principles density-functional theory, and molecular mechanics calculations to analyze the adsorption and growth of quinacridone derivatives (QA) with alkyl chains of 4 and 16 carbon atoms on a Ag(110) substrate. Surprisingly, we find that the alkyl chains determine the orientation of the molecular overlayers. While the interaction of QA and the Ag substrate is primarily due to chemical bonding of oxygen to the silver substrate, determining the molecular orientation and preferred adsorption site, the intermolecular arrangement can be adjusted via the length of alkyl chains. We are thus able to fabricate uniform QA films with very well controlled physical properties. 相似文献
34.
Wu W Kiryukhin V Noh HJ Ko KT Park JH Ratcliff W Sharma PA Harrison N Choi YJ Horibe Y Lee S Park S Yi HT Zhang CL Cheong SW 《Physical review letters》2008,101(13):137203
We have studied quasi-two-dimensional multiferroic LuFe2O4 with strong charge-spin-lattice coupling, in which low-temperature coercivity approaches an extraordinary value of 9 T in single crystals. The enhancement of the coercivity is connected to the collective freezing of nanoscale pancakelike ferrimagnetic domains with large uniaxial magnetic anisotropy ("Ising pancakes"). Our results suggest that collective freezing in low-dimensional magnets with large uniaxial anisotropy provides an effective mechanism to achieve enhanced coercivity. This observation may help identify novel approaches for synthesis of magnets with enhanced properties. 相似文献
35.
From the measurement of a reflection spectrum of an open microwave cavity, the poles of the scattering matrix in the complex plane have been determined. The resonances have been extracted by means of the harmonic inversion method. By this, it became possible to resolve the resonances in a regime where the linewidths exceed the mean level spacing up to a factor of 10, a value inaccessible in experiments up to now. The obtained experimental distributions of linewidths were found to be in perfect agreement with predictions from random matrix theory when wall absorption and fluctuations caused by couplings to additional channels are considered. 相似文献
36.
Bäcker A Ketzmerick R Löck S Robnik M Vidmar G Höhmann R Kuhl U Stöckmann HJ 《Physical review letters》2008,100(17):174103
We study the fundamental question of dynamical tunneling in generic two-dimensional Hamiltonian systems by considering regular-to-chaotic tunneling rates. Experimentally, we use microwave spectra to investigate a mushroom billiard with adjustable foot height. Numerically, we obtain tunneling rates from high precision eigenvalues using the improved method of particular solutions. Analytically, a prediction is given by extending an approach using a fictitious integrable system to billiards. In contrast to previous approaches for billiards, we find agreement with experimental and numerical data without any free parameter. 相似文献
37.
Hossain MA Hu Z Haverkort MW Burnus T Chang CF Klein S Denlinger JD Lin HJ Chen CT Mathieu R Kaneko Y Tokura Y Satow S Yoshida Y Takagi H Tanaka A Elfimov IS Sawatzky GA Tjeng LH Damascelli A 《Physical review letters》2008,101(1):016404
Sr3(Ru(1-x)Mnx)2O7, in which 4d-Ru is substituted by the more localized 3d-Mn, is studied by x-ray dichroism and spin-resolved density functional theory. We find that Mn impurities do not exhibit the same 4+ valence of Ru, but act as 3+ acceptors; the extra eg electron occupies the in-plane 3d(x2-y2) orbital instead of the expected out-of-plane 3d(3z2-r2). We propose that the 3d-4d interplay, via the ligand oxygen orbitals, is responsible for this crystal-field level inversion and the material's transition to an antiferromagnetic, possibly orbitally ordered, low-temperature state. 相似文献
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39.
Zotti LA Teobaldi G Palotás K Ji W Gao HJ Hofer WA 《Journal of computational chemistry》2008,29(10):1589-1595
We modelled the adsorption of benzene, fluorobenzene and meta-di-fluorobenzene on Cu(110) by Density Functional Theory. We found that the adsorption configuration depends on the coverage. At high coverage, benzene assumes a tilted position, while at low coverage a horizontal slightly distorted geometry is favoured. Functionalizing the benzene ring with one or two fluorine atoms weakens the bonding to the surface. A rotation is induced, which decreases the distance of the fluorine atom from the surface. STM simulations reveal that details about both, benzene adsorption geometry and fluorine position, can be only detected at short tip-surface distances. 相似文献
40.
Berger R Cheng Y Förch R Gotsmann B Gutmann JS Pakula T Rietzler U Schärtl W Schmidt M Strack A Windeln J Butt HJ 《Langmuir : the ACS journal of surfaces and colloids》2007,23(6):3150-3156
In this paper, we describe atomic force microscope (AFM) friction experiments on different polymers. The aim was to analyze the influence of the physical architecture of the polymer on the degree and mode of wear and on the wear mode. Experiments were carried out with (1) linear polystyrene (PS) and cycloolefinic copolymers of ethylene and norbornene, which are stabilized by entanglements, (2) mechanically stretched PS, (3) polyisoprene-b-polystyrene diblock copolymers, with varying composition, (4) brush polymers consisting of a poly(methyl methacrylate) (PMMA) backbone and PS side chains, (5) PMMA and PS brushes grafted from a silicon wafer, (6) plasma-polymerized PS, and (7) chemically cross-linked polycarbonate. For linear polymers, wear depends critically on the orientation of the chains with respect to the scan direction. With increasing cross-link density, wear was reduced and ripple formation was suppressed. The cross-linking density was the dominating material parameter characterizing wear. 相似文献