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941.
G.D. Manolis 《Journal of sound and vibration》2003,266(2):281-305
This work examines elastic wave scattering around cavities embedded in a continuum with depth-dependent shear modulus and under conditions of plane strain. A restricted case of inhomogeneity is considered, where the Poisson ratio is fixed at 0.25 and where the density profile also varies, but proportionally to the shear modulus. For this specific case, the wave speeds remain macroscopically constant and it becomes possible to recover the exact Green functions by using an algebraic transformation method. These functions are subsequently used as kernels in a standard 2D boundary element formulation defined in the Laplace transform domain. The final step involves an inverse Laplace transformation, whereby the transient behavior of cavities in the aforementioned inhomogeneous continuum can be recovered. Two basic examples are solved, namely the circular cylindrical cavity under sudden internal explosion and under a pressure wave sweep. In the latter case, it is possible to investigate the effect that the angle of wave incidence has on the displacement and stress that develop along the cavity's perimeter, given the fact that the shear modulus is changing along the vertical direction. These examples serve to illustrate the present approach and to reveal some interesting differences that are observed in transient wave scattering phenomena between homogeneous and continuously inhomogeneous models, where the latter models yield a more realistic representation of geological formations. 相似文献
942.
A crystalline quartz plate of thickness 1.070 mm is calibrated between 370 and 794 nm. Throughout this spectral interval, the retardance varied by 32π and the plate introduced quarterwave retardance 16 times at different wavelengths. The birefringence (ne−no) of crystalline quartz was calculated as a single quantity and varied from 0.00971 at 370 nm to 0.00891 at 794 nm. All measurements were carried out at 23°C. 相似文献
943.
H. Yonemura S. Moribe K. Hayashi M. Noda H. Tokudome S. Yamada H. Nakamura 《Applied magnetic resonance》2003,23(3-4):289-307
Photoinduced intramolecular electron-transfer reactions in carbazole (Cz)-fullerene (C60) (Cz(8)C60) and phenothiazine (Ph)-C60 (Ph(n)C60 (n=8, 10, 12)) linked compounds have been investigated in benzene and benzonitrile by fluorescence, transient absorption, and time-resolved electron paramagnetic resonance measurements, and by magnetic field effects on the decay rate constants of the photogenerated biradicals. In benzonitrile, photoinduced intramolecular electron transfer from Cz to the singlet excited state of C60 (1C60 *) occurred in Cz(8)C60, but not to the triplet excited state (3C60 *), while the intramolecular electron-transfer to both1C60 * and3C60 * occurred in Ph(n)C60 (n=8, 10, 12). In benzene, on the other hand, no electron transfer to both1C60 * and3C60 * took place in all linked compounds. These results were interpreted in terms of the different Gibbs free energy changes in the two solvents. 相似文献
944.
Timoshenko's theory of vibrating beams requires a shear correction factor to correctly take into account the effects of shear deformation for different beam cross-sections. This correction is crucial for a precise determination of the shear modulus from the resonant frequencies. Hutchinson's beam theory is used to derive a new shear correction coefficient for anisotropic materials. A comparison is made with other shear coefficients for anisotropic materials published in the literature. Computer-simulated spectra are used to validate the new anisotropic shear correction coefficient. 相似文献
945.
The refraction holodiagram RHD is analyzed here with respect to the law of refraction. Particularly, we study the surface that exactly conjugates by refraction a virtual point source with a real image or conversely. By using the total optical path as a parameter we build a diagram that consists in a family of Descartes ovals of the apple type that contains the Pascal's limaçon as a particular extreme case and the spherical surface with the Weierstrass points as another. These representations permit the straightforward application of Fermat's principle in the case of arbitrary refracting surfaces and show the shape of generalized Fresnel's zones in the intersections with any surface. Snell's law is applied to rays incident on the apple type surfaces to find out the conditions for exact conjugation. Sensitivity to optical path variations is also discussed. The RHD curves family can be represented in a Cartesian way where the ovals appear as equally spaced straight lines. 相似文献
946.
C.H. Chen 《Journal of sound and vibration》2003,263(4):797-813
A neural-network-based method is offered to determine the flutter derivatives of section models under smooth and turbulent flows. The approach uses the observed dynamic responses to train an appropriate neural network. Subsequently, the modal parameters of the model for different mean velocities of wind flow are directly estimated using weight matrices in the neural network. The flutter derivatives can then be determined accurately. The validity of the present method is verified through numerical studies. Finally, the procedure is employed to process experimental data from an inverted-U-type section model, obtained from wind tunnel tests. 相似文献
947.
The local vibrational spectra of copper crystals containing vacancies are calculated using the pair atomic potential derived in the framework of the resonance pseudopotential theory. The calculations are performed by a recursive method with due regard for the symmetry of the defect region. The frequencies of the vacancy-induced resonance vibrations of different symmetries are determined. 相似文献
948.
949.
Determination of electronic structure of ozone related geometry is the main subject in this research. The proposed electronic structure must satisfy the experimental geometry, explain the excellent oxidizing properties of ozone, and can also explain the capability of additional reaction with unsaturated hydrocarbons. The potential energy surface of singlet and triplet state of ozone has been studied in order to check the correctness of the proposed structure. The proposed electronic structure of ozone is capable of explaining the oxidizing behavior of ozone in visible wavelength (daylight) 430–700 nm. For comparison, the other proposed structure of ozone in literature such as Pauling, Linnett and Weinhold has also been discussed. The main method used in this research is well-known density functional procedure, B3LYP, which takes the electron correlation aspect into consideration. The polarization and diffused functions are included in the basis set, 6-311++G**. The obtained geometry is a bent and cumulated double bond with inter-bond angle 118.42° (1.39%), and bond length 1.256 Å (1.72%). The obtained results revealed that frontier orbital theory is a proper tool for explaining the addition reaction. 相似文献
950.
Kukharev B. F. Stankevich V. K. Klimenko G. R. 《Russian Journal of Organic Chemistry》2003,39(5):625-629
Russian Journal of Organic Chemistry - 相似文献