Indium-mediated one-pot three-component reaction of aromatic amines, enol ethers, and allylic bromides

[reaction: see text] A new and efficient indium-mediated one-pot three-component reaction for the synthesis of N-aryl-substituted homoallylamines from aromatic amines, enol ethers, and allylic bromides in THF at room temperature is described.     

Seshadri-exceptional foliations

 The maximal Seshadri number μ(L) of an ample line bundle L on a smooth projective variety X measures the local positivity of the line bundle L at a general point of X. By refining the method of Ein-Küchle-Lazarsfeld, lower bounds on μ(L) are obtained in terms of L ⁿ , n=dim(X), for a class of varieties. The main idea is to show that if a certain lower bound is violated, there exists a non-trivial foliation on the variety whose leaves are covered by special curves. In a number of examples, one can show that such foliations must be trivial and obtain lower bounds for μ(L). The examples include the hyperplane line bundle on a smooth surface in ℙ³ and ample line bundles on smooth threefolds of Picard number 1. Received: 29 June 2001 / Published online: 16 October 2002 RID="⋆" ID="⋆" Supported by Grant No. 98-0701-01-5-L from the KOSEF. RID="⋆⋆" ID="⋆⋆" Supported by Grant No. KRF-2001-041-D00025 from the KRF.     

Synthesis of nonlinear optical maleimide copolymer by polymer reaction and their electro-optic properties

Thermally stable poly(α-methyl styrene-co-maleimide) (MSMI) and poly(α-methyl styrene-co-4-carboxyphenyl maleimide) (MSCM) substrate polymers were obtained readily by free radical polymerization of comonomers. Introduction of a DR1 chromophore to the maleimide units of MSMI substrate polymer by the Mitsunobu reaction was dependent on the reaction solvent. The degree of substitution of DR1 into the MSMI polymer was bound to be 91.1 mol % and 0.4 mol % by UV spectrometers in the THF and DMF solvent, respectively. DR1 chromophore was, however, substituted in the MSCM polymer at 33.0 mol % by Mitsunobu reaction in the THF solvent. Both substrate and NLO polymer exhibited high thermal stability due to the incorporation of maleimide units in the polymer chain. The glass transition temperature (T_g) and initial decomposition temperature (T_i) of the NLO polymer were in the range of T_g = 185°C and T_i = 310–345°C. The electro-optic coefficient (r₃₃) of NLO polymer was determined with an experimental setup capable of the real-time measurement while varying both the poling field and temperature. The NLO polymer MSMI-THF had a higher r₃₃ value than MSCM-DR due to an increased degree of substitution of DR1 chromophore. MSMI-THF had a maximum r₃₃ value of 16 pm/V at 135 MV/m poling field with a 632.8 nm light source. © 1999 John Wiley & Sons, Inc. J Polym Sci A: Polym Chem 37: 3715–3722, 1999     

Synthesis and characterization of liquid crystals containing a non-activated 1' ,3' ,3'-trimethylspiro\[2H-1-benzopyran-2,2-indoline] group

Two series of mesogens derived from the non-activated spiropyran dyes 6-hydroxy-1 ,3 ,3- trimethylspiro\[2H -1-benzopyran-2,2-indoline] (series trimethylspiro\[2 H -1-benzopyran-2,2-indoline] (series 2 ) have been synthesized. Analysis by differential scanning calorimetry, polarizing microscopy and X-ray diffraction showed compounds in series 1 form monotropic nematic and SmA phases, while compounds in series 2 form only a monotropic nematic phase.     

Novel stilbene‐based Fischer base analog of leuco‐TAM – (2E,2′Z)‐{2‐(4‐(E)‐styrylphenyl)propane‐1,3‐diylidene}bis(1,3,3‐trimethylindoline) – derivatives: synthesis and structural consideration by 1D NMR and 2D NMR spectroscopy

We report the synthesis of a series of novel stilbene‐based (St) Fischer base analogs of leuco‐triarylmethane (LTAM) dyes by treating Fischer base with (E)‐4‐styrylbenzaldehyde derivatives. All St‐LTAM molecules examined herein are characterized by 1D and 2D NMR. They were found to exhibit ZE configuration and isomerize to their diastereomers EE and ZZ in 2–3 h. They exhibit type I behavior of diastereomeric isomerization. Copyright © 2015 John Wiley & Sons, Ltd.     

Novel Reductive Cleavage Reaction of Thiobenzoates with Samarium Diiodide: Convenient Synthesis of Disulfides

The reductive cleavage of thiobenzoates promoted by samarium diiodide afforded various kinds of disulfides in good yields under mild and neutral conditions.     

Working group report: Low energy and flavour physics

This is a report of the low energy and flavour physics working group at WHEPP-8, held at the Indian Institute of Technology, Mumbai, India, during 5–16 January 2004.     

Input shaping control of a nuclear power plant’s fuel transport system

In this paper, the residual vibration control problem of a nuclear power plant’s fuel-transport system is discussed. The purpose of the system is to transport fuel rods to the target position within the minimum time. But according to observations, the rods oscillate at the end of the maneuver, causing an undesirable delay in the operation and affecting the system’s performance in terms both of productivity and of safety. In the present study, a mathematical model of the system was developed to simulate the under-water sway response of the rod while keeping in view the effects of the hydrodynamic forces imposed by the surrounding water. Experiments were performed to validate the model’s correctness. Further, simulation results were used to design the input shaping control that generates shaped velocity commands for transport of the fuel rods to the target position with the minimum residual vibration. It was observed that due to the under-water maneuvering, the fuel-handling system behaves as a highly damped process and that the generated shaped velocity commands fail to effect the desired suppression of the residual vibration. Therefore, keeping in view the highly damped nature of the system, a modified shaped command was generated that transported the fuel rods to the target position with the minimum residual vibration.     

Construction of surfaces of general type from elliptic surfaces via {\mathbb{Q}}-Gorenstein smoothing

We present methods to construct interesting surfaces of general type via ${\mathbb{Q}}$ -Gorenstein smoothing of a singular surface obtained from an elliptic surface. By applying our methods to special Enriques surfaces, we construct new examples of a minimal surface of general type with ${p_g=0, \pi_1=\mathbb{Z}/2\mathbb{Z}}$ , and K ² ≤ 4.