三氧化钨/氧化银复合材料的水热法合成及其光催化降解性能研究

染料污染是水污染中最严重的问题之一,吸引了很多科学家的关注.人们尝试了很多方法去解决该问题,如化学氧化法、物理吸附法、光催化降解法和生物降解法等.与其他几种方法相比,光催化法有着低能耗、环保以及高效等优势.三氧化钨是常见的半导体材料,具有独特的光学性能,近年来受到了广泛的研究.本文以钨酸钠和硫脲为前驱体,通过水热法制备了三氧化钨/氧化银(WO_3/Ag_2O)复合材料,并用光催化降解亚甲基蓝来分析其光催化性能.通过X射线光电子能谱、X射线衍射、透射电子显微镜、扫描电子显微镜、紫外可见吸收光谱等表征手段对样品的形貌、晶格结构和光催化的性能进行表征.氧化银的带宽为1.2 e V,对可见光很敏感,三氧化钨和氧化银的复合使材料在可见光下的光催化活性显著增强,在可见光下对亚甲基蓝染料的光降解率可以达到98%.实验结果表明,复合材料中的三氧化钨纳米棒为六方相,其平均直径约为200 nm,平均长度约为4μm.而复合材料中的氧化银纳米颗粒为六方相,附着在氧化钨纳米棒的表面,平均晶粒尺寸为20 nm.氧化银的存在为复合材料提供了更多的反应活性位点.相较于单一组分,复合材料在可见光下的光吸收度更高,这说明三氧化钨和氧化银的复合改变了材料的能带结构.研究发现,三氧化钨和氧化银之间形成的异质结构是其优良光催化性能的来源.此外,三氧化钨和氧化银复合材料还具有良好的催化稳定性和化学稳定性.本文结果表明,可以通过给宽带隙的半导体材料复合一些带隙合适的金属氧化物以提升其光催化活性.     

锁频锁相的高功率微波器件技术研究

综述了中国工程物理研究院应用电子学研究所锁频锁相的高功率微波器件最新研究成果,主要包括稳频稳相的相对论速调管放大器和注入锁相的相对论返波管振荡器.针对高功率长脉冲相对论速调管研究中遇到的问题,介绍了该放大器的束波互作用特点、杂频振荡抑制、脉冲缩短、高频段高功率运行、高增益等物理、设计与实验中的关键技术研究概况,使其功率、相位稳定性、增益等性能有了显著提高,S波段环形单注相对论速调管实现了高功率稳相输出,重频25 Hz运行时输出功率大于1 GW,脉宽大于150 ns、相位波动18°,高增益运行时在注入微波功率数kW条件下也实现类似功率和相位水平;采用同轴多注器件结构,突破了速调管高频段运行条件下高效率电子束引入和高功率束波转换技术等难题,使X波段相对论速调管在注入功率30 kW条件下实现了功率大于1 GW的放大输出,效率为34%,相位波动为15°.在掌握相对论返波管技术的基础上,利用返波管的高效率和结构紧凑的优点,开展了注入调制电子束锁相的相对论返波管研究,采用百kW级的种子微波实现了对GW量级输出微波的相位锁定.该研究结果对功率合成、粒子加速和多功能雷达等技术具有重要的推动作用.     

Collective bands in 104,106,108Mo

We have used our analysis of γ-γ-γ data (5.7 × 10¹¹ triples and higher folds) taken with Gammasphere from prompt γ rays emitted in the spontaneous fission of ²⁵²Cf to study the collective bands in ^104,106,108Mo. The one-phonon and two-phonon γ-vibrational bands and known two-quasiparticle bands in neutron-rich ^104,106Mo were extended to higher spins. The one-and two-phonon γ-vibrational bands have remarkably close energies for transitions from the same spin states and identical moments of inertia. Several new bands are observed and are proposed as quasiparticle bands in ^104,106Mo, along with the first β-type vibrational band in ¹⁰⁶Mo. The quasiparticle bands have essentially constant moments of inertia near the rigid-body value that indicate blocking of the pairing interaction. Candidates for chiral doublet bands in ¹⁰⁶Mo are strong. These are the first reported chiral vibrational bands in an even-even nucleus. The text was submitted by the authors in English.     

高电荷态离子207Pbq+(24≤q≤36)与Si(110)固体表面作用的电子发射研究

报道了利用兰州重离子加速器国家实验室ECR源引出的高电荷态离子207Pbq+(24≤q≤36)入射到Si(110)表面产生的电子发射的实验测量结果.结果表明,高电荷态离子与固体表面相互作用产生的电子发射产额Y与入射离子的电荷态q、入射角度ψ和入射能量E都有很强的关联.首次发现,电子发射产额Y与入射角度ψ间有接近1/tanψ的关系.理论分析认为,这些过程与基于经典过垒模型的势能电子发射过程密切相关.     

980 nm激发下Er3+/Yb3+共掺杂ZrO2-Al2O3粉末的上转换发光特性

通过固相反应法制备了Er3+/Yb3+共掺杂ZrO2-Al2O3粉末的样品,并对样品在980nm激光激发下的上转换发光特性进行了研究.从发射光谱可以发现,在可见光范围内有3个强的发光带,一个位于654nm附近的红光带和两个分别位于545nm、525nm附近的绿光带,分别对应于Er3+离子的以下辐射跃迁:4F9/2→4I15/2、4S3/2→4I15/2、2H11/2→4I15/2.其中又以Er3+离子的4F9/2→4I15/2跃迁产生的红色荧光辐射最强.对其上转换发光机制进行了分析,发现这三个发光过程都是双光子过程.对样品粉末进行了XRD检测,发现ZrO2主要以立方相为主,并且计算得到了这种立方结构的晶格常数.Al2O3固溶于ZrO2中,Al3+嵌入ZrO2后产生氧空位,导致ZrO2晶体的对称性降低,这种结构变化更有利于提高上转换效率,即上转换发光强度增强.     

Space-selective co-precipitation of silver and gold nanoparticles in femtosecond laser pulses irradiated Ag, Au co-doped silicate glass

We report on space-selective co-precipitation of silver and gold nanoparticles in Ag⁺, Au³⁺ co-doped silicate glasses by irradiation of femtosecond laser pulses and subsequent annealing at high temperatures. The color of the irradiated area in the glass sample changed from yellow to red with the increase of the annealing temperature. The effects of average laser power and annealing temperature on precipitation of the nanoparticles were investigated. A reasonable mechanism was proposed to explain the observed phenomena.     

Effects of linear birefringence inside sensing head upon bulk glass current sensors’ sensitivity

The effects of the linear birefringence inside a bulk glass current sensing element and the incident polarizing angle upon the performance of a bulk glass optical current sensor are derived and analyzed theoretically. The investigation results show that the linear birefringence will modify the scale factor of the system with a sample function; it can also affect the extent of the influence of the incident polarizing angle, at the same time. When the incident polarizing angle has some special values such as 0, 45, or 90, its effect on the system will be zero. These results might provide some useful reference to the researchers and designers of bulk glass optical current sensors.     

Linear and nonlinear optical properties of ZnO nanorod arrays

Polarization-dependent linear absorption, second-harmonic generation （SHG） and 3rd-order nonlinearities of wellaligned ZnO nanorod arrays have been investigated with ps pulses. The depressed spectral width and the enhanced intensity of reflective SHG along the long axis of ZnO nanorods were observed by using p-polarized pulses, which is explained by the optical confinements. The nonlinear absorption coefficient measured with s-polarization reached the maximum 4.0×10^4cm/GW at the wavelength -750nm, which revealed a large two-photon resonance absorption attributed to the quantum confined exciton when the polarization is vertical to the long axis of ZnO nanorod.     

S波段相对论速调管振荡器研究

介绍利用20 GW加速器二极管产生的电子束源,开展S波段相对论速调管振荡器(RKO)的理论设计、粒子模拟和实验研究的情况.该RKO采用3个紧密耦合的圆柱腔作为振荡腔,束流经过一段漂移管的群聚后采用三轴输出腔提取微波.该振荡器具有起振时间快、结构紧凑、束波转换效率较高等优点.采用无箔空心阴极和0.9 T的恒流源磁场引出的电压1 MV、束流13kA、脉宽40 ns的环形电子束驱动RKO,单次运行输出了3.5 GW的辐射微波功率,效率27％,频率2.86 GHz,瞬时带宽2%;脉冲重复频率20 Hz运行时,输出 关键词： 相对论速调管 振荡器 三轴提取腔 高功率微波     

Study of radiation background at the north crossing point of the BEPCⅡ in collision mode

Understanding the radiation background at the north crossing point (NCP) in the tunnel of BEPCII is crucial for the performance safety of the High Purity Germanium (HPGe) detector, and in turn of great significance for long-term stable running of the energy measurement system. Therefore, as the first step, a NaI(Tl) detector is constructed to continuously measure the radiation level of photons as background for future experiments. Furthermore, gamma and neutron dosimeters are utilized to explore the radiation distribution in the vicinity of the NCP where the HPGe detector will be located. Synthesizing all obtained information, the shielding for neutron irradiation is studied based on model-dependent theoretical analysis.