Synthesis and evaluation of substituted indolizidines as peptidomimetics of RGD tripeptide sequence

The synthesis of seven peptidomimetics of RGD is presented. The indolizidine building block was obtained by condensation of allylglycine with dimethoxydihydrofuran followed by an intermolecular cyclization. The bicyclic ring was functionalised with a carboxylic acid and a guanidinium appendage. The seven peptidomimetics were evaluated by cell-adhesion assays.     

Antihydrogen formation via antiproton scattering on positronium between the $e^{-} +\bar {H}(n = 2)$ and e−+H̄(n=3)$e^{-}+\bar {H}(n = 3)$ thresholds

The charge exchange reaction \(\bar {\mathrm {p}} + \text {Ps} \rightarrow \mathrm {e}^{-} + \bar {\mathrm {H}} \), of interest for the future experiments (GBAR, AEGIS, ATRAP, ...) aiming to produce antihydrogen atoms, is investigated in the energy range between the \(\mathrm {e}^{-}+\bar {\mathrm {H}}(n = 2)\) and \(\mathrm {e}^{-}+\bar {\mathrm {H}}(n = 3)\) thresholds. An ab-initio method based on the solution of the Faddeev-Merkuriev equations is used. Special focus is put on the impact of the Feshbach resonances and the Gailitis-Damburg oscillations, appearing in the vicinity of the \(\bar {\mathrm {p}} +\text {Ps}(n = 2)\) threshold, on the \(\bar {\mathrm {H}}\) production cross section.     

A measurement of K1 (1420) decay branching ratios

The decay branching ratios of K¹⁰ (1420) into K⁺π^?, K⁰π⁺π^? and K¹⁺(892) π^? are measured in the charge exchange reaction $\text{K}{}^{\mathrm{+}}\text{d}\text{→}\text{K}{}^{10}\text{(1420)}\text{pp}{}_{\mathrm{S}}$ using data from a K⁺d bubble chamber experiment at 4.6 GeV/c incident momentum. For the branching ratio $\text{(}\text{K}{}^1\text{(1420) →}\text{K}{}^1\text{(892)π)/(}\text{K}{}^1\text{(1420) →}\text{K}\text{π)}\text{a value of}\text{(0.54 ± 0.16)}$ is obtained. The results are compared with previous measurements.     

Anneal temperature dependence of Si/SiO2 superlattices photoluminescence

Photoluminescence spectroscopy, Fourier transform infrared spectroscopy, X-ray reflectometry and high resolution electron microscopy have been used to interpret the photoluminescence properties of annealed (3/19 nm) Si/SiO₂ multilayers grown by reactive magnetron sputtering. The multilayers show an emission in the visible and near-infrared range after heat treatment from 900°C which tends to decrease from 1200°C. Three different origins for the photoluminescence activity have been found. An anneal temperature of 1200°C is necessary to optimise the silicon crystallisation within the silicon sublayers.     

Electron distribution of small Ni particles and Ce ions in X and Y zeolites related to their catalytic properties

Catalytic behaviour of nickel particles smaller than 1.3 nm, encaged in X and Y zeolites, in the presence of Ce³⁺, is related to their electronic properties. In general the rates of reaction are lower than those of a standard catalyst made of 2.5 nm nickel particles on SiO₂; this is attributed to the strong localization of the Ni 3d states due to the size effect. However a high rate, more than twice the standard, is found for Ni in X zeolite, in relation with a Ni 3d ¹⁰ configuration. On the other hand the fragmentation of butane is deeper with Ni in Y support than in X support and this corresponds to a high density of Nid states at the Fermi level.     

Atomic and chemical effects in Sm and Sm2O3 photoelectron spectra

We present here a comparative study of Sm and Sm₂O₃ photoelectron spectra. They are well interpreted by atomic effects, except the Sm₂O₃ d spectra which exhibit chemical effects.     

Intercomparison of simultaneously obtained infrared (4.8 microm) and visible (515-715 nm) ozone spectra using ACE-FTS and MAESTRO

Laboratory ozone absorption spectra were measured simultaneously in the visible (515-715 nm) and infrared (2070-2140 cm(-1)) spectral regions using SCISAT-1's MAESTRO (Measurement of Aerosol Extinction in the Stratosphere and Troposphere Retrieved by Occultation) and ACE-FTS (Atmospheric Chemistry Experiment-Fourier Transform Spectrometer) spectrometers. An intercomparison of these measurements was used to assess the relative accuracy of HITRAN absolute line strengths, for which there was a 4% change between the 2000 and 2004 versions. Results reported here show that Chappuis band cross section strengths are more consistent with the HITRAN 2004 4.8 microm band line strengths than with the 2000 compilation.