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11.
12.
Amylopectin tris(phenylcarbamate) has been evaluated as a chiral stationary phase for HPLC; the influence on its cptical resolving capabilities of mobile phase composition and nature of the alcohol used as modifier has been studied. Separation and resolution of twelve arylalcohol racemates were examined. In most instances, the stationary phase exhibited high optical resolving capacity. 相似文献
13.
Amotz Bar-Noy Guy Kortsarz 《Journal of Algorithms in Cognition, Informatics and Logic》1998,28(2):339-365
The problem ofminimum color sumof a graph is to color the vertices of the graph such that the sum (average) of all assigned colors is minimum. Recently it was shown that in general graphs this problem cannot be approximated withinn1 − ε, for any ε > 0, unlessNP = ZPP(Bar-Noyet al., Information and Computation140(1998), 183–202). In the same paper, a 9/8-approximation algorithm was presented for bipartite graphs. The hardness question for this problem on bipartite graphs was left open. In this paper we show that the minimum color sum problem for bipartite graphs admits no polynomial approximation scheme, unlessP = NP. The proof is byL-reducing the problem of finding the maximum independent set in a graph whose maximum degree is four to this problem. This result indicates clearly that the minimum color sum problem is much harder than the traditional coloring problem, which is trivially solvable in bipartite graphs. As for the approximation ratio, we make a further step toward finding the precise threshold. We present a polynomial 10/9-approximation algorithm. Our algorithm uses a flow procedure in addition to the maximum independent set procedure used in previous solutions. 相似文献
14.
15.
J. Ramier L. Chazeau C. Gauthier L. Guy M. N. Bouchereau 《Journal of Polymer Science.Polymer Physics》2006,44(1):143-152
The treatment of nanoscopic silica grafted in the blend during the processing of silica‐filled styrene butadiene rubber was performed with silane, introduced at different concentrations, or at a constant concentration with a given length of alkyl chain. From swelling measurements in water and in solvent, the maximum silane content that can be grafted has been calculated as a function of the length of the silane alkyl chains as well as their efficiency to cover the silica surface. The found values are close to the values found in the literature for grafting in solution. Moreover, a direct correspondence between the length of the silane alkyl chains and their concentration has been deduced. © 2005 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 44: 143–152, 2006 相似文献
16.
Juray De Wilde Denis Constales Geraldine J. Heynderickx Guy B. Marin 《International Journal of Multiphase Flow》2007
The propagation speeds of linear waves in gas–solid suspensions depend strongly on the solids volume fraction and the wave frequency. The latter is due to gas–solid momentum transfer and allows a simple test on filtered gas–solid momentum transfer models. Such models may predict linear wave propagation speeds different from those obtained with the non-filtered model at wave frequencies higher than the filter frequency, but not at wave frequencies lower than the filter frequency. 相似文献
17.
For about thirty years, time series models with time-dependent coefficients have sometimes been considered as an alternative
to models with constant coefficients or non-linear models. Analysis based on models with time-dependent models has long suffered
from the absence of an asymptotic theory except in very special cases. The purpose of this paper is to provide such a theory
without using a locally stationary spectral representation and time rescaling. We consider autoregressive-moving average (ARMA)
models with time-dependent coefficients and a heteroscedastic innovation process. The coefficients and the innovation variance
are deterministic functions of time which depend on a finite number of parameters. These parameters are estimated by maximising
the Gaussian likelihood function. Deriving conditions for consistency and asymptotic normality and obtaining the asymptotic
covariance matrix are done using some assumptions on the functions of time in order to attenuate non-stationarity, mild assumptions
for the distribution of the innovations, and also a kind of mixing condition. Theorems from the theory of martingales and
mixtingales are used. Some simulation results are given and both theoretical and practical examples are treated.
Received 2004; Final version 23 December 2004 相似文献
18.
A simple and quite general approach is proposed to derive criteria for transience and ergodicity of a certain class of irreducibleN-dimensional Markov chains in
+
N
assuming a boundedness condition on the second moment of the jumps. The method consists in constructing convenient smooth supermartingales outside some compact set. The Lyapounov functions introduced belong to the set of quadratic forms in
+
N
and do not always have a definite sign. Existence and construction of these forms is shown to be basically equivalent to finding vectors satisfying a system of linear inequalities.Part I is restricted toN=2, in which case a complete characterization is obtained for the type of random walks analyzed by Malyshev and Mensikov, thus relaxing their condition of boundedness of the jumps. The motivation for this work is partly from a large class of queueing systems that give rise to random walks in
+
N
相似文献
19.
E. Matsinos J. Guy E. Simopoulou W. Venus P. Allport M. Berggren M. Calicchio T. Coghen A. M. Cooper-Sarkar O. Erriquez N. Giannakopoulos G. T. Jones P. Marage M. M. Mobayyen D. R. O. Morrison S. O'Neale M. A. Parker J. Sacton R. A. Sansum N. Schmitz G. W. Van Apeldoorn K. Varvell A. Vayaki H. Wachsmuth W. Wittek BEBC WA Collaboration 《Zeitschrift fur Physik C Particles and Fields》1989,44(1):79-87
Backward proton and pion production is studied in ν and \(\bar v\) charged current interactions in neon. The results are compared with other experiments and theory. The complete backward proton data is compatible with protons produced by reinteractions in the nucleus. However in events with only one proton, muon variables appear correlated to those for the backward proton, as expected by the two-nucleon correlation model. 相似文献
20.
Sabbe MK Saeys M Reyniers MF Marin GB Van Speybroeck V Waroquier M 《The journal of physical chemistry. A》2005,109(33):7466-7480
A complete and consistent set of 95 Benson group additive values (GAV) for the standard enthalpy of formation of hydrocarbons and hydrocarbon radicals at 298 K and 1 bar is derived from an extensive and accurate database of 233 ab initio standard enthalpies of formation, calculated at the CBS-QB3 level of theory. The accuracy of the database was further improved by adding newly determined bond additive corrections (BAC) to the CBS-QB3 enthalpies. The mean absolute deviation (MAD) for a training set of 51 hydrocarbons is better than 2 kJ mol(-1). GAVs for 16 hydrocarbon groups, i.e., C(C(d))(3)(C), C-(C(d))(4), C-(C(t))(C(d))(C)(2), C-(C(t))(C(d))(2)(C), C-(C(t))(C(d))(3), C-(C(t))(2)(C)(2), C-(C(t))(2)(C(d))(C), C-(C(t))(2)(C(d))(2), C-(C(t))(3)(C), C-(C(t))(3)(C(d)), C-(C(t))(4), C-(C(b))(C(d))(C)(H), C-(C(b))(C(t))(H)(2), C-(C(b))(C(t))(C)(H), C-(C(b))(C(t))(C)(2), C(d)-(C(b))(C(t)), for 25 hydrocarbon radical groups, and several ring strain corrections (RSC) are determined for the first time. The new parameters significantly extend the applicability of Benson's group additivity method. The extensive database allowed an evaluation of previously proposed methods to account for non-next-nearest neighbor interactions (NNI). Here, a novel consistent scheme is proposed to account for NNIs in radicals. In addition, hydrogen bond increments (HBI) are determined for the calculation of radical standard enthalpies of formation. In particular for resonance stabilized radicals, the HBI method provides an improvement over Benson's group additivity method. 相似文献