Windmill polynomials over fields of characteristic two

Chambers andSmeets [3] have designed a windmill arrangement of linear feedback shift registers (LFSRs) to generate pn-sequences overGF(2) with high speed. When the windmill hasv vanes, the associated minimal feedback polynomial (having degreen, relatively prime tov) can be taken to have the shapef ₁(x ^v )+x ⁿ f ₂(x ^–v ), where the polynomialsf ₁ andf ₂ have degree [n/v]. Their numerical evidence, whenv is divisible by 4, suggests that, surprisingly, there areno such windmill polynomials which are irreducible ifn±3 (mod 8), while about twice as many irreducible and primitive windmill polynomials as they expected occur ifn±1 (mod 8). A discussion of this behaviour is presented here with proofs. The brief explanation is that the Galois group of the underlying generic windmill polynomial overGF (4) is equal to the alternating groupA _n .     

Backward particle production in neutrino neon interactions

Backward proton and pion production is studied in ν and \(\bar v\) charged current interactions in neon. The results are compared with other experiments and theory. The complete backward proton data is compatible with protons produced by reinteractions in the nucleus. However in events with only one proton, muon variables appear correlated to those for the backward proton, as expected by the two-nucleon correlation model.     

Group additive values for the gas phase standard enthalpy of formation of hydrocarbons and hydrocarbon radicals

A complete and consistent set of 95 Benson group additive values (GAV) for the standard enthalpy of formation of hydrocarbons and hydrocarbon radicals at 298 K and 1 bar is derived from an extensive and accurate database of 233 ab initio standard enthalpies of formation, calculated at the CBS-QB3 level of theory. The accuracy of the database was further improved by adding newly determined bond additive corrections (BAC) to the CBS-QB3 enthalpies. The mean absolute deviation (MAD) for a training set of 51 hydrocarbons is better than 2 kJ mol(-1). GAVs for 16 hydrocarbon groups, i.e., C(C(d))(3)(C), C-(C(d))(4), C-(C(t))(C(d))(C)(2), C-(C(t))(C(d))(2)(C), C-(C(t))(C(d))(3), C-(C(t))(2)(C)(2), C-(C(t))(2)(C(d))(C), C-(C(t))(2)(C(d))(2), C-(C(t))(3)(C), C-(C(t))(3)(C(d)), C-(C(t))(4), C-(C(b))(C(d))(C)(H), C-(C(b))(C(t))(H)(2), C-(C(b))(C(t))(C)(H), C-(C(b))(C(t))(C)(2), C(d)-(C(b))(C(t)), for 25 hydrocarbon radical groups, and several ring strain corrections (RSC) are determined for the first time. The new parameters significantly extend the applicability of Benson's group additivity method. The extensive database allowed an evaluation of previously proposed methods to account for non-next-nearest neighbor interactions (NNI). Here, a novel consistent scheme is proposed to account for NNIs in radicals. In addition, hydrogen bond increments (HBI) are determined for the calculation of radical standard enthalpies of formation. In particular for resonance stabilized radicals, the HBI method provides an improvement over Benson's group additivity method.     

A reliable two-dimensional gel electrophoresis procedure for separating neural proteins

A facile two-dimensional gel electrophoresis procedure has been developed for the analysis of neural tissue proteins which eliminates the serious problems associated with protein insolubility at the point of sample application onto polymerized first-dimension isoelectric focusing gels. This was accomplished by combining the methods of two previously published procedures. Our procedure provides an alternative method to the complex gel systems often employed for less soluble proteins, and yields very reproducible, high resolution separations. This procedure, which is in routine use in our laboratories for the analysis of total proteins extracted from retina and brain, produces protein patterns that are easily compared using both visual and computer-assisted image analysis techniques. Presented here are the results of a set of experiments designed to identify proteins unique to retina. This procedure should be useful to investigators studying protein changes resulting from genetic mutation, development, drug treatment or disease, in neural tissue as well as in virtually all other tissues.     

The mechanism of photoinduced acylation of amines by N-acyl-5,7-dinitroindoline as determined by time-resolved infrared spectroscopy

[reaction: see text] The photochemistry of N-acyl-5,7-dinitroindoline (1) was studied in acetonitrile using nanosecond time-resolved infrared (TRIR) spectroscopy. Upon photolysis, two nearly but not completely overlapping sets of transient IR bands are observed that are assigned to two non-interconvertible conformers of mixed acetic nitronic anhydride 7. While syn-7 reverts rapidly to 1, anti-7 is long-lived and is able to acylate amines. Results of density functional theory calculations support conclusions based on experimental TRIR data.     

Aluminium(III) as a promoter of cellular oxidation

Aluminium has been known as a neurotoxic agent to experimental animals since the last century (Arch. Exp. Pharmacol. 40 (1897) 98). However, great interest arose in it bioinorganic chemistry as well biology when it was demonstrated to be the causative agent in pathologies related to the long-term dialysis treatment of uremic subjects with renal failure (Life Chem. 11 (1994) 197), and as a potential etiopathogenic cofactor for several neurodegenerative diseases. The inorganic biochemistry of aluminium is still largely to be discovered. In this review the pro-oxidative property of aluminium toward biological membrane will be presented and its implications in involvement in human pathology will be discussed in an interdisciplinary frame from the bioinorganic point of view.     

Analyse de couches minces de verres chalcogenures par diffusion elastique de protons et mesure de gammas prompts

Résumé Une méthode d'étude de la composition stoéchiométrique de couches minces (10 à 500 μg/cm²) de verres chalcogénures est développée. L'étude des réactions nucléaire; induites par bombardement de protons de basse énergie (<4 MeV) sur les éléments constitutifs Ge, As, Te et S, conduit à choisir la diffusion élastique et la détection de gammas prompts pour le dosage simulatené. La précision et la sensibilité de la méthode sont discutées à partir des résultats obtenus. L'utilisation de la résonance fine sur le soufre (p, p'γ) est appliquée à l'étude de l'homogénéité des cibles.