The fibre track detector

The new type of a solid state track detector is described. The detector consists of the fibre or capillary target and the multistage image intensifier. The standard microchannel plate filled with liquid scintillator and the input fibre plate of the image intensifier was investigated as the targets.     

Thermal electron capture in organic compound-carbon dioxide gas mixtures

The rates of free thermal electron capture were measured depending on the buffer gas (CO₂) pressure for 15 organic compounds in an ionization chamber with laser cathode photoionization. Procedures for preparing the tested gas mixtures and experimental data processing are described.     

Parametric generation of low-frequency waves by plasma electrons accelerated under electron cyclotron resonance conditions

It has been shown experimentally that the diamagnetic effect appearing when electrons of a magnetized plasma in the antenna near field are accelerated under electron cyclotron resonance conditions can be used to generate low-frequency waves. The amplitude modulation of a signal supplied to the antenna is accompanied by the modulation of the diamagnetic effect and leads to the emission of waves at the modulation frequency to the surrounding plasma. In this process, the extended plasma region containing accelerated electrons serves as a parametric bodiless antenna. The results of the model laboratory experiments make it possible to propose a method for the parametric generation of low-frequency whistler waves in the Earth’s ionosphere by a powerful amplitude-modulated signal supplied to the satellite-borne antenna.     

A Novel Niobium Cluster Aqua Ion with Capping μ4‐Se Ligand

The aqueous solution chemistry of niobium is underexplored, and well characterized aqua complexes are scarce. In this contribution, a new niobium aqua complex was obtained by treatment of Zn‐reduced ethanolic solution of NbCl₅ with HCl in the presence of a selenide source (ZnSe). This is the first example of selenium containing aqua complex of niobium. The yellow‐green aqua complex was isolated by cation‐exchange chromatography and transformed into corresponding isothiocyanate complex by ligand exchange, which was crystallized as (PyH)_4.5[H_1.5Nb₄SeO₅(NCS)₁₀] · 0.5H₂O. X‐ray structural analysis revealed a metal‐metal bonded tetranuclear {Nb₄(μ₄‐Se)(μ₂‐O)₅}⁴⁺ core with a capping μ₄‐Se ligand.     

The Destruction of Carbon Tetrachloride Dissolved in Water in a Dielectric Barrier Discharge in Oxygen

The kinetics of decomposition of tetrachloromethane (TCM) in its aqueous solutions and the kinetics of decomposition products formation was investigated under the action of DBD at atmospheric pressure in oxygen in a falling-flow reactor. The range of initial concentrations of TCM was 25–325 μmol/l, the discharge power—2–11 W and O₂ flow rates—1–3 cm³/s. It is shown that the kinetics of the TCM decomposition can be described by the equation of pseudo-first kinetic order. The rate constant depended weakly on the discharge parameters and was?~?5 s^?1. The energy efficiency of the decomposition, depending on the parameters, was 0.1–1.3 molecules per 100 eV. When the residence time of the solution with the discharge zone is more than 1 s, it is possible to achieve almost 100% degree of TCM decomposition. It is shown that the main products of the TCM decomposition in the liquid phase are aldehydes and Cl^? ions, and in the gas phase—the molecules CO and CO₂. The results for energy efficiency are compared with the results obtained in other AOP’s processes (Fenton process, photocatalytic process, the radiation process by the action of high-energy electron flux). It is shown that the action of the DBD is more effective than the action of the above processes.

     

Use of electromagnetically induced transparency for measurement of superhyperfine splitting of the levels of rare-earth metals doped in optical crystals

The results of experimental and theoretical investigations of the electromagnetically induced transparency regime on the ⁴ I _9/2-⁴ G _5/2 transition in Nd³⁺ ions doped in LaF₃ are presented. The superhyperfine splitting of the upper and lower working levels has been determined on the basis of the results obtained. A theoretical model adequately describing the parameters of the resonances of electromagnetically induced transparency has been developed by analyzing the experimental data.