Phase diagrams of decomposing nanoalloys

The thermodynamics of nucleation and decomposition in small isolated particles are considered. There exist three possibilities: phase separation, prohibition of decomposition and a metastable state. We investigate the peculiarities of phase diagrams related to depletion of the nanosize parent phase even at the nucleation stage. For small particles the equilibrium diagram becomes split (and shifted and size dependent). Concentration, size and temperature hystereses take place. Size-dependent ‘critical supersaturation’, increasing with decreasing size, has been analysed.     

Model of phase separation and of morphology evolution in two-phase alloy

Elementary theory of mass-transfer in two-phase alloy under electromigration with account of two competing mechanisms of the fluxes equilibration is presented. These two competing mechanisms are Kirkendall effect and backstress. Various versions of Monte Carlo models for simultaneous simulation of structure evolution kinetics and of mass-transfer kinetics under high-density current are presented. Possibility of self-organization with minimization of Joule heating is demonstrated.     

In situ investigation of dye adsorption on TiO2 films using a quartz crystal microbalance with a dissipation technique

Dye adsorption plays a crucial role in dye-sensitized solar cells. Herein, we demonstrate an in situ liquid-phase analytical technique to quantify in real time adsorption of dye and coadsorbates on flat and mesoporous TiO(2) films. For the first time, a molar ratio of co-adsorbed Y123 and chenodeoxycholic acid has been measured.     

A model of a reinforced tyre with a rod protector

A tyre design consisting of a steel-cord-reinforced rigid bond with sides connected to the wheel disc and a protector(tread) in contact with the road is examined. The tread is in the form of a set of rods connected by one end to the band, with the other end either free or in contact with the road. The rod end in contact with the road is acted upon by a force applied from the road, represented by a force normal to the road plane and a shear force due to dry friction. If the modulus of the shear force does not exceed the magnitude of the normal force multiplied by the dry friction coefficient, there is no slip at the contact point. In the opposite case, the rod end will be displaced along the road by an amount sufficient to distribute the normal and shear forces. The dynamics of longitudinal and transverse strains of the rods in contact with the road is analysed using the motion separation method in the quasi-static approximation. The behaviour of the tread rods as a function of the vertical displacement of the wheel centre is investigated, the contact area is found and the conditions are determined under which the contact area is divided into parts in which either slip of the rod ends occurs or does not occur, depending on the magnitude of the longitudinal displacement of the wheel centre or its turning relative to the horizontal axis. An analogue of a continuous model of a rod-like tread is considered, and the magnitudes of the forces and moments are found as a function of the wheel disc displacements. The equations of wheel rolling are obtained, and the conditions under which steady motions exist are found.