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991.
Raj K Gupta 《Pramana》2001,57(2-3):481-492
The quantum mechanical fragmentation theory (QMFT), given for the cold synthesis of new and superheavy elements, is reviewed
and the use of radioactive nuclear beams (RNB) and targets (RNT) is discussed. The QMFT is a complete theory of cold nuclear
phenomena, namely, the cold fission, cold fusion and cluster radioactivity. Also, the structure calculations based on the
axially deformed relativistic mean field (DRMF) approach are presented which predict new regions of spherical magicity, namely
Z=120 and N=172 or 184, for superheavy nuclei. This result is discussed in the light of recent experiments reporting the cold synthesis
of Z=118 element. 相似文献
992.
Dhruba Gupta C Samanta R Kanungo P Basu Subinit Roy S Kailas A Chatterjee B J Roy K Mahata A Samant A Shrivastava 《Pramana》2001,57(1):209-213
Inclusive cross sections of α particles and tritons from the breakup of 42 MeV 7Li by 12C and 197Au targets are presented and analysed in the framework of the Serber model. Spectral distortions due to the targets and relevant
reaction mechanisms are discussed. 相似文献
993.
994.
Necessary and sufficient conditions are specified for a group of a specified type to be generated by its given elements (F is a free product). Using these conditions (and relying essentially on the Shmel'kin embedding), we establish the criterion of being primitive for metabelian products of Abelian groups. A result by Birman and the primitivity criterion for free metabelian groups are generalized. 相似文献
995.
2‐Thioxo‐5,7‐dimethylpyrido[2,3‐d]pyrimidin‐4(3H)‐ones 3 were synthesized by the cyclocondensation of 2‐amino‐3‐carbethoxy‐4,6‐dimethylpyridine 1 with methyl‐N‐aryldithiocarbamates 2 and compared with the condensation between 1 and aryl isothiocyanates 4. When a comparative study of N vs S alkylation of ambident 2‐thioxo‐5,7‐dimethylpyrido[2,3‐d]pyrimidin‐4(3H)‐ones 3 was carried out under liquid‐liquid and solid‐liquid phase transfer conditions using various alkylating agents 5 , the S‐alkylated products 6 were obtained exclusively and selectively. 相似文献
996.
Henry's constants of n-alkanols (methanol to n-hexanol) in water were measured at temperatures between 40°C and 90°C using a recently developed headspace gas chromatographic technique. The data were in good agreement with literature data when available. The consistency of the data was verified by comparing calculated partial molar enthalpies with calorimetric values. The temperature dependence of dimensionless Henry's constants was fitted with the classical van't Hoff equation and an empirical correlation was established for the dimensionless Henry's constants as a function of temperature and number of carbon atoms in the n-alkanol. 相似文献
997.
4‐Hydrazino‐7H‐pyrrolo[2,3‐d]pyrimidines ( 4 ) were cyclocondensed with formic acid or triethyl orthoformate to give 7H‐1,2,4‐triazolo[1,5‐c]pyrrolo[3,2‐e]pyrimidines ( 5 ) and 7H‐1,2,4‐triazolo[4,3‐c]pyrrolo‐[3,2‐e]pyrimidines ( 6 ) respectively. The [4,3‐c]‐isomers ( 6 ) were rearranged into thermodynamically more stable [1,5‐c]‐isomers ( 5 ). The identical compounds ( 5 ) were prepared using another route by reacting 3‐amino‐4‐imino‐7H‐pyrrolo[2,3‐d]pyrimidines ( 3 ) with formic acid or triethylorthoformate. Reaction of 2‐amino‐3‐cyanopyrroles ( 1 ) with triethyl orthoformate followed by hydrazinolysis afforded ( 3 ) via the formation of N‐ethoxymethylene‐2‐amino‐3‐cyanopyrroles ( 2 ). 相似文献
998.
We study finite difference schemes to approximate the first initial-boundary value problem for linear second order parabolic equations and obtain some convergence rate estimates. When difference schemes are constructed for such problems, in the process of obtaining convergence rate estimates compatible with smoothness of the solution, various authors assume that the solution of the problem can be extended to the exterior of the domain of integration, preserving the Sobolev class. Our investigations show that this restriction can be removed if, instead of using the exact initial condition, we use certain approximations of the initial conditions. (© 2008 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim) 相似文献
999.
Influence of electron‐beam (e‐beam) irradiation on multi‐walled (MW) and single‐walled (SW) carbon nanotube films grown by microwave chemical vapor deposition technique is investigated. These films were subjected to an e‐beam energy of 50 keV from a scanning electron microscope for 2.5, 5.5, 8.0, and 15 h, and to 100 and 200 keV from a transmission electron microscope for a few minutes to ∼2 h continuously. Such conditions resemble an increased temperature and pressure regime enabling a degree of structural fluidity. To assess structural modifications, they were analyzed prior to and after irradiation using resonance Raman spectroscopy (RRS) in addition to in situ monitoring by electron microscopy. The experiments showed that with extended exposures, both types of nanotubes displayed various local structural instabilities including pinching, graphitization/amorphization, and formation of an intramolecular junction (IMJ) within the area of electron beam focus possibly through amorphous carbon aggregates. RRS revealed that irradiation generated defects in the lattice as quantified through (1) variation of the intensity of radial breathing mode (RBM), (2) intensity ratio of D to G band (ID/IG), and (3) positions of the D and G bands and their harmonics (D* and G*) and combination bands (D + G). The increase in the defect‐induced D band intensity, quenching of RBM intensity, and only a slight increase in G band intensity are some of the implications. The MW nanotubes tend to reach a state of saturation for prolonged exposures, while the SW ones transform from a semiconducting to a quasi‐metallic character. Softening of the q = 0 selection rule is suggested as a possible reason to explain these results. Furthermore, these studies provide a contrasting comparison between MW and SW nanotubes. Copyright © 2006 John Wiley & Sons, Ltd. 相似文献
1000.
A short‐range force constant model has been applied to investigate the Raman and the infrared wavenumbers in R2BaNiO5 (R = Y, Gd) in their orthorhombic phase of space group Immm. Calculations of zone‐center phonons are made with seven stretching and four bending force constants. The force constants are evaluated by fitting nine Raman and two infrared modes. Two Raman modes are reassigned on the basis of group theoretical calculations. The calculated Raman and infrared modes show good agreement with the observed values. The infrared values are assigned for the first time in these oxides. Copyright © 2006 John Wiley & Sons, Ltd. 相似文献