Optimum design and sensitivity analysis of piezoelectric truss structures

This paper is concerned with the optimum design and sensitivity analysis methods of piezoelectric intelligent trusses on the structural stiffness and free-vibration frequency. On the basis of the finite element method and taking into account the mechanical-electric coupling effect under electric load and mechanical load, the computational formula of sensitivities of structural displacement and free-vibration frequency with respect to the size and shape design variables are proposed. A new kind of design variable of the electric voltage and the calculating method of displacement sensitivity with respect to the electric voltage variable is presented. The new method for structural deformation control by optimizing the voltages of piezoelectric active bars is given. The numerical methods of optimum design and sensitivity analysis for piezoelectric truss structures are implemented in JIFEX software. Numerical examples demonstrate the effectiveness of the methods and the program. Project supported by the Special Funds for National Key Basic Research of China (No. G1999032805) and the Foundation for University Key Teachers by the Ministry of Education of China.     

Boltzmann-Poisson系统解的动量及能量估计

In this paper, the properties of the solutions of Boltzmann-Poisson system in three dimensions are considered. The estimates of the energies (the kinetic and the potential energies) and the γ-th moments with γ∈[2,3) are obtained. The latter answers an open problem.     

钼硫碘纳米线结构特性和化学改性的理论研究

 采用第一性原理密度泛函理论研究了纳米线结构的钼硫碘材料. 结构的理论模拟结果显示, 钼硫碘纳米线机械性能很高, 且其形变过程中显示出一种特殊的磁滞现象. 形成能、投影态密度以及电荷密度的计算结果显示, 使用电负性接近硫的碳元素可对钼硫碘纳米线化学改性同时不失去其良好的结构性能和电子性能. 该结果为化学改性钼硫碘纳米线材料应用于催化提供了依据. 这些钼硫碘纳米线材料将在纳米电子学、纳米机械学、催化、纳米限域等研究中有潜在应用.     

Solvothermal synthesis, cubic structure and multicolor upconversion emission of ultrasmall monodisperse lanthanide-doped BaYF5 nanocrystals

Lanthanide (Ln³⁺) doped BaYF₅ (Ln=Yb³⁺, Er³⁺, Tm³⁺) nanocrystals (NCs) with a mean size of approximately 10 nm are synthesized by a solvothermal method using oleic acid as a stabilizing agent at 210 °C. The size of BaYF₅ NCs can be controlled by simply tuning the reaction parameters such as reaction temperature, reaction time and the molar ratio of F⁻/Y³⁺. The detailed structure investigation reveals that the as-synthesized BaYF₅ NCs are in the cubic structure with space group Fm3¯m instead of the reported tetragonal structure. Ln³⁺ cations occupy crystal lattice positions with lower point symmetry, which may lead to high upconversion efficiency under the excitation of a 980 nm diode laser. By adjusting the dopant concentrations of Yb³⁺, Er³⁺ and Tm³⁺, intense near-infrared, blue, yellow and white upconversion emissions are readily realized, respectively. The desirable property of the ultrasmall monodisperse NCs makes it the promising material for the applications in miniaturized solid-state light sources, multicolor three-dimensional display devices and fluorescent labels for biomedicine imaging.     

热结构稳态响应的耦合灵敏度分析方法

研究结构稳态热变形和热应力的灵敏度分析方法，给出了直接法和伴随法两种算法。考虑了温度场的耦合作用，在直接法中需要计算温度场对设计变量的导数，在伴随法中需要计算热载荷对温度场的导数。对尺寸和形状两类设计变量的灵敏度分析算例，验证了本文方法的精度。伴随法在应用程序中的实现，为大型结构优化提供了高效率的灵敏度计算方法。     

GPS技术在金川露天矿边坡变形监测中的应用

本文结合金川露天矿边坡变形GPS监测研究，主要论述监测基点的选择，基点WGS-84坐标的确定，变形监测网的布设，GPS数据采集、处理和质量，坐标转换的实施等，给出反演推出的若干四等三角点及其它控制点的变形数据，这些数据和造成变形的物理成因符合得很好，最后概括出GPS技术应用于变形观测的若干优点。     

Mesoporous Carbon Nanofibers Embedded with MoS2 Nanocrystals for Extraordinary Li‐Ion Storage

MoS₂ nanocrystals embedded in mesoporous carbon nanofibers are synthesized through an electrospinning process followed by calcination. The resultant nanofibers are 100–150 nm in diameter and constructed from MoS₂ nanocrystals with a lateral diameter of around 7 nm with specific surface areas of 135.9 m² g^?1. The MoS₂@C nanofibers are treated at 450 °C in H₂ and comparison samples annealed at 800 °C in N₂. The heat treatments are designed to achieve good crystallinity and desired mesoporous microstructure, resulting in enhanced electrochemical performance. The small amount of oxygen in the nanofibers annealed in H₂ contributes to obtaining a lower internal resistance, and thus, improving the conductivity. The results show that the nanofibers obtained at 450 °C in H₂ deliver an extraordinary capacity of 1022 mA h g^?1 and improved cyclic stability, with only 2.3 % capacity loss after 165 cycles at a current density of 100 mA g^?1, as well as an outstanding rate capability. The greatly improved kinetics and cycling stability of the mesoporous MoS₂@C nanofibers can be attributed to the crosslinked conductive carbon nanofibers, the large specific surface area, the good crystallinity of MoS₂, and the robust mesoporous microstructure. The resulting nanofiber electrodes, with short mass‐ and charge‐transport pathways, improved electrical conductivity, and large contact area exposed to electrolyte, permitting fast diffusional flux of Li ions, explains the improved kinetics of the interfacial charge‐transfer reaction and the diffusivity of the MoS₂@C mesoporous nanofibers. It is believed that the integration of MoS₂ nanocrystals and mesoporous carbon nanofibers may have a synergistic effect, giving a promising anode, and widening the applicability range into high performance and mass production in the Li‐ion battery market.     

Theo-chlorotoluene photodissociation at 266 nm

Based on theab initio calculation results, the hydrogen atom transfer has been investigated. In order to explain the experimental results, a new mechanism is proposed, that is, hydrogen transfer occurs before but not after CI atom eliminates from aromatic ring. The calculation result strongly supports this mechanism.     

纳米MgTi2O5的制备

纳米ＭｇＴｉ_２Ｏ_５的制备彭子飞，冯贵武，汪国忠，田兴友，张伟，张立德（中国科学院固体物理研究所合肥２３００３１，安徽大学化学系合肥）关键词ＭｇＴｉ_２Ｏ_５，纳米材料，制备，共沉淀钛酸镁是高频低介电常数的电容陶瓷材料，以往合成ＭｇＴｉ２Ｏ５的方法都采...