Ultra-high molecular weight polyethylene (UHMWPE) fibrous adsorbents with different molar content of amidoxime (MAO) and acrylic acid (MAA) were prepared by graft polymerization of acrylonitrile (AN) and acrylic acid (AA), followed by amidoximation. Uranium adsorption experiments in both artificial and natural seawater were carried out to investigate the effect of MAO and MAA on the uranium adsorption capacity of UHMWPE fibrous adsorbents. Adsorption results showed that the UHMWPE fibrous adsorbent with MAO = 4.27 and MAA = 4.64 mmol/g-ads exhibited better uranium adsorption capacity in both artificial (7.01 mg-U/g-ads) and natural (0.77 mg-U/g-ads) seawater.
This paper reports experimental study on the development of cadmium tungstate scintillator material in the form of nanocrystal films through controlled sol-gel processing and pre-designed doping. We chose cadmium tungstate as a base material for doping and nanostructure development due to its excellent inherent photoluminescence (PL) property, and chemical and thermal stability including non-hydroscopicity. Experimental results revealed that doping with Li+, B3+ and Bi3+ resulted in appreciably reduced grain size and increased density leading to enhanced optical transmittance. Further analyses indicated that PL output changed significantly with the introduction of dopants. The relationships between doping, microstructure, and PL were discussed. 相似文献
The reactions of 2-methylimidazoline and 2-methyl-1,4,5,6-tetrahydropyrimidine with 1,3-diacid chlorides, in the presence of Et3N in refluxing MeCN give highly functionalized potentially bioactive 1,8-naphthyridinetetraones. 2-Methylimidazoline and 2-methyl-1,4,5,6-tetrahydropyrimidine can be viewed as tridentate nucleophiles which give four consecutive tandem nucleophilic attacks on electrophiles. 相似文献