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51.
酸性品红与蛋白质结合反应的研究及应用 总被引:2,自引:0,他引:2
在pH1.4的Clark-Lubs缓冲介质中,蛋白质与酸性品红反应形成结合物,该结合物的最大吸收波长为576nm,与酸性品红相比,红移了34nm。据此拟定了分析方法,制定了牛血清白蛋白(BSA)、人血清白蛋白(HAS)、γ-球蛋白(γ-G)和酪蛋白的工作曲线,测定的摩尔吸光系数均在10^5数量级,用于人血清中总蛋白的测定,结果与溴甲酚绿(BCG)法基本一致。 相似文献
52.
The title compound, {[Cu(2,2'-bipy)(C7H4O5S)(H2O)2](H2O}n (2,2'-bipy = 2,2'- bipyridine), was synthesized by the hydrothermal reaction of Cu(NO3)2(3H2O, 2,2'-bipyridine and 2-sulphobenzoic acid, and structurally characterized by single-crystal X-ray diffraction analysis. The crystal is of triclinic, space group P with a = 9.21(3), b = 10.17(3), c = 10.77(3) (A), α = 77.017(16), β = 89.80(8), γ = 68.46(7)°, V = 911(5) (A)3, Z = 2, (D/s)max = 0.001, Mr = 473.94, Dc = 1.728 g/cm3, μ(MoKα) = 1.365 mm-1, F(000) = 486, the final R = 0.0246 and wR = 0.0628 for 3809 observed reflections with I > 2σ(I). The mononuclear crystal structure extends into a two-dimensional net- work via hydrogen-bonding interactions and a three-dimensional framework is further formed by means of π-π stacking interactions. 相似文献
53.
构筑了MgO部分稳定的ZrO2基固体电解质电化学电池测量EAF的实验装置,测定了Sm2CuO4的标准Gibbs生成自由能。结果表明化合物RE2CuO23(RE=La,Nd,Sm,Eu)随着镧系元素离子半径减小,热力学稳定性下降,并用晶体场理论解释了这一规律。 相似文献
54.
螯合型二甘醇钛酸酯的合成及其催化性能研究 总被引:3,自引:0,他引:3
报导了两种新的螯合型二甘醇钛酸酯的合成方法,进行了IR和UV鉴定,并作为酯化反应催化剂催化合成了邻苯二甲酸二辛酯。研究了酯化反应转化率与反应时间、反应温度及催化剂用量的关系,探讨了催化剂结构与催化性能的关系。 相似文献
55.
The vacuum-ultraviolet (VUV) pulsed-field ionization-photoelectron (VUV-PFI-PE) spectra of trans-1-bromopropene (trans-CH(3)CH[Double Bond]CHBr) and cis-1-bromopropene (cis-CH(3)CH[Double Bond]CHBr) have been measured in the energy region of 74 720-76 840 cm(-1). The simulation of fine structures observed in the origin VUV-PFI-PE vibrational bands of these molecules has provided the ionization energies (IEs) of trans-1-bromopropene and cis-1-bromopropene to be 74 779.3+/-2.0 cm(-1) (9.2715+/-0.0002 eV) and 75 140.2+/-2.0 cm(-1) (9.3162+/-0.0002 eV), respectively. The vibrational bands resolved in these VUV-PFI-PE spectra at energies 0-1700 cm(-1) above the IEs of trans-1-bromopropene and cis-1-bromopropene have been assigned based on theoretical vibrational frequencies and calculated Franck-Condon factors for the ionization transitions. 相似文献
56.
含氰基侧基聚芳醚砜的合成与表征 总被引:1,自引:0,他引:1
汉2,6-二卤苯甲腈、4,4′-二氯二苯砜、4,4′-二羟基二苯砜、间苯二酚、对苯二酚、酚酞及双酚A为主要原料,合成了含不同结构单元和不同氰基含量的含氰基侧基的聚芳醚砜,并采用IR、^13CNMR等分析手段对其结构进行了表征,同时研究了结构单元和氰基含量对聚芳醚砜性能的影响。 相似文献
57.
A Kinetic Evidence for the Nitroxyl Radicals Recycling Mechanism in the Photostabilizing Process of HALS 总被引:1,自引:0,他引:1
XiaoXuanLIU XingHongZHANG GuangGuoWU JianWenYANG ZhaoHuaZENG YongLieCHEN 《中国化学快报》2003,14(10):1085-1088
The photoinduced bulk polymerization of a reactive-hindered amine fight stabilizers(r-HALS), 4-acryloyl-2, 2, 6, 6-tetramethylpiperidinyl (ATMP), was performed at 80℃ by using a DPC technique. An unique periodic exponential attenuation-type oscillating curve was found when the polymerization was carried out in air, but this phenomenon was not found in nitrogen.It is supposed that this unique kinetic performance may be attributed to nitroxyl radicals that are produced in situ from the oxidation of ATMP. ATMP polymer with narrow polydispersity (d =1.03) can be obtained by photoinduced solution polymerization of ATMP. The signal detected in ESR may be assigned to the nitroxyl radicals in the matrix of ATMP polymer. Since this kind of recycling of nitroxyl radicals is well documented for the photostabilizing mechanism of HALS, the present results may serve as a kinetic evidence for this mechanism. 相似文献
58.
A modified poly(ethylene glycol) (PEG) has been developed as the soluble polymeric supports for liquid phase synthesis of novel thiourea derivatives.In each step of the sequence,the PEG-bound products were precipitated in cold Et2O and the unreacted materials and by-products were removed by simple filtration.The progress of reaction,purity of the isolation and the structure of the PEG-bound products were easily monitored by TLC,IR and ^1H NMR spectra.Representative thiourea derivatives were obtained in moderate yields with excellent purity from this modified PEG-bound product by the cleavage with 50% TFA/H2O. 相似文献
59.
两亲性丙烯酸酯共聚物的聚合研究 总被引:1,自引:0,他引:1
利用过氧化苯甲酰为引发剂探讨了甲基丙烯酸β-羟乙酯和丙烯酸长链烷基酯的自由基共聚合。重点讨论了合成条件如溶剂、沉淀剂、引发剂用量、单体配比、反应时间等对共聚反应的影响以及各种聚合条件对该共聚物的组成、结构和性能的影响。并用IR,GPC,^13CNMR等手段对共聚物进行了表征。 相似文献
60.
Jian Wang Xing‐You Xu Lu‐De Lu Xu‐Jie Yang Wei‐Xing Ma Xiang‐Ning Cui 《Surface and interface analysis : SIA》2007,39(6):482-486
The streaming potential of supersaturated solution of binary carboxylic acids, which have even carbon atoms, was determined to characterize crystallization under different temperatures. The value of the streaming potential was related to the type and solubility of the acids and the starting temperature of crystallization, and was easily influenced by the pressure difference of the liquid or the rate of temperature decline. When the temperature was declined to the point where a crystal nucleus appeared, the streaming potential reached the minimum. Thereafter, as the temperature was sequentially lowered, some minicrystals grew, and the streaming potential presented an ascendant tendency. The higher the starting temperature of the acids saturated solution, the higher is the temperature corresponding to the streaming potential minimum. The less the carbon atoms in the acids and the greater the solubility of the acids are, the higher is the temperature of the streaming potential minimum. Copyright © 2007 John Wiley & Sons, Ltd. 相似文献