电感耦合等离子体原子发射光谱法及离子选择电极法测定荧光级氧化钇中痕量铈的研究

文章描述了荧光级氧化钇中痕量稀土铈的测定方法,在溴酸钾存在下,5摩尔/升HNO_3介质中,以P507萃取微量铈,然后有机相用硝酸、过氧化氢反萃取、再将水相浓缩定容,然后以电感耦合等离子体原子发射光谱法分析。同时用铈的离子选择电极以二次标准加入法作第二种手段分析。样品溶液以乙醇预去溶方式引入等离子体,测定下限为2微克/克,方法简单、快速、准确。离子选择电极法测定铈离子下限1×10～(-5)摩尔/升,回收率为94-101%,方法简单,结果满意、价格便宜。     

Transition of Bery Phase and Pancharatnam Phase and Phase Change

Berry Phase and time-dependent Pancharatnam phase are investigated for nuclear spin polarization in a liquid by a rotation magnetic field, where two-state mixture effect is exactly included in the geometric phases. We find that when the system of nuclear spin polarization is in the unpolarized state, the transitive phenomena of both Berry phase and Pancharatnam phase are taken place. For the polarized system, in contrast, such a transition is not taken place. It is obvious that the transitions of geometric phase correspond to the phase change of physical system.     

ISG-FHEV等效燃油消耗最小控制策略

针对室内复杂环境下火灾识别准确率会降低的问题,提出了一种改进的粒子群算法优化支持向量机参数进行火灾火焰识别的方法。首先在 颜色空间进行火焰图像分割,对获得的火焰图像进行预处理并提取相关特征量;其次采用PSO算法搜索SVM的最优核参数和惩罚因子,并在PSO算法中加入变异操作和非线性动态调整惯性权值的方法,加快了搜索SVM最优参数的精度和速度;然后将提取的火焰各个特征量作为训练样本输入SVM模型进行训练,并建立参数优化后的SVM分类器模型;最后将待测试样本输入SVM模型进行分类识别。算法的火灾识别准确率达到94.09%,分类效果明显优于其他分类算法。仿真结果表明,改进的PSO优化SVM算法提高了火焰识别的准确率和实时性,算法的自适应性更强,误判率更低。     

Hollow glass microspheres coated with CoFe2O4 and its microwave absorption property

Spinel CoFe₂O₄ coating on the surface of hollow glass microspheres of low density was synthesized by co-precipitation method. The phase structures, morphologies, particle size, shell thickness, chemical compositions of the composites have been characterized by X-ray diffraction (XRD), field emission scanning electron microscope (FESEM) and energy dispersive X-ray spectroscopy (EDS). The results show that CoFe₂O₄ coating on hollow glass microspheres can be achieved, and the coating layers are constituted by CoFe₂O₄ nanoparticles of mean size ca. 10 nm. The as-synthesized powder materials were uniformly dispersed into the phenolic cement, then the mixture was pasted on metal plate with the area of 200 mm×200 mm as the test plate. The test of microwave absorption was carried out by the radar-absorbing materials (RAM) reflectivity far field radar cross-section (RCS) method. The results indicate that the coated CoFe₂O₄/hollow glass microspheres composites can be applied in lightweight and strong absorption microwave absorbers.     

Total internal reflection–refraction beam expander

Beam expanders being used presently have complex structure and none is perfect. A novel beam expander is proposed first. The beam expander can magnify (or decrease) the diameter of incident laser beam according to the theory of total internal reflection–refraction (TIR-R) principle. The characteristic of the beam expander was studied by using ray-tracing method and computer simulation. The beam expander can propagate a parallel laser beam along the propagation axis and would not change the propagation direction of the beam. For a nonparallel beam the Lagrange invariant (the product of diameter and divergence angle) is not constant. This beam expander would be an effective device in some applications.     

High-resolution heteronuclear correlation spectroscopy in solid state NMR of aligned samples

A new two-dimensional scheme is proposed for accurate measurements of high-resolution chemical shifts and heteronuclear dipolar couplings in NMR of aligned samples. Both the (1)H chemical shifts and the (1)H-(15)N dipolar couplings are evolved in the indirect dimension while the (15)N chemical shifts are detected. This heteronuclear correlation (HETCOR) spectroscopy yields high-resolution (1)H chemical shifts split by the (1)H-(15)N dipolar couplings in the indirect dimension and the (15)N chemical shifts in the observed dimension. The advantages of the HETCOR technique are illustrated for a static (15)N-acetyl-valine crystal sample and a (15)N-labeled helical peptide sample aligned in hydrated lipid bilayers.     

Control and image processing for streak tube imaging lidar based on VB and MATLAB

In this letter, we develope a control and image processing system for Streak Tube Imaging Lidar （STIL）. In the system, the data acquisition card control and the software interface are programmed in Visual Basic （VB） while the image processing is finished by MATLAB. A STIL imaging experiment is carried out in the laboratory. We obtained the intensity and range images of targets with pseudo color by image processing and reconstruction for a set of raw streak images of targets at different distances acquired by STIL. The range resolution is better than 2 centimeters.     

Spectral tuning of InGaAs/GaAs quantum dot infrared photodetectors with bandpass guided‐mode resonance filters

Quantum dot infrared photodetectors can be coupled with micro‐structured filters to create narrowband sensors. Guided‐mode resonance filters based on a high‐index dielectric slab can exhibit bandpass characteristics that are suitable for monolithic integration with focal‐plane arrays. Here, patterned Ge filters were integrated with InGaAs/GaAs quantum dot detectors to linearly tune their 77 K photoresponse peaks from 5.6 µm to 6.2 µm. The dark current was not influenced by these filters but the ability to narrow the photoresponse linewidth was limited by substrate scattering, which is often encountered with front‐side illumination architectures. (© 2014 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)     

气体开关抖动对单模块快脉冲直线型变压器驱动源输出特性的影响

分析了快脉冲直线型变压器驱动源(FLTD)气体开关触发击穿延时的分布规律,利用MAT-LAB软件生成随机序列模拟开关击穿延时和抖动,在FLTD简化二阶电路的基础上,利用MATLAB分析了开关抖动对40个支路并联1 MA,100 ns FLTD模块输出电流脉冲前沿和幅值的影响。模拟计算结果表明:开关理想时,即抖动为0,输出电流峰值为996 kA,峰值时间为90 ns,10%~90%脉冲前沿为54 ns;开关自身抖动与开关之间分散性之和为10 ns时,输出电流脉冲前沿增加约14%,电流峰值下降约2%;开关自身抖动与开关之间分散性之和为20 ns时,输出电流脉冲前沿增加约38%,电流峰值下降约5%。