四磺基钴酞菁/MCM-41的制备、表征及其催化性能

将四磺基钴酞菁（CoTSPc）通过共价结合连接在氨基化的介孔分子筛MCM-41孔道壁上，制成负载酞菁催化剂，对其进行了X射线衍射（XRD）和红外分析，并研究了其对巯基乙醇的催化氧化反应动力学．结果表明，负载酞菁催化剂有优良的催化性能，在液相反应过程中扩散阻力较小．这种负载催化剂有酶催化特点，即遵循米氏动力学规律，米氏常数Km为0．015mol／L．反应完成后，通过沉淀即可从反应体系中分离，解决了酞菁催化剂无法回收利用和对环境造成新的污染的问题．在工业生产和环境保护方面有着良好应用前景．     

刻槽结构高功率微波输出窗次级电子倍增效应

从理论上分析了周期性矩形刻槽对喇叭天线输出窗真空侧次级电子倍增的影响。采用动力学方法分析得到电子沿介质窗表面运动的渡越时间和碰撞能量,验证得到一定尺寸的矩形刻槽介质窗可以有效抑制次级电子倍增效应。在此情况下,对比了刻槽和不刻槽两种输出窗的辐射特性,发现周期2 mm、宽度1 mm、深度1 mm的矩形刻槽对介质窗辐射特性的影响可以忽略。     

X波段高功率微波选模定向耦合器

高功率、长脉冲是高功率微波技术发展的趋势,提高微波器件的功率容量成为一项重要的任务,使用过模器件可以有效提高微波源的功率容量,然而却会带来微波源中同时存在多种模式的问题。为了识别一个X波段长脉冲过模高功率微波源的输出主模TM01模式,设计了一种在线选模定向耦合器,进行了理论分析和模拟优化设计。当频率范围为9.2~9.6 GHz时,模拟结果显示该选模耦合器对TM01模的耦合度为-54 dB,在400 MHz带宽内定向性大于35 dB,对TM02模的抑制度大于15 dB,功率容量可达到3 GW以上。     

Continuous and Segmented Semiconducting Fiber-like Nanostructures with Spatially Selective Functionalization by Living Crystallization-Driven Self-Assembly

Fiber-like π-conjugated nanostructures are important components of flexible organic electronic and optoelectronic devices. To broaden the range of potential applications, one needs to control not only the length of these nanostructures, but the introduction of diverse functionality with spatially selective control. Here we report the synthesis of a crystalline-coil block copolymer of oligo(p-phenylenevinylene)-b-poly(2-vinylpyridine) (OPV₅-b-P2VP₄₄), in which the basicity and coordinating/chelating ability of the P2VP segment provide a landscape for the incorporation of a variety of functional inorganic NPs. Through a self-seeding strategy, we were able to prepare monodisperse fiber-like micelles of OPV₅-b-P2VP₄₄ with lengths ranging from 50 to 800 nm. Significantly, the exposed two ends of OPV core of these fiber-like micelles remained active toward further epitaxial deposition of OPV₅-b-PNIPAM₄₉ and OPV₅-b-P2VP₄₄ to generate uniform A-B-A and B-A-B-A-B segmented block comicelles with tunable lengths for each block. The P2VP domains in these (co-)micelles can be selectively decorated with inorganic and polymeric nanoparticles as well as metal oxide coatings, to afford hybrid fiber-like nanostructures. This work provides a versatile strategy toward the fabrication of narrow length dispersity continuous and segmented π-conjugated OPV-containing fiber-like micelles with the capacity to be decorated in a spatially selective way with varying functionalities.     

Effective biosorption of U(VI) from aqueous solution using calcium alginate hydrogel beads grafted with amino-carbamate moieties

Journal of Radioanalytical and Nuclear Chemistry - The kinetics of Co ions sorption on CoTreat® was investigated in the 5–40 mg/L concentration range at a bulk temperature of...     

Exciton coupling of tetra(p-hydroxyphenyl)porphyrin controlled by substituents of counterions in Triton X-100 micellar solution

The interactions of nonionic meso-tetra(p-hydroxyphenyl)porphyrin (THPP) with CX3COOH (X = F, Cl, Br) in Triton X-100 (TX) micellar solution have been investigated by optical absorption, resonance light-scattering, and fluorescence spectroscopies. The double red-shifted absorption bands and strong resonance light scattering (RLS) signal imply that the assemblies induced by trihalo acetic acids belong to J-aggregates. The fluorescence of porphyrin is quenched due to the aggregate formation. The kinetics of assemblies trigged by CBr3COOH is studied via stopped-flow techniques. No characteristics of autocatalyzed reactions are observed, and there is only a log phase. The nature of the exciton coupling of transition dipole moment can be systematically changed by the haloid substituents of the organic counteranion.     

Synthesis and antitumor activities of 2‐(substituted)phenyl‐1,2,4‐triazolo[1,5‐a]pyridines

Twenty‐three 2‐(substituted)phenyl‐1,2,4‐triazolo[1,5‐a]pyridines have been synthesized by cycloadditison reaction between N‐amino methylpyridinium mesitylenesulfonates and substituted benzonitriles under the presence of potassium hydroxide at room temperature. The structures of all products were confirmed by ¹H NMR, MS and elemental analyses. The antitumor activities of these compounds were evaluated against human ovary cancer cell line (HO‐8910) in vitro by MTT method. The preliminary results showed that compound 1e (IC₅₀ 28μM) and compound 1w (IC₅₀ 31μM) exhibited stronger antitumor activities than cisplatin (IC₅₀ 35μM) in vitro. Hence, 1e and 1w have potential antitumor activities and are worth further investigation.     

METHANE REFORMING WITH CARBON DIOXIDE TO PRODUCE SYNGAS?a?aCATALYST REGENERATION

The regeneration conditions of the deactivated catalyst 18wt%NiO/a-A12O3 used in methane reforming with carbon dioxide were studied by using a fix-bed flow reactor and TPR technique. When the deactivated catalyst was reduced at 1 123 K in a conventional regeneration process, the activity increased a little, but was still much lower than that of the fresh catalyst. When the deactivated catalyst was reduced, then treated in site With an activity-rejuvenating agent of 5-10 vo1% C (aqueous hydrogen peroxide solution) and reduced again at 1123K, the activity was renewed to approach that of the fresh one.     

强碱阴离子交换树脂合成及热稳定性能研究

氯甲基化聚苯乙烯树脂与不同的叔胺反应制备了含不同季铵基团的强碱树脂.将氯甲基化聚苯乙烯树脂进行硝化、溴化反应后,再用三甲胺进行季铵化制备了苯环上含有吸电子基团的强碱树脂,测定了所制备树脂在水中的热稳定性.结果表明,位阻较大的季铵表现出较高的热稳定性;硝化、溴化后的树脂热稳定性有一定改善;而热重分析表明苯环上引入吸电子取代基不利于提高碱基在高温下的稳定性.