Catalytic Properties of TiO<Subscript>2</Subscript>/Fe<Subscript>3</Subscript>O<Subscript>4</Subscript> Nanoparticles in Plasma Chemical Treatment

We proposed here a new process coupling dielectric barrier discharge (DBD) plasma with magnetic photocatalytic material nanoparticles for improving yield in DBD degradation of methyl orange (MO). TiO₂ doped Fe₃O₄ (TiO₂/Fe₃O₄) was prepared by the sol-gel method and used as a new type of magnetic photocatalyst in DBD system. It was found that the introduction of TiO₂/Fe₃O₄ in DBD system could effectively make use of the energy generated in DBD process and improve hydroxyl radical contributed by the main surface Fenton reaction, photocatalytic reaction and catalytic decomposition of dissolved ozone. Most part of MO (88%) was degraded during 30 min at peak voltage of 13 kV and TiO₂/Fe₃O₄ load of 100 mg/L, with a rate constant of 0.0731 min^?1 and a degradation yield of 7.23 g/(kW h). The coupled system showed higher degradation efficiency for MO removal.     

浅海平均混响强度的数值模拟

海中混响是回声探测的严重干扰。利用本文给出的混响模型可较快地计算分层海洋中平均混响强度的衰减规律及深度结构。
对于近程混响,由于海水非均匀性的影响较小,使用均匀层的射线方法计算。对于远程混响,使用简正波方法计算,它保持了平滑平均后的深度结构。在中等距离上两者能很好地衔接起来,由于考虑了复本征值对简正波入射场的影响,提高了计算精度,通过比较不同散射模型对混响强度计算的影响,提出以分离型二元散射模型作为混响数值模拟的基础,使能由界面反向散射系数估算二元后向散射系数,并大大简化混响强度的数值计算。     

$$\pmb {H_\infty }$$ H ∞ fusion estimation of time-delayed nonlinear systems with energy constraints: the finite-horizon case

Nonlinear Dynamics - The fusion estimation issue of sensor networks is investigated for nonlinear time-varying systems with energy constraints, time delays as well as packet loss. For the addressed...     

THERMODYNAMIC AND PARTICLE-DYNAMIC STUDIES ON SYNTHESIS OF SILICA NANOPARTICLES USING MICROWAVE-INDUCED PLASMA CVD

1. Introduction1.1 Silica nanoparticles and synthesis methods Silica (SiO2) nanoparticles are widely used in industry asan active filler for polymer reinforcement, a rheologicaladditive in fluids, a free flow agent in powders, and anagent for chemical mechanical polishing during IC (inte-grated circuit) fabrication (Sniegowski & de Boer, 2000).Silica powder is also used for producing silicon carbide(Koc & Cattamanchi, 1998) or opaque silica aerosols (Leeet al., 1995). Many methods can …     

求平行力系中心的几何方法

在求平行力系中心位置的过程中,要用到合力矩定理. 现有方法把合力的作用点设为平行力系中心,较难理解. 该文应用合力矩定理时,把合力作用点假设为合力作用线上任意一点,平行力系合力作用线总是通过一个固定点的物理意义非常明确.     

Influence of fluorinated substituent and terminal length on phase behavior of mesogen‐jacketed liquid crystalline polymers with a biphenyl mesogen

A series of mesogen‐jacketed liquid crystalline polymers, poly{2,2,3,3,4,4,4‐heptafluorobutyl 4′‐hydroxy‐2‐vinylbiphenyl‐4‐carboxylate} (PF3Cm, where m is the number of carbon atoms in the alkoxy groups, and m = 1, 4, 6, and 8), the side chain of which contains a biphenyl core with a fluorocarbon substituent at one end and an alkoxy unit of varying length on the other end, were designed and successfully synthesized via atom transfer radical polymerization. For comparison, poly{butyl 4′‐hydroxy‐2‐vinylbiphenyl‐4‐carboxylate} (PC4Cm), similar to PF3Cm but with a butyl group instead of the fluorocarbon substituent, was also prepared. Differential scanning calorimetric results reveal that the glass transition temperatures (T_gs) of the two series of polymers decrease as m increases and T_gs of the fluorocarbon‐substituted polymers are higher than those of the corresponding butyl‐substituted polymers. Wide‐angle X‐ray diffraction measurements show that the mesophase structures of these polymers are dependent on the number of the carbon atoms in the fluorocarbon substituent and the property of the other terminal substituent. Polymers with fluorocarbon substituents enter into columnar nematic phases when m ≥ 4, whereas the polymer PF3C1 exhibits no liquid crystallinity. For polymers with butyl substituents, columnar nematic phases form when the number of carbon atoms at both ends of the side chain is not equal at high temperatures and disappear after the polymers are cooled to ambient temperature. However, when the polymer has the same number of carbon atoms at both ends of the side chain, a hexagonal columnar phase develops, and this phase remains after the polymer is cooled. © 2012 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem, 2013     

加权总体最小二乘问题的解集和性质

本文讨论了加权总体最小二乘问题的等价解集，分析了加权总体最小二乘解与加权最小二乘问题的解之间的关系。推广了Ｇｏｌｕｂ和Ｖａｎ Ｌｏａｎ，Ｖａｎ Ｈｕｆｆｅｌ和Ｖａｎｄｅｗａｌｌｅ，及Ｗｅｉ的相应结果。     

Difference in enzyme activity and conformation of glucose oxidase before and after purification

Enzyme activity of commercial glucose oxidase was enhanced after purification through a strong anionic exchange resin. In order to get a better insight into this phenomenon, surface pressure–area (π–A) isotherms and surface pressure–time (π–t) isotherms was used to study the interaction and the absorption at different pH values of the subphases between octadecylamine and glucose oxidase purified by a styrene system quaternary ammonium type strongly basic anionic exchange resin. Circular dichroism (CD), electrophoresis and enzyme activity measurements were conducted to study these phenomena. A preliminary hypothesis has been suggested to explain why the enzyme activity of purified glucose oxidase was higher than that of the commercial one.