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981.
Xiaodong Zhang Dexu Lin Zhengmin Liu 《Journal of Radioanalytical and Nuclear Chemistry》2005,266(1):149-151
Summary The elastic scattering cross sections of natural vanadium for protons have been measured for beam energies below 2.64 MeV in steps of 10 keV and in the angular 160° and 170°. The overall standard error (ΔσExp/σExp) in the measured cross sections is estimated to be better than ±3% at all the beam energies and angles. The results are presented in graphical and tabular forms that should be useful for those who wish to use the cross sections for material analysis. 相似文献
982.
983.
(PdCl2—PVP)/Al2O3催化剂中Pd状态的探讨 总被引:3,自引:0,他引:3
氯化钯先锚定在聚乙烯吡咯烷酮上后进一步负载到Al_2O_3上所制的催化剂[简称(PdCl_2-PVP)/Al_2O_3]是一种活性、选择性高,稳定性好的烯烃、二烯烃和多烯烃加氢催化剂。本文结合加氢反应,使用XPS、FT-IR、电镜及用CO为探针的FT-IR,对这种催化剂进行了考察。实验说明,在这种催化剂中,钯的价态是在0—2之间。红外光谱在486cm~(-1)处有一微弱的小峰,说明存在Pd—N的配位键。催化剂中钯含量低时(0.2wt%)稳定性好,不吸附CO,活性中心是络合钯原子;当钯含量较高时(0.7wt%),催化剂的初活性虽不低,稳定性却较差,这种催化剂能吸附CO,IR谱图上仅在1919cm~(-1)处有CO桥式吸附态的伸缩振动。表明除络合钯原子外,还有聚集的钯金属存在。FT-IR尚表明,PVP在Al_2O_3上可能并非单纯的物理吸附。电镜结果表明,PVP在Al_2O_3上呈30—70(?)的微球状,(PdCl_2-PVP)/Al)_2O_3上的(PdCl_2-PVP)亦呈微球状,与前者无明显区别,这种催化剂中其活性中心是络合钯原子。 相似文献
984.
T. Vlase Gabriela Vlase A. Chiriac N. Doca 《Journal of Thermal Analysis and Calorimetry》2005,80(1):87-90
Summary In order to obtain catalysts, the thermal decomposition of the precursors is a compulsory step. However, kinetic analysis of the decomposition data obtained under non-isothermal conditions lead very seldom to the intimate reaction mechanism. There is also a lack of information because in non-isothermal kinetics, the compensation effect, is rather a rule and unfortunately a source of debate. In order to discriminate between these processes, and the influence of conversion, respectively temperature on the reaction rate, the NPK (non-parametric kinetic - Sempere and Nomen) method was used. This method is based on the singular value decomposition algorithm (SVD) applied on the matrix of reaction rate at corresponding conversion and temperature. This method allows a less speculative determination of the conversion functions and of the kinetic parameters. 相似文献
985.
In this work, surface-enhanced Raman scattering (SERS)-active gold substrates were first developed by combining the technologies of oxidation–reduction cycles (ORCs) and plasmas treatments in roughening metal substrates. First, a gold substrate was treated by argon plasmas. Then the treated gold substrate was further roughened by triangular-wave ORCs in an aqueous solution containing 0.1 M HCl. Encouragingly, the SERS of Rhodamine 6G (R6G) adsorbed on this roughened gold substrate modified by argon plasmas pretreatment exhibits a higher intensity by 10-fold of magnitude and a better resolution, as compared with the SERS of R6G adsorbed on an unmodified roughened gold substrate. Meanwhile, the probing concentration of R6G adsorbed on the modified substrate can be reduced by one order. It was also found that the pretreatment of argon plasmas demonstrates a positive effect on the (2 2 0) face of Au partly changing into the (1 1 1) face with the lowest surface energy after the ORCs roughening, which is contributive to the improved SERS observed. 相似文献
986.
2,2'-Biphenanthroline (2,2'-biphen) formed from 1,10-phenanthroline when a new two-dimensional layered vanadium oxide metal coordination complex, [(2,2'-biphen)Co]V3O8.5, which contains novel 4,8,10-net sheets, was hydrothermally synthesized. 相似文献
987.
Molecular and nanoscale materials and devices in electronics 总被引:2,自引:0,他引:2
Over the past several years, there have been many significant advances toward the realization of electronic computers integrated on the molecular scale and a much greater understanding of the types of materials that will be useful in molecular devices and their properties. It was demonstrated that individual molecules could serve as incomprehensibly tiny switch and wire one million times smaller than those on conventional silicon microchip. This has resulted very recently in the assembly and demonstration of tiny computer logic circuits built from such molecular scale devices. The purpose of this review is to provide a general introduction to molecular and nanoscale materials and devices in electronics. 相似文献
988.
Nathalie Laronze Jean-François Moisan Catherine Roch-Marchal Feng-Xian Liu Gilbert Hervé 《Journal of Cluster Science》2002,13(3):355-368
Transition metal salts of heteropolyacids have been prepared taking into account the strong acidic and cation exchanging properties of the solid heteropolyacids. The exchange between protons and the transition metal cation is carried out by stirring a suspension of the hydrated heteropolyacid in a solution of the metal acetylacetonate complex in toluene. The exchange occurs on the surface of the solid particles and diffusion of protons and metal cations into the hydrated lattice leads to the substitution of all the protons. The method can be utilized in order to prepare supported vanadyl and copper molybdophosphates from supported heteropolyacids and they have been studied in the catalysis of the oxidative dehydrogenation of isobutyric acid. The effect of vanadyl counter-ions on the catalytic behavior is the same as observed with bulk catalysts but, on the contrary, copper supported molybdophosphate shows an acid catalytic activity not observed with bulk catalysts. 相似文献
989.
Yuming Dong Yuqiang Ding Weifu Dong Cheng Yang Xuefeng Liu Ye Fan Jing Wang Qingwei Pan 《大学化学》1986,35(10):71-76
Based on the development prospect of cosmetics industry, the advantage of light industry characteristic and the foundation of applied chemistry in Jiangnan University, a systematic upgrading of applied chemistry was carried out through "emerging engineering education (3E)" project "upgrade and practice of chemistry-related majors of local and/or trade university responding to the social developments" supported by the Ministry of Education. On the basis of investigation and analysis, the orientation and training goal of applied chemistry were updated first, and then the curriculum system was determined and the curriculum construction is strengthened, so as to achieve more distinctive characteristics, more solid foundation and more comprehensive quality. In view of the new requirements of the 3E for talent training, some practices have been formed in the aspects of multi-disciplinary integration, multi-angle coordination and close integration to industry. Contributing the development of cosmetics industry and seizing the commanding point of science and technology from the perspective of talent training, will play a unique role in human social progress. 相似文献
990.
病态分析体系有偏估计的研究 总被引:3,自引:0,他引:3
运用广义岭估计和Liukejian提出的有偏估计,对病态分析体系进行了数值模拟和实际光度测定,结果表明,广义岭估计显优于最小二乘估计,Liukejian法有功效,可和为解析病态分析体系的化学计量学方法。 相似文献