两个由双咪唑基配体构筑的锰、镉配合物的合成及晶体结构(英文)

通过水热法合成了2个金属-有机配位聚合物[Mn(dipha)(1,3-bix)]n·nH2O(1)和[Cd2(NIPH)2(bimb)2.5(H2O)]n·3nH2O(2)(H2dipha=2,2′-联苯二甲酸,1,3-bix=1,3-双(咪唑基-1-甲基)-苯,H2NIPH=5-硝基间苯二甲酸,bimb=1,4-双(咪唑基-1-甲基)-丁烷)。并对其进行了元素分析、红外光谱、热重和X-射线单晶衍射测定。这2个配合物通过氢键和π-π相互作用形成了超分子网状结构。此外还研究了配合物2的荧光性质。     

Decreasing the CTE of Thermoplastic Polyimide by Blending with a Thermosetting System

Chinese Journal of Polymer Science - A series of thermoplastic polyimide resins with a low coefficient of thermal expansion (CTE) were prepared by blending a rigid resin system...     

类固醇激素的低温等离子体质谱研究

将自行设计和搭建的低温等离子体装置作为离子源,成功地与常压高分辨质谱结合,并将其用于类固醇样品的定性分析.与常规电喷雾质谱相比,用低温等离子体质谱检测类固醇样品具有样品前处理简单、谱图干扰少等优点.对类固醇样品进行了一级质谱以及串联质谱的表征,发现其一级谱图能够体现出类固醇化合物的结构稳定性,而在串联质谱图中则出现了较多的丢水碎片.本工作结合能量计算详细比较分析了典型类固醇样品在碰撞诱导解离(CID)碎裂过程中的丢水过程.另外,通过比较二级质谱的不同以及对其碎裂过程的分析推测,睾酮和去氢表雄酮这对同分异构体得以区分.     

Generalized shift-splitting iteration method for a class of two-by-two linear systems

In this paper, we propose a generalized-shift splitting (GSS) iteration method for solving a broad class of two-by-two linear systems. The convergence theory of the GSS iteration method is established and the spectral properties of the corresponding preconditioned matrix of some special choices for the parameter matrices are analyzed. In addition, the optimal choice of the iterative parameter is discussed. Numerical experiments are used to verify the validity of the theoretical results and the effectiveness of the new method.     

两个由5-硝基间苯二甲酸和双咪唑基配体构筑的锰、钴配合物的合成及晶体结构(英文)

通过水热法合成了2个新的配合物[Mn(NIPH)(mbix)]n(1)和[Co(NIPH)(mbix)(H2O)3]2n·2n H2O(2)(H2NIPH=5-硝基间苯二甲酸,mbix=1,3-双(咪唑基-1-基)苯)。并对其进行了元素分析、红外光谱、紫外光谱、热重和X-射线单晶衍射测定。这两个配合物通过氢键和π-π相互作用形成了三维超分子网状结构。     

基于K-S算法的水质硝酸盐含量光谱检测方法研究

应用紫外光谱对水体中的总氮进行测定,常规的测定方法在分析精度上依赖于所建立的光谱数学模型.测量过程中所依据的紫外光谱数据波段较多,模型的建立所依据的测试样本也比较多,因而很容易引入干扰光谱信息.对水质样本的原始光谱进行一阶微分处理后,采用Kennard-Stone算法对41个样本进行优选,选出30个作为训练集,剩余11...     

Quantum Discord in any Mixture of Two Bi-Qubit Arbitrary Product States

Quantum discord in any mixture of two bi-qubit arbitrary product states is studied with two different approaches. In the first approach the maximal classical correlations are obtained via numerical computations, while in the second approach they are analytically derived. Quantum correlations captured with both approaches completely coincide, as is in accord with the conclusion of Cen et al. [Phys. Rev. A 83 (2011) 054101]. The symmetry reduction of the concerned states concerning quantum correlations is accomplished. The captured discords are amply analyzed so that some inherent distinct properties are revealed.     

Theoretical analyses on improved beam properties of GaSb-based 2.X-μm quantum-well diode lasers with no degradation in laser parameters

An asymmetric laser heterostructure is developed to improve the beam properties of GaSb-based diode lasers with no degradation in laser parameters.Employing the semivectorial finite difference method,the dependences of beam divergence and optical confinement factor on waveguide width and refractive index step are investigated theoretically.After carefully design,a particular asymmetric laser structure is proposed.Its beam divergence in the fast axis is reduced from 61° to 34° compared with that of the broad-waveguide structure.The optical confinement factor is approximately equal to 0.0362 and comparable to that of the conventional broad-waveguide structure.     

在不同扩散系数下反应扩散平面波的折射

在二维复金兹堡-朗道方程描述的反应扩散振荡系统中,就扩散对平面波折射率的影响进行了数值研究,从Snell定律出发导出了折射率的解析表达式,数值和理论结果表明：在纯扩散情况下,平面波的折射满足Snell折射定律,扩散只影响着平面波折射率的大小;在同时存在反应扩散情况下,只有在适当的扩散系数和系统参数下,平面波的折射才满足Snell折射定律.这些结果表明扩散系数对折射规律和折射率都有影响. 关键词： 复金兹堡-朗道方程 扩散 折射率     

SiC晶界薄膜的变电荷分子动力学模拟

基于迭代变电荷方法,用分子动力学模拟了SiC中的晶界薄膜．从原子尺度上模拟了不同的晶界薄膜的结构．观察到了晶粒与晶界薄膜间的电荷转移并且晶界薄膜的厚度与电荷转移有关．该结果提供了晶界存在空间电荷的直接证据,并证明静电作用与晶界薄膜的平衡厚度密切相关． 关键词： 分子动力学 变电荷 晶界薄膜