全文获取类型
收费全文 | 28441篇 |
免费 | 3434篇 |
国内免费 | 2357篇 |
专业分类
化学 | 16938篇 |
晶体学 | 392篇 |
力学 | 1825篇 |
综合类 | 119篇 |
数学 | 3699篇 |
物理学 | 11259篇 |
出版年
2024年 | 87篇 |
2023年 | 465篇 |
2022年 | 744篇 |
2021年 | 802篇 |
2020年 | 926篇 |
2019年 | 875篇 |
2018年 | 830篇 |
2017年 | 758篇 |
2016年 | 1138篇 |
2015年 | 1080篇 |
2014年 | 1304篇 |
2013年 | 1843篇 |
2012年 | 2221篇 |
2011年 | 2397篇 |
2010年 | 1729篇 |
2009年 | 1602篇 |
2008年 | 1772篇 |
2007年 | 1570篇 |
2006年 | 1457篇 |
2005年 | 1231篇 |
2004年 | 1034篇 |
2003年 | 888篇 |
2002年 | 904篇 |
2001年 | 970篇 |
2000年 | 785篇 |
1999年 | 657篇 |
1998年 | 518篇 |
1997年 | 465篇 |
1996年 | 482篇 |
1995年 | 413篇 |
1994年 | 346篇 |
1993年 | 245篇 |
1992年 | 255篇 |
1991年 | 255篇 |
1990年 | 206篇 |
1989年 | 165篇 |
1988年 | 105篇 |
1987年 | 91篇 |
1986年 | 102篇 |
1985年 | 89篇 |
1984年 | 67篇 |
1983年 | 47篇 |
1982年 | 46篇 |
1981年 | 41篇 |
1980年 | 29篇 |
1979年 | 21篇 |
1978年 | 25篇 |
1977年 | 19篇 |
1976年 | 18篇 |
1975年 | 21篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
71.
Guosong Wu Xiaoqin Zeng Wenbin Ding Xingwu Guo Shoushan Yao 《Applied Surface Science》2006,252(20):7422-7429
Ceramic thin films have been widely used to protect the metal substrate as coatings in the past years. In order to improve the poor corrosion resistance of AZ31 magnesium alloy, the study in this paper used the electron beam evaporation method to prepare ceramic PVD films on its surface with TiO2 and Al2O3 as donors, respectively. Atomic force microscopy (AFM), scanning electron microscope (SEM), energy dispersive X-ray spectrometer (EDS), Auger electron spectroscopy (AES) and X-ray diffraction (XRD) were used to investigate the surface morphology, composition and microstructure of the thin films. Both films deposited on AZ31 took on compact top surface morphologies and grew as amorphous structures on substrate. AES test not only showed that films compositions deviated the standard stoichiometric ratios, but also found that element Mg diffused into films and existed as magnesium oxide in the TiOx film as well as the AlOx film. In the electrochemical corrosion test, the AlOx coating on AZ31 exhibited the largest electrochemical impedance in a 3.5% NaCl solution. But it did not show better corrosion resistance than others for the poorer adhesion. Even if its thickness was small, the TiOx coating on AZ31 exhibited the best corrosion resistance in this study. According to the observation and analysis, the damage of these films on AZ31 in aggressive solutions was mainly due to the existence of pores, microcracks, vacancies and poor adhesion between coating and substrate. 相似文献
72.
73.
Yan Guo 《纯数学与应用数学通讯》2007,60(2):291-293
The original article to which this erratum refers was published in Communications on Pure and Applied Mathematics Comm Pure Appl Math(2006)59(5) 626 . 相似文献
74.
An analytical method is presented to investigate the bending-torsion vibration characteristics of a cylinder with an arbitrary cross-section and partially submerged in water. The compressibility and the free surface waves of the water are considered simultaneously in the analysis. The exact solution of structure–water interaction is obtained mathematically. Firstly, the analytical expression of the velocity potential of the water is derived by using the method of separation of variables. The unknown coefficients in the velocity potential are determined by the longitudinal and circumferential Fourier expansions along the outer surface of the cylinder and are expressed in the form of integral equations including the unknown dynamic bending deflection and torsional angle of the cylinder. Secondly, the force and torque acting on the cylinder per unit length, provided by the water, are obtained by integrating the water dynamic pressure along the circumference of the cylinder. The general solution of bending-torsion vibration of the cylinder under the water dynamic pressure is derived analytically. The integral equations included in the velocity potential of the water can be solved exactly. Finally, the eigenfrequency equation of cylinder–water interaction is obtained by means of the boundary conditions of the cylinder. Some numerical examples for elliptical columns partially submerged in water are provided to show the application of the present method. 相似文献
75.
X.C. Li J. Wu K. Xu A.Q. Liu J.T. Lin 《Applied Physics A: Materials Science & Processing》2007,89(2):327-332
This paper presents the theoretical model and the optimization method to suppress the sidelobes of side-coupled photonic crystal
filters. Numerical verification shows a good agreement between the theoretical method and the finite-difference time-domain
simulation, but the theoretic method does not involve the time-consuming computation. The theoretical method also presents
a better physical image for choosing the critical parameters, such as the quality factor, phase shift and the number of resonators.
Based on the theoretical model, two optimization methods (chirp and cascading) are proposed to deeply suppress the sidelobes.
They also show more flexibility in controlling the bandwidth and steepness of the roll-off in the filter.
PACS 42.70.Qs 相似文献
76.
Yangyang Jiang Chen Guo Huizhou Liu 《中国颗粒学报》2007,5(1):130-133
A magnetically rotational reactor (MRR) has been developed and used in absorbing benzene emissions. The MRR has a permanent magnet core and uses magnetic ionic liquid [bmim]FeCl4 as absorbent. Benzene emissions were carried by N2 into the MRR and were absorbed by the magnetic ionic liquid. The rotation of the permanent magnet core provided impetus for the agitation of the magnetic ionic liquid, enhancing mass transfer and making benzene better dispersed in the absorbent. 0.68 g benzene emissions could be absorbed by a gram of [bmim]FeCl4, 0.27 and 0.40 g/g higher than that by [bmim]PF6 and [bmim]BF4, respectively. The absorption rate increased with increasing rotation rate of the permanent magnet. 相似文献
77.
The hydrothermal synthesis and magnetic entropy change for the perovskite manganite La0.5Ca0.3Sr0.2MnO3 have been studied. The La0.5Ca0.3Sr0.2MnO3 can be produced as phase-pure, crystalline powders in one step from solutions of metal salts in aqueous potassium hydroxide solution at a temperature of 513 K in 72 h. Scanning electron microscopy shows that the materials are made up of cuboid-shaped particles in typical dimension of 4.0×2.5×1.6 μm. Heat treatment can improve the magnetocaloric effect for the hydrothermal sample. The maximum magnetic entropy change ΔSM for the as-prepared sample is 0.88 J kg−1 K−1 at 315 K for a magnetic field change of 2.0 T. It increases to 1.52 J kg−1 K−1, near its Curie temperature (317 K) by annealing the sample at 1473 K for 6 h. The hydrothermal synthesis method is a feasible route to prepare high-quality perovskite material for magnetic refrigeration application. 相似文献
78.
Ping-xing Chen Jian-ming Cai Zheng-wei Zhou Guang-can Guo 《量子光学学报》2006,12(B08):72-73
The second law of thermodynamics is one of the most fundamental and for-reaching laws of physics. It teaches us that when a closed system undergoes a thermodynamic process the entropy of the system never decreases; it increases, or at least remains constant. If the entropy increases the thermodynamic process is irreversible, otherwise it is reversible. Only ideal thermal process is reversible. In classical world a great number of facts have proved the second law is true. But in quantum world since the quantum coherence and correlations exist we are not sure the second law is still true, at least in principle. This is because that: 1. on the microscopic level the irreversibility is conflict with the reversibility of all fundamental physical laws ; 2. there are not enough evidences to show it is true in quantum world. 相似文献
79.
Corrosion-related defects of pure iron were investigated by measuring Doppler broadening energy spectra (DBES) of positron annihilation and positron annihilation lifetime (PAL). Defect profiles of the S-parameter from DBES as a function of positron incident energy up to 30 keV (i.e. ∼1 μm depth) were analyzed. The DBES data show that S-parameter increases as a function of positron incident energy (mean depth) after corrosion, and the increase in the S-parameter is larger near the surface than in the bulk due to corrosion. Furthermore, information on defect size from PAL data as a function of positron incident energy up to 10 keV (i.e. ∼0.2 μm depth) was analyzed. In the two-state trapping model, the lifetime τ2 = 500 ps is ascribed to annihilation of positrons in voids with a size of the order of nanometer. τ1, which decreases with depth from the surface to the bulk, is ascribed to the annihilation of positrons in dislocations and three-dimensional vacancy clusters. The corroded samples show a significant increase in τ1 and the intensity I2, and near the surface the corroded iron introduces both voids and large-size three-dimensional vacancy clusters. The size of vacancy clusters decreases with depth. 相似文献
80.
M. Q. Zhang 《Communications in Mathematical Physics》1991,141(3):523-531
We show explicitly how to construct the quantum Lax pair from the Yang-Baxter equation. We demonstrate the new method by applying it to the Heisenberg XYZ model.Supported by DOE contract DE-FG02-88ER25053 相似文献