Photoluminescence characteristics of ZnTiO3: Bi nanocrystals

The photoluminescence properties of the Bi³⁺ in sol-gel derived ZnTiO₃ nanocrystals have been investigated. An ultra-violet emission at 360 nm and a visible emission band at 506 nm have been observed, originating from two kinds of emission centers. The former is ascribed to the ³P₁-¹S₀ transition of Bi³⁺ and the latter to the recombination of the electrons with the photo-generated holes trapped in the zinc vacancies. In all cases the latter contribution is predominant.     

NOESY技术在地胆草倍半萜内酯化合物结构鉴定中的应用（I）

明确从地胆草中分离得到的两对牦牛儿内酯型的立体异构体即地胆草种内酯（scabertopin）、异地胆草种内酯（isoscabertopin）、异去氧地胆草内酯（isodeoxyelephantopin）和去氧地胆草内酯（deoxyelephantopin）的C-2相对构型；方法 NOESY技术，并结合这4个化合物的¹H NMR，¹³C NMR，HMQC谱；结果 两对立体异构体的NOESY谱有明显差异；结论 通过分析NOESY谱，找寻H-1相关信息，若发现H-1与H-8，H-9β和14-CH₃有NOE相关，可以判断化合物的C-2为α构型，若H-1与H-5，H-7，H-3α及H-9α之间有NOE相关，则化合物的C-2为β构型.     

The Characterisitic of Proton-Exchanged LiNbO3 Waveguide Formed by Different Proton Source

Benzoic acid as a source of proton is widely used in the technology of manufacture of proton exchanged ( PE) waveguide .But the diffusing speed of proton is too fast to make the waveguide stable in the pure benzoic acid. The characteristic of waveguide is improved with mixture of benzoic acid and lithium benzoate .     

Hierarchical structures in a turbulent pipe flow

A hierarchical structure (HS) analysis (β-test and γ-test) is applied to a fully developed turbulent pipe flow. Velocity signals are measured at two cross sections in the pipe and at a series of radial locations from the pipe wall. Particular attention is paid to the variation of turbulent statistics at wall units 10<y⁺<3000. It is shown that at all locations the velocity fluctuations satisfy the She–Leveque hierarchical symmetry (Phys. Rev. Lett. 72 (1994) 336). The measured HS parameters, β and γ, are interpreted in terms of the variation of fluid structures. Intense anisotropic fluid structures generated near the wall appear to be more singular than the most intermittent structures in isotropic turbulence and appear to be more outstanding compared to the background fluctuations; this yields a more intermittent velocity signal with smaller γ and β. As turbulence migrates into the logarithmic region, small-scale motions are generated by an energy cascade and large-scale organized structures emerge which are also less singular than the most intermittent structures of isotropic turbulence. At the center, turbulence is nearly isotropic, and β and γ are close to the 1994 She–Leveque predictions. A transition is observed from the logarithmic region to the center in which γ drops and the large-scale organized structures break down. We speculate that it is due to the growing eddy viscosity effects of widely spread turbulent fluctuations in a similar way as in the breakdown of the Taylor vortices in a turbulent Couette–Taylor flow at high Reynolds numbers.     

Crystal Structure of Adduct 2-Phenyl-imidazo [ 4,5-f ] 1,10-phenanthroline Methanol

The structure of the title adduct comprises a phenanthroline derivative 2-phenyl-imidazo[4,5-f]1,10-phenanthroline and a methanol.The composition of the crystalline adduct was characterized as C19H12N4.CH3OH.It belongs to orthorhombic system,space group Pna21 with a=1.3693(4)nm,b=2.2988(7)nm,c=0.51338(15)nm,V=1.6160(8)nm^3.Z=4,and final R1=0.0423.wR2=0.1012 .Crystal structure shows that all the 19 carbon atoms and 4 nitrogen atoms are coplanar.The bond length data indicated that a very extensive conjugation system was formed.This conjugation makes the compound being a potentially excellent energy transformer used for luminescent materials.     

Speciation Analysis of Inorganic Tin (Sn(II)/Sn(IV)) by Graphite Furnace Atomic Absorption Spectrometry Following Ion-Exchange Separation

A new method based on anion exchange resin separation and graphite furnace atomic absorption spectrometry (GFAAS) detection is proposed for the determination of inorganic tin species. The result showed that Sn(IV) was quantitatively retained on the resin when [HCl] = 9.0 mol · L⁻¹, but Sn(II) could not be adsorbed on the resin under the same condition. Thus, a separation of Sn(II) and Sn(IV) has been realized. When the concentration of NaOH solution was between 2.0–7.0 mol · L⁻¹, Sn(IV) that adsorbed on the resin could be eluated from the resin completely. Meanwhile, under the atmosphere and the nitrogen states, the translation between Sn(II) and Sn(IV) was investigated. Under the optimal conditions, the detection limit of Sn(IV) is 0.40 μg · L⁻¹ with RSD of 2.3% (n = 5, c = 2.0 μg · L⁻¹). The proposed method was applied to the speciation analysis of tin in different water samples and the recovery of total Sn was in the range of 98.7–101.7%. In order to verify the accuracy of the method, a certified reference water sample was analyzed and the results obtained were in good agreement with the certified value.     

Ionic conductivity of epitactic MBE-grown BaF2 films

We studied parallel conductivities of pure BaF₂ films with thicknesses ranging from 35 to 300 nm, epitaxially grown on Al₂O₃(0 1 2) substrates by molecular beam epitaxy technique. The overall conductivities of the films are found to increase with decreasing thickness. The detailed investigation of the overall conductance as a function of the thickness permits the deconvolution of bulk and boundary effects, the latter being attributed to distinct space charge effects in the interface between BaF₂ film and Al₂O₃ substrate. The (extrinsic) Debye length (λ) is estimated to be about 8 nm at T=593 K, which corresponds to an impurity content of 10¹⁸/cm³ (singly ionized dopant assumed). This is consistent with the fact that we observed a constant boundary contribution for all investigated films (film thickness >4λ). It is also consistent with the Debye length observed in a previous report on CaF₂/BaF₂ heterolayers fabricated by the same technique, in which the low temperature enhancement was also attributed to space charges in BaF₂ [Nature 408 (2000) 946]. Only at low temperatures (below 370 °C), the conductance seems to be influenced by strain effect.     

牛顿第二定律实验中的误差分析

本文是通过对加速度的实验值和理论值进行比较和分析，给出误差的合理范围。     

ALGEBRAIC INDEPENDENCE OF CERTAIN NUMBERS OVER A FIELD OF FINITE TRANSCENDENCE TYPE

The transcendental degree of certain numbers concerned with the exponential funotion over a field of finite transcendence type is considered.     

Essentially normal Hilbert modules and Khomology Ⅲ: Homogenous quotient modules of Hardy modules on the bidisk

In this paper, we study the homogenous quotient modules of the Hardy module on the bidisk. The essential normality of the homogenous quotient modules is completely characterized. We also describe the essential spectrum for a general quotient module. The paper also considers K-homology invariant defined in the case of the homogenous quotient modules on the bidisk. This work is partially supported by the National Natural Science Foundation of China (Grant No. 10525106), the Young Teacher Fund, the National Key Basic Research Project of China (Grant No. 2006CB805905) and the Specialized Research for the Doctoral Program