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991.
Hong Tao Gao Dong Mei Dai Tong Hua Li 《中国化学快报》2007,18(4):495-498
Non-negative matrix factorization(NMF)is a technique for dimensionality reduction by placing non-negativity constraints onthe matrix.Based on the PARAFAC model,NMF was extended for three-dimension data decomposition.The three-dimension non-negative matrix factorization(NMF3)algorithm,which was concise and easy to implement,was given in this paper.The NMF3algorithm implementation was based on elements but not on vectors.It could decompose a data array directly without unfolding,which was not similar to that the traditional algorithms do.It has been applied to the simulated data array decomposition andobtained reasonable results.It showed that NMF3 could be introduced for curve resolution in chemometrics. 相似文献
992.
Two new compounds from Zingiber officinale 总被引:1,自引:0,他引:1
Yu Zhao Qiao Feng Tao Rong Ping Zhang Chang Xin Zhou Hui Dou Shu Yun Shi Ye Cheng Xiao Lian Li Sun Su Zeng Ke Xin Huang Xiao Dong Zhang Xiao Kun Li 《中国化学快报》2007,18(10):1247-1249
A new cyclic diarylheptanoid,1,5-epoxy-3-hydroxy-1-(3-methoxy-4,5-dihydroxyphenyl)-7-(4-hydroxyphenyl)-heptane (1),as well as a new monoterpene,10-O-β-D-glucopyranosyl-hydroxy cineole (2) were isolated from the rhizomes of Zingiber officinale. The structures of compounds 1 and 2 were established based on their spectral data.In addition,the antioxidant activities of these compounds were also measured. 相似文献
993.
Xi‐Zhao Wang Jiong Jia Yan Zhang Wei‐Ren Xu Wei Liu Fang‐Niu Shi Jian‐Wu Wang 《中国化学会会志》2007,54(3):643-652
The synthesis of a series of new 5‐isoxazolpenicillins is described, which were obtained by coupling substituted isoxazoles with 6‐APA. Concise large‐scale synthesis of 3,5‐disubstituted isoxazoles by 1,3‐dipolar cycloaddition using copper(I) as catalyst was also investigated. Representative compounds were assayed for antimicrobial activities, showing satisfactory antimicrobial activities against Gram‐negative bacteria. 相似文献
994.
CeO2-ZrO2-Y2O3对Pt-Rh型三效催化剂性能的影响 总被引:4,自引:0,他引:4
采用共沉淀法技术制备了Ce0.35Zr0.55Y0.10固溶体,并对其进行了比表面积、储氧量的测试和XRD的表征.将其用于低贵金属Pt-Rh型三效催化剂的制备,考察了CeO2-ZrO2-Y2O3对三效催化剂性能的影响.结果表明,Ce0.35Zr0.55Y0.10具有与Ce0.50Zr0.50O2相似的立方结构和相近的储氧量,经高温(1000 ℃)后仍能保持较大的比表面积(38.66 m2·g-1).和含Ce0.50Zr0.50O2的三效催化剂相比,含CeO2-ZrO2-Y2O3的三效催化剂经高温老化后,C3H8,CO,NO仍具有较高的转化率和较低的起燃温度. 相似文献
995.
The use of the reverse atom transfer radical polymerization (RATRP) to end-functionalize poly(methyl methacrylate) (PMMA) with fullerenes, e.g. C60 and C70 was described in this paper. The Cl-terrninated PMMA was prepared via RATRP with designed molecular weight and narrow molecular weight distributions, and then directly used to react with fullerenes to produce C60(C70) terminated PMMA polymers in the presence of CuBr/Cu/bipy or FeCl2/bipy catalysts. The resultant polymers exhibit good solubility in some common organic solvents, e.g. THF, CHCl3 and toluene, and were well structurally characterized by a variety of physical techniques. 相似文献
996.
High dispersion and electrocatalytic properties of palladium nanoparticles on single-walled carbon nanotubes 总被引:1,自引:0,他引:1
Palladium (Pd) nanoparticles were electrochemically dispersed on single-walled carbon nanotubes (SWNTs) by electroreduction of octahedral Pd(IV) complex formed on the SWNT surface. The structure and nature of the resulting Pd-SWNT composites were characterized by transmission electron microscopy and X-ray diffraction. The electrocatalytic properties of the Pd/SWNT electrode for hydrazine oxidation have been investigated by cyclic voltammetry; high electrocatalytic activity of the Pd/SWNT electrode can be observed. This may be attributed to the high dispersion of palladium catalysts and the particular properties of SWNT supports. The results imply that the Pd-SWNT composite has good potential applications in fuel cells. 相似文献
997.
A simple and efficient preparation of gramicidin S and its analogues is described. It involves solid-phase peptide synthesis and on-resin macrolactamization without side chain protection, affording cyclic products in high yield and high purity. The high specificity of the cyclization reaction was shown to originate in the formation of a pre-organized conformation of the linear biosynthetic precursor of gramicidin S. This facile method will provide convenient access to the analogues of the natural product for functional optimization to counter microbial resistance. 相似文献
998.
There are many organic pollutants in the environment, such as polychlorinated biphenyl, polycyclic aromatic hydrocarbons, dichlorodiphenyl-trichloroethane (DDT), and polychlorinated naphthalene. These organic pollutants are persistent,liposoluble and easily cumulated in organism; consequently, the potential toxicity will be high. Risk assessment of industrial chemicals is currently carried out using scanty experimental data, because many of these chemicals have very little or no test data. S… 相似文献
999.
Winny Dong Jeffrey Sakamoto Bruce Dunn 《Journal of Sol-Gel Science and Technology》2003,26(1-3):641-644
The electrochemical properties of high surface area transition metal oxide aerogels are extremely interesting because aerogels serve to amplify surface effects. As a result, the electrochemical properties are dominated by surfaces rather than by bulk behavior. In the case of vanadium oxide aerogels this leads to extraordinary electrochemical properties, including an extremely high capacity for lithium and electrochemical responses that are both battery-like and capacitor-like. By exploiting sol-gel synthesis, it is possible to synthesize nanocomposite electrodes in which aerogels are in intimate contact with carbon nanotubes. The resulting nanocomposites exhibit superior electrochemical properties, especially at high discharge. 相似文献
1000.
低硫可膨胀石墨的制备 总被引:18,自引:0,他引:18
低硫可膨胀石墨的制备宋克敏,路文义,高淑英,阎秋燕(河北教育学院石家庄050091)关键词低硫可膨胀石墨,制备,过氧化氢,硫酸柔性石墨具有耐高温、耐酸碱、抗拉、抗压、抗辐射、回弹性等优良性能,被广泛应用于化工、机械、肮天、原子能等领域。但其原材料可膨... 相似文献