Influence of Pickling High Alloyed CrNi-Steels and Nickel Base Alloys with Citric Acid on the Composition of their Tarnish Oxides

 Extra-ordinary mechanical features and high corrosion resistance are essential qualities of CrNi-steels and nickel base alloys. The corrosion resistance of these materials fundamentally depends on their surface conditions. Tarnish colours and welding scale, formed during thermal treatment or joining, are removed by pickling components made of these alloys with sulphuric acid, nitric acid and hydrofluoric acid as well. By this kind of surface refinement several million tons per annum of aggressive waste waters are produced, that cause high environmental risks and not acceptable employee endangerings. Therefore, a project was promoted by the DECHEMA e.V. to replace hydrofluoric acid by organic complexing agents. The related surface analytical examinations are reported in this publication.     

Über die Bestimmung von Hydrochinon und Brenzkatechin neben Resorzin und einigen anderen Phenolen

Ohne Zusammenfassung     

Mumford Curves with Maximal Automorphism Group II: Lamé Type Groups in Genus 5-8

A Mumford curve of genus g=5,6,7 or 8 over a non-Archimedean field ofcharacteristic p (such that if p=0, the residue field characteristic exceeds 5) has at most 12(g–1) automorphisms. In this paper, all curves that attain this bound and their automorphism groups (called of Lamé type) are explicitly determined.     

On the <Emphasis Type="Italic">K</Emphasis>-Theory of Graph <Emphasis Type="Italic">C</Emphasis><Superscript>*</Superscript>-Algebras

We classify graph C ^*-algebras, namely, Cuntz-Krieger algebras associated to the Bass-Hashimoto edge incidence operator of a finite graph, up to strict isomorphism. This is done by a purely graph theoretical calculation of the K-theory of the C ^*-algebras and the method also provides an independent proof of the classification up to Morita equivalence and stable equivalence of such algebras, without using the boundary operator algebra. A direct relation is given between the K ₁-group of the algebra and the cycle space of the graph. We thank Jakub Byszewski for his input in Sect. 2.8. The position of the unit in K ₀( _Ч) was guessed based on some example calculations by Jannis Visser in his SCI 291 Science Laboratory at Utrecht University College.     

Inkjet-printed thiol self-assembled monolayer structures on gold: quality control and microarray electrode fabrication

Laterally structured, self-assembled monolayers (SAMs) of different thiols (HS-R-X, R = (CH 2) 3-16, X = -CH 3, -COOH, -NH 2) on gold have been prepared by inkjet printing. The printer is a modified, low-cost desktop printer (Epson Stylus Photo R200), the ink is a 1 mM solution of the thiol in ethanol/glycerol (6:1). The quality of inkjet-printed large area SAMs obtained in this study is between that of a layer self-assembled from a thiol solution and that obtained by soft lithography, according to cyclic voltammetry, electrochemical impedance spectroscopy, scanning electrochemical microscopy (SECM), and polarization-modulated Fourier transform infrared reflection-absorption spectroscopy (PM IRRAS). For the first time, simultaneous printing of two different thiols in a single print job as an alternative to sequential printing and backfilling is demonstrated. The smallest structures consisting of conductive disks of 40 microm diameter were analyzed as single spots by SECM and as random array electrodes with different average disk-disk distance. Conductive band electrodes with variable bandwidth (300 microm to 1 cm) are presented, as well as a pH switchable band structure. As compared to stamping, inkjet printing allows for simultaneous multiple thiol printing in a single print job with the resolution limited only by the droplet size and the precision of the translation stage.     

Synthesis of highly phenylene substituted p-phenylene oligomers from pyrylium salts

A transition metal free route to phenyl substituted oligophenylenes that tolerates halogens is described.     

Photophysics and deactivation pathways of thymine

Combined complete active space perturbation theory (CASPT2) and multireference configuration interaction calculations with single and double excitations (MR-CISD) were performed in order to explore possible deactivation pathways of thymine after photoexcitation. Equilibrium geometries are reported together with a total of eight extremes (minima or maxima) on the crossing seam (MXS), through which such radiationless transitions may occur. Furthermore, conformational analysis allows grouping these conical intersections in five distinct types. Reaction paths were calculated connecting the S1 (1)n pi* minimum with the lowest-energy MXS of each group. Two distinct types of paths were observed, both with features that should delay the internal conversion to the ground state. This is shown to provide a possible explanation for the relatively long excited-state lifetime of thymine.     

Scanning electrochemical microscopy study of laccase within a sol-gel processed silicate film

The enzyme p-diphenol:dioxygen oxidoreductase (laccase, EC 1.10.3.2) was isolated from Cerrena unicolor fungus and embedded in a sol-gel film obtained by acidic condensation of TMOS. The gel was cast to thin films on glass. The laccase-containing silicate films were inspected by confocal laser scanning microscopy (CLSM), scanning force microscopy (SFM) and scanning electrochemical microscopy (SECM). CLSM images in the reflection mode showed aggregates within the silicate films. SECM images in the substrate-generation/tip-collection mode using 2,2'-azino-bis(3-ethylbenzothiazoline-6-sulfonate) (ABTS) as electron donor for laccase showed that the position of aggregates coincides with increased enzymatic activity within the silicate film. The flux from individual aggregates was detected. SECM images in the redox competition mode confirmed the assignment and could exclude that topographic features observed by CLSM and SFM could be the reason for the image contrast. SFM images showed that the aggregates partially dissolve during prolonged exposure to aqueous buffer. The experimental setup allowed following one individual aggregate over time with all three microscopic techniques which enabled the collection of complementing information on morphology and catalytic activity as well as their development over time.