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排序方式: 共有491条查询结果,搜索用时 31 毫秒
71.
Ashutosh Sharma R. Khanna Gunter Reiter 《Colloids and surfaces. B, Biointerfaces》1999,14(1-4):223-235
We present experimental results on the instability and dewetting of thin liquid polydimethylsiloxane (PDMS) films intercalated between an aqueous medium and a silicon wafer grafted with PDMS ‘brushes’. This is a thin film analog of the precorneal thin mucus coating sandwiched between the aqueous tear film and the glycocalyx carrying corneal epithelial surface. Lowering of the PDMS–water interfacial tension by a surfactant results in dewetting even of micrometer thick films within a few minutes. The instability appears to be induced by a long range non-classical DLVO force which has the same decay behavior as the nonretarded van der Waals force, but a magnitude which is about 2–3 orders higher. Implications for the breakup of the precorneal mucus layer and the tear film are discussed. 相似文献
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Masumi Asakawa Peter R. Ashton Vincenzo Balzani Alberto Credi Christoph Hamers Gunter Mattersteig Marco Montalti Andrew N. Shipway Neil Spencer J. Fraser Stoddart Malcolm S. Tolley Margherita Venturi Andrew J. P. White David J. Williams 《Angewandte Chemie (International ed. in English)》1998,37(3):333-337
A mechanical switch in a [2]catenane , made up of a cyclobis(paraquat-p-phenylene) tetracation interlocked with a macrocyclic polyether containing a redox-active tetrathiafulvalene (TTF) unit and a 1,5-dioxynaphthalene ring system, can be thrown either chemically or electrochemically. The neutral TTF unit resides “inside” the tetracationic cyclophane in the reduced state and “alongside” it in the oxidized species (TTF+/ TTF2+). Switching between the reduced (I4+) and oxidized state (I5+(I6+)) is accompanied by a dramatic color change. 相似文献
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77.
Kara Lee Walcher 《Journal of Graph Theory》1996,23(4):355-360
Let G be a graph on p vertices. Then for a positive integer n1 G is said to be n-extendible if (i) n < p/2, (ii) G has a set of n independent edges, and (iii) every such set is contained in a perfect matching of G. In this paper we will show that if p is even and G is n-connected, then Gk is -extendible for every integer k ≥ 2 such that . © 1996 John Wiley & Sons, Inc. 相似文献
78.
Madhumita Mukherjee Tanya Das Saswata Bose Chapal Kumar Das Alexander P. Kharitonov Kaushik Banik Tham Nguyen Chung Gunter Mennig 《Macromolecular Symposia》2009,277(1):24-35
Kevlar fiber was fluorinated and oxy-fluorinated directly in presence of undiluted fluorine and fluorine gas mixture and processed with Polycarbonate and LCP at 320 °C under 20 rpm in a twin-screw extruder. The composites were then injection molded into dumbbell shaped specimens under different conditions like various mold temperatures, injection temperatures, injection speeds and mold filling rates. Various physico-chemical characterizations have been performed under definite processing parameter. Orientation of fibers under different injection parameters was evaluated using mold flow simulation technique. Most injection molded or extruded structures however, exhibit non-uniform fiber orientation across the final parts, with a diverging variety of different local fiber orientation states. Distinct skin and core regions were observed in the injection molded parts and it has also been found out that fiber orientation is different in skin and core region for both unmodified and modified derivative, which affects the flow behavior. Processing parameters significantly affect the fiber orientation pattern in the skin and core region for all blended materials. It is worth mentioning that the maximum fiber orientation occurred during the extrusion process at the wall but different extent of fiber orientation is observed during the injection molding depending on the shape of the dumbbell specimen. This fibrillation has been corroborated by the SEM study in both the skin and core region. 相似文献
79.
Sleno L Daneshfar R Eckert GP Müller WE Volmer DA 《Rapid communications in mass spectrometry : RCM》2006,20(18):2641-2648
Active phloroglucinol constituents of Hypericum perforatum (St. John's wort) extracts, hyperforin and adhyperforin, have been studied following ion activation using tandem mass spectrometry (MS/MS) and complemented by accurate mass measurements. These two compounds were readily analyzed as protonated and deprotonated molecules with electrospray ionization. MS/MS and MS3 data from a quadrupole-linear ion trap tandem mass spectrometer were employed to elucidate fragmentation pathways. Fourier transform ion cyclotron resonance measurements afforded excellent mass accuracies for the confirmation of elemental formulae of product ions formed via infrared multiphoton dissociation and sustained off-resonance irradiation collision-induced dissociation. Fragmentation schemes have been devised for the dissociation of hyperforin and adhyperforin in negative and positive ion modes. This information is expected to be especially valuable for the characterization of related compounds, such as degradation products, metabolites and novel synthetic analogs of hyperforin. 相似文献
80.
U. Siodlaczek P. Achenbach J. Ahrens J.R.M. Annand H.-J. Arends R. Beck R. Bilger H. Clement V. Hejny M. Kotulla B. Krusche V. Kuhr R. Leukel J.C. McGeorge V. Metag R. Novotny V. Olmos de León F. Rambo M. Schepkin A. Schmidt I. Seluzhenkov H. Ströher G.J. Wagner Th. Walcher J. Weiß F. Wissmann M. Wolf 《The European Physical Journal A - Hadrons and Nuclei》2001,10(3):365-371
Differential cross-sections for the reactions d (γ,π0)d and d (γ,π0)pn have been measured at MAMI with the TAPS detector setup in the energy range 140 MeV < E
γ < 306 MeV. By use of the Glasgow tagging spectrometer an 0.8 MeV energy resolution for photons incident on the target was
achieved. The π0 missing energy resolution was sufficient for a reliable separation of coherent and incoherent channels. The data for the
break-up channel exhibit very strong final state interaction effects, whereas the observed angular dependence of the inclusive
process d (γ,π0)X is in quantitative agreement with predictions for a quasi-free process. The observed absolute d (γ,π0)X cross-sections, on the other hand, are significantly smaller than predicted by the quasi-free process for E
γ >∼ 250 MeV. Associating this failure with the π0 photoproduction on the neutron would suggest that its cross-section is up to 25% below the presently believed value.
Received: 13 February 2001 / Accepted: 13 April 2001 相似文献