全文获取类型
收费全文 | 590篇 |
免费 | 11篇 |
国内免费 | 3篇 |
专业分类
化学 | 327篇 |
晶体学 | 26篇 |
力学 | 12篇 |
数学 | 84篇 |
物理学 | 155篇 |
出版年
2022年 | 4篇 |
2021年 | 10篇 |
2020年 | 5篇 |
2019年 | 10篇 |
2018年 | 9篇 |
2017年 | 4篇 |
2016年 | 7篇 |
2015年 | 9篇 |
2014年 | 16篇 |
2013年 | 23篇 |
2012年 | 32篇 |
2011年 | 38篇 |
2010年 | 11篇 |
2009年 | 21篇 |
2008年 | 23篇 |
2007年 | 35篇 |
2006年 | 49篇 |
2005年 | 28篇 |
2004年 | 11篇 |
2003年 | 18篇 |
2002年 | 22篇 |
2001年 | 12篇 |
2000年 | 18篇 |
1999年 | 9篇 |
1998年 | 4篇 |
1997年 | 4篇 |
1996年 | 10篇 |
1995年 | 8篇 |
1994年 | 7篇 |
1992年 | 6篇 |
1989年 | 3篇 |
1987年 | 3篇 |
1986年 | 3篇 |
1985年 | 6篇 |
1984年 | 5篇 |
1983年 | 7篇 |
1982年 | 6篇 |
1981年 | 8篇 |
1980年 | 11篇 |
1979年 | 8篇 |
1978年 | 5篇 |
1977年 | 5篇 |
1975年 | 7篇 |
1974年 | 3篇 |
1971年 | 3篇 |
1960年 | 3篇 |
1947年 | 6篇 |
1946年 | 5篇 |
1944年 | 4篇 |
1943年 | 7篇 |
排序方式: 共有604条查询结果,搜索用时 390 毫秒
111.
Kesava Reddy M Vijaya Bhaskar Reddy M Jayakrishna G Gunasekar D Caux C Bodo B 《Chemical & pharmaceutical bulletin》2003,51(2):191-193
Two new flavonoids, 5, 7, 2', 5'-tetramethoxyflavanone (1) and 5-hydroxy-7, 2'-dimethoxyflavone (2), together with two known flavones, skullcapflavone I (3) and echioidin (4) were isolated from the whole plant of Andrographis rothii. The structures of the new compounds were established by extensive one- and two-dimensional (1D- and 2D-) NMR spectral studies. 相似文献
112.
Detection of triplet-triplet energy transfer in an aqueous solution of P-trypsin is reported. This conclusion is based on the observation that a light excited phenolate side chain can sensitize the destruction of an adjacent indole side chain. The role that the indole triplet might play in the UV-induced photolysis of /l-trypsin is also investi-gated. The results suggest that the UV (309 nm)-induced inactivation of P-trypsin is not caused by indole ring destruction but by the disruption of disulfide bonds without thiol formation. 相似文献
113.
114.
Ramachandran PV Burghardt TE 《Chemistry (Weinheim an der Bergstrasse, Germany)》2005,11(15):4387-4395
Reactions of N-silyl- and N-aluminoimines with B-allyldiisopinocampheylborane in the presence of methanol, followed by oxidative workup furnished homoallylic amines in good yields and high ee. A 11B NMR spectroscopy study revealed that the reactions do not proceed, even at room temperature, unless a molar equivalent of water or methanol is added. The first reagent-controlled asymmetric crotylboration and alkoxyallylboration of aldimines furnishing beta-methyl or beta-alkoxy homoallylic amines in very high diastereoselectivity and enantioselectivity are reported herein. Crotylboration and alkoxyallylboration of imines proceed only with the "allyl"-boron "ate" complexes, instead of the "allyl"-dialkylboron reagents used with aldehydes. The addition of methanol is necessary for these reactions as well. Application of this methodology for the conversion of representative nitriles to beta-amino acids in two steps has been described. Additionally, a procedure for the preparation of chiral delta-amino alcohols and gamma-lactams from nitriles is also reported. 相似文献
115.
A. P. Balachandran R. Ramachandran H. Rupertsberger B. S. Skagerstam 《Letters in Mathematical Physics》1980,4(2):79-86
We show that the solutions of a class of nonlinear models also generate gauge ambiguities in the vacuum sector of Yang-Mills theories. Our results extend known connections between gauge ambiguities and certain nonlinear -models, and clarify the underlying group theory. For many nonlinear models, we also give a simple, intrinsic parametrization of physical fields (which have values in a homogeneous space of a group).Supported in part by the U.S. Department of Energy.Supported by Fonds zur Förderung der Wissenschaftlichen Forschung in Österreich 相似文献
116.
The possible existence of charmed multiquark hadrons are investigated using phenomenologicalmit bag model and the SU(4) flavour symmetry. The masses of 6q, 9q and 15q systems having the same quantum numbers as the physically interesting ordinary nuclei, hypernuclei and supernuclei are estimated.
We find that several new states with distinct signatures are predicted. 相似文献
117.
A convenient synthesis of (+)-goniodiol, (-)-8-epigoniodiol, and (+)-9-deoxygoniopypyrone has been developed via asymmetric alkoxyallylboration and ring-closing metathesis pathways. 相似文献
118.
Kanmani S. S. Rajamanickam N. Ramachandran K. 《Journal of Solid State Electrochemistry》2020,24(10):2499-2509
Journal of Solid State Electrochemistry - In the present work, Eosin yellowish (EY) dye–sensitized and CdS-sensitized TiO2 photoanodes prepared by doctor blade technique, for dye (DSSC)- and... 相似文献
119.
120.