Electropolishing for the formation of anodic nanotubular TiO2 with uniform length and density

Electropolishing of Ti was carried out in alcohol-based electrolyte and subsequently the polished Ti was anodized in ethylene glycol containing 0.25 wt% NH₄F. Anodization of polished and non-polished Ti, respectively, showed no big difference in the degree of local arrangement of the nanotubes, whereas the surface roughness on a large area was dramatically improved in the anodized polished Ti. Anodization of polished Ti leads to the formation of nanotubular TiO₂ structures with more uniform length and relatively time-independent density of nanotubes compared to that prepared with anodization of non-polished Ti, meaning that electropolishing is indispensable for the formation of uniform nanotubular TiO₂ structures.     

Zygmund Type Mean Lipschitz Spaces on the Unit Ball of ℂ n

On the unit ball of ? ⁿ , the space of those holomorphic functions satisfying mean Lipschitz condition $$ \int_0^1 \omega^*_p(t, f)^q \frac{dt}{t^{1+ q}} <\infty$$ is characterized by integral growth conditions of the tangential derivatives as well as the radial derivatives, where \(\omega^*_p(t, f)\) denotes the double difference L ^p modulus of continuity defined in terms of the unitary transformations of ? ⁿ .     

Synergistic Antibacterial and Antibiofilm Effect Between (+)-Medioresinol and Antibiotics In Vitro

In this study, antibacterial effects of (+)-Medioresinol isolated from stem bark of Sambucus williamsii and its synergistic activities in combination with antibiotics such as ampicillin, cefotaxime, and chloramphenicol were tested by antibacterial susceptibility testing and checkerboard assay. (+)-Medioresinol possessed antibacterial effects against antibiotics-susceptible- or antibiotics-resistant strains. Most of combinations between (+)-Medioresinol and each antibiotic showed synergistic interaction (fractional inhibitory concentration index ≤0.5) against bacterial strains including antibiotics-resistant Pseudomonas aeruginosa. Furthermore, the antibiofilm effect of (+)-Medioresinol alone or in combination with each antibiotic was investigated. The results indicated that not only (+)-Medioresinol but also its combination with each antibiotic had antibiofilm activities. It concludes that (+)-Medioresinol has potential as a therapeutic agent and adjuvant for treatment of bacterial infection.     

Dual Role of Silver Moieties Coupled with Ordered Mesoporous Cobalt Oxide towards Electrocatalytic Oxygen Evolution Reaction

Herein, we show that the performance of mesostructured cobalt oxide electrocatalyst for oxygen evolution reaction (OER) can be significantly enhanced by coupling of silver species. Various analysis techniques including pair distribution function and Rietveld refinement, X‐ray absorption spectroscopy at synchrotron as well as advanced electron microscopy revealed that silver exists as metallic Ag particles and well‐dispersed Ag₂O nanoclusters within the mesostructure. The benefits of this synergy are twofold for OER: highly conductive metallic Ag improves the charge transfer ability of the electrocatalysts while ultra‐small Ag₂O clusters provide the centers that can uptake Fe impurities from KOH electrolyte and boost the catalytic efficiency of Co–Ag oxides. The current density of mesostructured Co₃O₄ at 1.7 V_RHE is increased from 102 to 211 mA cm^?2 with incorporation of silver spices. This work presents the dual role of silver moieties and demonstrates a simple method to increase the OER activity of Co₃O₄.     

Phosphorus‐based Schiff bases and their complexes as nontoxic antioxidants: Structure–activity relationship and mechanism of action

Phosphorus‐based Schiff base were synthesized by treating bis{3‐[2‐(4‐amino‐1.5‐dimethyl‐2‐phenyl‐pyrazol‐3‐ylideneamino)ethyl]‐indol‐1‐ylmethyl}‐phosphinic acid with paraformaldehyde and characterized as a novel antioxidant. Its corresponding complexes [(VO)₂L(SO₄)₂], [Ni₂LCl₄], [Co₂LCl₄], [Cu₂LCl₄], [Zn₂LCl₄], [Cd₂LCl₄], [Hg₂LCl₄], [Pd₂LCl₄], and [PtLCl]Cl₂ were analyzed by Fourier transform‐infrared, (¹H and ¹³C) nuclear magnetic resonance, and mass and UV–Vis spectroscopy. Experimental data showed that the ligand coordinated with the metal ions via donor atoms such as nitrogen to form an octahedral arrangement of the Schiff base around the central transition‐metal atom. The nature of these complexes was identified using the molar ratio and Job's methods, with the results agreeing with a metal‐to‐ligand (M:L) molar ratio of 2:1, expect for Pt, whose M:L was 1:1. Thermodynamic activation parameters such as ?E*, ?H*, ?S*, ?G*, and K were determined from the thermogravimetric analysis curve using the Coats–Redfern method. The antioxidant activities of the prepared compounds were assessed by using 1.1‐diphenyl‐2‐picrylhydrazyl as the free radical, and the results show that the complex Schiff bases were found to possess potent antioxidant activity. The structure–activity relationship of the ligand and its complexes indicates that the presence of electron‐donating moieties, such as Co(II) and Ni(II), in the chemical structure increases the antioxidant activity, whereas the Pt(IV) and Pd(II) complexes diminished the antioxidant activity, indicating the superior activity of the hydroxyl radical (OH^·) over the superoxide radical.     

Odd-even behavior of ferroelectricity and antiferroelectricity in two homologous series of bent-core mesogens

Two chiral bent-core mesogens Pn-O-PIMB(n - 2)* (n = 9 and 10) and their oxygen analogues Pn-O-PIMB(n - 2)*-(n - 4)O (n = 8, 9, and 10) with omega-[(S)-amyloxy]alkoxy terminal groups were prepared, and their phase structures were investigated by means of electro-optic, polarization reversal current and second harmonic generation measurements in order to clarify the effect of the interlayer steric interaction on the emergence of polar orderings. The odd-even behavior for the alternative appearance of ferroelectricity and antiferroelectricity was observed in two homologous series; the bent-core mesogens P10-O-PIMB8*, P8-O-PIMB6*-4O, and P10-O-PIMB8*-6O in addition to the previously reported P6-O-PIMB4* and P8-O-PIMB6*, where the length of chains n is even, exhibited ferroelectric phases. On the contrary, the mesogens P7-O-PIMB5*, P9-O-PIMB7*, and P9-O-PIMB7*-5O, where n is odd, showed antiferroelectric phases. It is obvious that the interlayer steric interaction plays a major role for the emergence of a variety of phase structures.