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961.
962.
Time-gated luminescence detection technique using lanthanide complexes as luminescent probes is a useful and highly sensitive
method. However, the effective application of this technique is limited by the lack of the target-responsive luminescent lanthanide
complexes that can specifically recognize various analytes in aqueous solutions. In this work, a dual-functional ligand that
can form a stable complex with Tb3+ and specifically recognize Hg2+ ions in aqueous solutions, N,N,N
1
,N
1
-{[2,6-bis(3′-aminomethyl-1′-pyrazolyl)-4-[N,N-bis(3″,6″-dithiaoctyl)-aminomethyl]- pyridine]} tetrakis(acetic acid) (BBAPTA), has been designed and synthesized. The luminescence
of its Tb3+ complex is weak, but can be effectively enhanced upon reaction with Hg2+ ions in aqueous solutions. The luminescence response investigations of BBAPTA-Tb3+ to various metal ions indicate that the complex has a good luminescence sensing selectivity for Hg2+ ions, but not for other metal ions. Thus a highly sensitive time-gated luminescence detection method for Hg2+ ions was developed by using BBAPTA-Tb3+ as a luminescent probe. The dose-dependent luminescence enhancement of the probe shows a good linearity with a detection
limit of 17 nM for Hg2+ ions. These results demonstrated the efficacy and advantages of the new Tb3+ complex-based luminescence probe for the sensitive and selective detection of Hg2+ ions. 相似文献
963.
以电子回旋脉塞非线性理论为基础, 结合三维电磁仿真软件, 通过导入高频场数值解替代理论解析的方法, 对波瓣波导谐振腔高次谐波太赫兹回旋管进行了理论和模拟研究. 给出了该类回旋管的起振电流、耦合系数以及注波互作用效率等重要参数, 并在此基础上设计了一只工作频率为0.4 THz, 工作模式TE33模三次谐波波瓣波导谐振腔回旋管, 其电子注参数为1.0 A, 40.5 kV, 横纵速度比1.5,互作用区引导磁场为5.09 T, 输出功率达到3.3 kW. 相似文献
964.
本文采用扩展Hubbard模型, 加上长程关联哈密顿量,在自然边界条件下用自洽场方法研究了有限长反式聚乙炔链中极化子的问题。计算了长程电子关联对极化子的影响并计算了极化子的长程关联能。计算发现长程电子关联使极化子的位形变宽变浅(局域性减弱),在极化子区域,长程电子关联能比平均长程电子关联能要大。当链长增加到100格点以上时,电子极化子和空穴极化子的平均关联能趋于-0.1663eV,而在极化子区域,电子极化子和空穴极化子的平均关联能趋于-0.1868eV。 相似文献
965.
The present research presents an extended evacuation field model for simulating crowd emergency evacuation processes under the control of evacuation assistants. Furthermore, a communication field for describing the escape information transmission process and its effect on evacuees is introduced. The effective locations and optimal numbers of evacuation assistants as generated through the model are proposed in an effort to verify as well as enhance existing models. Results show the following. (1) Locating evacuation assistants near exits reduces the time delay for pre-evacuation. (2) There is an optimal number of evacuation assistants for achieving evacuation efficiency; having excessive numbers of evacuation assistants does not improve the evacuation efficiency, and they may result in evacuation time delay and hinder the evacuation efficiency. (3) As the number of evacuees increases, the number of evacuation assistants needed decreases. 相似文献
966.
Using first-principles density functional theory and non-equilibrium Green′s function formalism for quantum transport calculation, we have investigated the electronic transport properties of the boron/nitrogen-doped C131-based molecular junction. Our results show that an obvious rectifying behavior is observed. Moreover, the rectifying performance can be tuned by adjusting the doping sites. The mechanism for the rectifying phenomenon is suggested. The present findings could be helpful for the application of the C131 molecule in the field of single molecular devices or nanometer electronics. 相似文献
967.
Weiguang ChenPengfei Yuan Shuai ZhangQiang Sun Erjun LiangYu Jia 《Physica B: Condensed Matter》2012,407(6):1038-1043
The effects of mono-doping of 4f lanthanides with and without oxygen vacancy defect on the electronic structures of anatase TiO2 have been studied by first-principles calculations with DFT+U (DFT with Hubbard U correction) to treat the strong correlation of Ti 3d electrons and lanthanides 4f electrons. Our results revealed that dopant Ce is easy to incorporate into the TiO2 host by substituting Ti due to its lower substitutional energy (∼−2.0 eV), but the band gap of the system almost keeps intact after doping. The Ce 4f states are located at the bottom of conduction band, which mainly originates from Ti 3d states. The magnetic moment of doped Ce disappears due to electron transfer from Ce to the nearest O atoms. For Pr and Gd doping, their substitutional energies are similar and close to zero, indicating that both of them may also incorporate into the TiO2 host. For Pr doping, some 4f spin-down states are located next to the bottom of the conduction band and narrow the band gap of the doping system. However, for Gd doping, the 4f states are located in deep valence band and there is no intermediate band in the band gap. The magnetic moment of dopant Gd is close to the value of isolated Gd atom (∼7 μB), indicating no overlapping between Gd 4f with other orbitals. For Eu, it is hard to incorporate into the TiO2 host due to its very higher substitutional energy. The results also indicated that oxygen vacancy defect may enhance the adsorption of the visible light in Ln-doped TiO2 system. 相似文献
968.
Electrical impedance tomography is an inverse problem of elliptic differential equations. Numerical methods based on combining generalized difference method and Levenberg–Marquardt iteration on a planar domain are proposed. Positive semi-definiteness and existence of solution of the generalized difference scheme are proved. Element geometry matrix is introduced to shortcut calculation and standardize computer program. A series of numerical experiments verify the reliability of its mathematical model and the feasibility of the algorithm. A class of electrical current patterns is proposed to minimize the number of direct problems to be solved in each iteration. These methods have been applied successfully in practical simulation of electrical impedance tomography. 相似文献
969.
In this paper, a simple repairable system (i.e. a one-component repairable system with one repairman) with preventive repair and failure repair is studied. Assume that the preventive repair is adopted before the system fails, when the system reliability drops to an undetermined constant R , the work will be interrupted and the preventive repair is executed at once. And assume that the preventive repair of the system is “as good as new” while the failure repair of the system is not, and the deterioration of the system is stochastic. Under these assumptions, by using geometric process, we present a bivariate mixed policy (R,N), respectively based on a scale of the system reliability and the failure-number of the system. Our aim is to determine an optimal mixed policy (R,N)∗ such that the long-run average cost per unit time (i.e. the average cost rate) is minimized. The explicit expression of the average cost rate is derived, and the corresponding optimal mixed policy can be determined analytically or numerically. Finally, a numerical example is given where the working time of the system yields a Weibull distribution. Some comparisons with a certain existing policy are also discussed by numerical methods. 相似文献
970.
采用10.6 μupm 的 CO2激光, 对单次激光脉冲辐照修复熔石英存在的烧蚀采用大光斑钝化去除. 经过辐照修复的区域置于前表面测试初始损伤阈值, 结果表明调制造成的损伤得到了一定程度的抑制; 辐照区域置于后表面修复后 熔石英的初始损伤阈值超过了基底的初始损伤阈值. 实验观察到了应力分布外扩, 同时明显减弱. 对损伤增长的测试说明, 经过激光熔融辐照后的损伤点, 当应力释放以后, 损伤扩展初期表现出指数增长趋势, 后期随着辐照次数的增加, 损伤增长不再明显, 并且趋于恒定值. 相似文献