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131.
J. M. Lpez‐Majada H. Palza J. L. Guevara R. Quijada M. C. Martínez R. Benavente J. M. Perea E. Prez M. L. Cerrada 《Journal of Polymer Science.Polymer Physics》2006,44(8):1253-1267
The relationships between the structure and properties have been established for copolymers of propylene and 1‐hexene synthesized with an isotactic metallocene catalyst system. The most important factor affecting the structure and properties of these copolymers is the comonomer content. The thermal treatment, that is, the rate of cooling from the melt, is also important. These factors affect the thermal properties, the degree of crystallinity, and therefore the structural parameters and the viscoelastic behavior. A slow cooling from the melt favors the formation of the γ phase instead of the α modification. Regarding the viscoelastic behavior, the β relaxation, associated with the glass‐transition temperature, is shifted to lower temperatures and its intensity is increased as the 1‐hexene content raises. The microhardness values are correlated with those of the storage modulus deduced from dynamic mechanical thermal analysis curves, and good linear relations have been obtained between these parameters. © 2006 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 44: 1253–1267, 2006 相似文献
132.
A simple field sampling-preconcentration method for zinc determination in seawater is described. Seawater was collected in situ by pumping it through a minicolumn packed with a chelating resin (Chelite P) connected to a field flow preconcentration system (FFPS). These packed minicolumns retain the dissolved zinc, and once are loaded with the analyte, they are returned to the laboratory where they are sequentially inserted into a flow injection system for on-line zinc elution with diluted hydrochloric acid and flame atomic absorption spectrometric detection. A factorial design has been used to optimize the FFPS and the flow injection elution process. The proposed method has a linear calibration range from 0.07 to at least 9.4 microg L(-1) of zinc, with a detection limit of 0.02 microg L(-1) and a throughput of 26 samples h(-1). Validation was carried out against certified reference water samples. This procedure has been successfully applied to the determination of Zn in seawater samples from Galicia (Spain). 相似文献
133.
M. López Granados F. Cabello Galisteo M. Alifanti J.L.G. Fierro 《Applied Surface Science》2006,252(24):8442-8450
This work reports the research carried out by studying aliquots extracted at different axial coordinates from Three Way Catalyst (TWC) monoliths aged under real traffic conditions. Our study focused on the catalytic properties and on several chemical and physical effects caused in the Front and Rear monolith washcoat surfaces by vehicle aging after 60,000 km. Regarding the catalytic properties, all the used aliquots showed poorer activity than their corresponding fresh counterparts. The strongest deactivation was detected for NO and hydrocarbon conversion. CO conversion was less affected and the Rear monolith was as deactivated as the Front one. The characterisation techniques (TXRF, N2 adsorption-desorption isotherms, XRD and H2-TPR) detected - (i) the deposition of P, Zn and Pb; (ii) the formation of CePO4 on account of the Ce from the washcoat; (iii) thermal sintering; (iv) inhibition of the reducibility of Ce oxides - as the main effects brought about by vehicle aging conditions. The deactivation observed at the beginning of the Front monolith was the result of a combination of the former effects. When moving downstream to higher axial coordinates, Pb accumulation and the loss of specific area appeared to be the only probable sources of deactivation. 相似文献
134.
B. Giner I. Gascón A. Villares C. Lafuente 《Journal of Thermal Analysis and Calorimetry》2006,83(3):735-745
The
relation between refractive index deviations and excess volumes for binary
mixtures formed by a cyclic ether and a haloalkane has been tested using several
methods: refractive index mixing rules and equations of state. Refractive
index deviations, excess volumes and molar refractions have been calculated
from experimental data of refractive indices and densities at two temperatures
298.15 and 313.15 K. Results obtained have been discussed in terms of intermolecular
interactions. Refractive indices were compared with those predicted by several
mixing rules. Excess volumes have also been correlated using several cubic
equations of state and finally a relation between parameter b
from equations of state and molar refraction has been provided. 相似文献
135.
136.
J. Balogh D. Kaptás L. F. Kiss T. Kemény L. Bujdosó I. Vincze 《Hyperfine Interactions》2006,169(1-3):1343-1347
Magnetic multilayers of 57Fe with nominal thickness, T
nom, between 0.4 and 1.0 nm separated by 3.0 nm Al spacer layers were prepared by alternate deposition of the constituents in
high vacuum. The samples were investigated at 4.2 K in external magnetic field. A fraction of Fe atoms corresponding to about
0.3 nm equivalent Fe-thickness was found to mix into the Al spacer. The extremely strong magnetic anisotropy observed for
T
nom < 0.8 nm is attributed to Fe layers of approximately two atomic planes thick. The anisotropy decreases considerably after
the building up of the third Fe atomic layer starts at T
nom = 0.8 nm, but full saturation was not achieved even for T
nom = 1 nm and 3 T magnetic field applied perpendicularly to the sample plane. 相似文献
137.
B. E. López M. A. Rodriguez S. L. A. Fucugauchi 《Journal of Radioanalytical and Nuclear Chemistry》1993,175(4):273-280
It has been established that the coexistence of chemical species structurally different from cerium, is a direct consequence of the time taken for its preparation. Its practical applications, within the scope of purifying uranium, may constitute the most important technological aspect in the process of ionic exchange, to separate141Ce from uranium. 相似文献
138.
Let F denote a family of pairwise disjoint convex sets in the plane. F is said to be in convex position if none of its members is contained in the convex hull of the union of the others. For any fixed k≥ 3 , we estimate P
k
(n) , the maximum size of a family F with the property that any k members of F are in convex position, but no n are. In particular, for k=3 , we improve the triply exponential upper bound of T. Bisztriczky and G. Fejes Tóth by showing that P
3
(n) < 16
n
.
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<pdfname>19n3p437.pdf
<pdfexist>yes
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Received March 27, 1997, and in revised form July 10, 1997. 相似文献
139.
M. A. Morón C. Romero F. R. Ruiz del Portal 《Journal of Optimization Theory and Applications》1996,91(3):643-649
The purpose of this paper is to seek utility functions satisfying a weak condition which guarantees that the utility optimum always belongs to the compromise set. This set is a special subset of the attainable or feasible set, which is generated through the application of the well-known operational research approach called compromise programming. It is shown that there are large families of utility functions satisfying this condition, thus reinforcing the value of compromise programming as a good surrogate of the traditional utility optimum.Thanks are due to the reviewers for their helpful suggestions. The English editing by Ms. Christine Méndez is appreciated. The authors have been supported by the Comisión Interministerial de Ciencia y Tecnología (CICYT), Madrid, Spain. 相似文献
140.
János Komlós 《Order》1990,7(2):107-113
Using Ramsey theory, we establish the following pigeon-hole type principle: From a large number of random variables (functions, vectors, etc.) one can always select two, X and Y, such that P(X < Y) 1/2. We apply the principle for a poset problem. 相似文献