The Role of Radial Electric Fields in the Tokamaks TEXTOR-94, CASTOR, and T-10

Radial electric fields (E _r) and their role in the establishment of edge transport barriers and improved confinement have been studied in the tokamaks TEXTOR-94 and CASTOR, where E _r is externally applied to the plasma in a controlled way using a biased electrode, as well as in the tokamak T-10 where an edge transport barrier (H-mode) is obtained during electron-cyclotron resonance heating (ECRH) of the plasma.The physics of radial currents was studied and the radial conductivity in the edge of TEXTOR-94 (R = 1.75 m, a = 0.46 m) was found to be dominated by recycling (ion-neutral collisions) at the last closed flux surface (LCFS) and by parallel viscosity inside the LCFS. From a performance point of view (edge engineering), such electrode biasing was shown to induce a particle transport barrier, a reduction of particle transport, and a concomitant increase in energy confinement. An H-mode-like behaviour can be induced both with positive and negative electric fields. Positive as well as negative electric fields were shown to strongly affect the exhaust of hydrogen, helium, and impurities, not only in the H-mode-like regime.The impact of sheared radial electric fields on turbulent structures and flows at the plasma edge is investigated on the CASTOR tokamak (R = 0.4 m, a = 0.085 m). A non-intrusive biasing scheme that we call "separatrix biasing" is applied whereby the electrode is located in the scrape-off layer (SOL) with its tip just touching the LCFS. There is evidence of strongly sheared radial electric field and E×B flow, resulting in the formation of a transport barrier at the separatrix. Advanced probe diagnosis of the edge region has shown that the E×B shear rate that arises during separatrix biasing is larger than for standard edge plasma biasing. The plasma flows, especially the poloidal E×B drift velocity, are strongly modified in the sheared region, reaching Mach numbers as high as half the sound speed. The corresponding shear rates ( 5×10⁶ s^-1) derived from both the flow and electric field profiles are in excellent agreement and are at least an order of magnitude higher than the growth rate of unstable turbulent modes as estimated from fluctuation measurements.During ECRH in the tokamak T-10 (R = 1.5 m, a = 0.3 m), a regime of improved confinement is obtained with features resembling those in the H-mode in other tokamaks. Using a heavy ion beam probe, a narrow potential well is observed near the limiter together with the typical features of the L-H transition. The time evolution of the plasma profiles during L-H and H-L transitions is clearly correlated with that of the density profile and the formation of a transport barrier near the limiter. The edge electric field is initially positive after the onset of ECRH. It changes its sign during the L-H transition and grows till a steady condition is reached. Similar to the biasing experiments in TEXTOR-94 and CASTOR, the experimentally observed transport barrier is a barrier for particles.     

Monotone iterative scheme for nonlinear hyperbolic boundary value problem

Monotone iterative scheme for nonlinear hyperbolic boundary value problem is established.     

A perturbation solution of Michaelis–Menten kinetics in a “total” framework

In this paper we expand the equations governing Michaelis–Menten kinetics in a total quasi-steady state setting, finding the first order uniform expansions. Our results improve previous approximations and work well especially in presence of an enzyme excess.     

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Conformational analysis of 1,2-difluoroethane, an ab-initio investigation

Contrary to expectation, the gauche conformer of 1,2-difluoroethane is more stable than the trans conformer in the gas phase. In order to understand the underlying causes of the “gauche effect”, a complete geometry relaxation was performed for the gauche and trans conformers of 1,2-difluoroethane with the 4-21G, 4-31G and 4-31G** basis sets. The 4-31G** optimized geometry of the gauche conformer compares well with the experimental values obtained from a number of electron-diffraction studies. A correction for the correlation energy, calculated by means of second-order Møller—Plesset perturbation theory with the 6-31G** basis set, proves to be essential to obtain a correct estimate of the energy difference between the gauche and trans conformers 1,2-difluoroethane.     

Diffusion effects on the interfacial tension of immiscible polymer blends

Most methods of measuring the interfacial tension between two immiscible polymers are based on the analysis of the shape that a drop of one polymer immersed in the other one exhibits under the action of flow or gravity. In such a situation, the small, yet nonzero mutual solubility between the two polymers acts toward mass transfer between the drop and the surrounding fluid. In this work, diffusion effects on the interfacial tension of the pair polyisobutylene/polydimethylsiloxane have been investigated by drop deformation under shear flow. When the drop was made of polyisobutylene, drop size decreased with time due to diffusion. Drop shrinkage was associated with a significant increase in interfacial tension, until an apparent plateau value was reached. The effect was attributed to a selective migration of molecular weights, which would act to enrich the drop with higher molar mass material. To support such an interpretation, drop viscosity was evaluated by drop shape analysis and it was actually found to increase with time. In some cases, the ratio between drop and continuous phase viscosity became higher than the critical value for drop breakup in shear flow. Upon inverting the phases (i.e., when the drop was made of polydimethylsiloxane), no significant transient effects were observed. In the light of these results, the problem of what are the correct values of interfacial tension and viscosity ratio for a polymer blend of a certain composition will also be discussed. Received: 25 January 1999 Accepted: 24 May 1999     

Lingshuine,an Unexpected Passerini Product from the Hainan Sponge Axinyssa variabilis

Lingshuine ( 1 ), a novel sesquiterpene amide, along with three known N‐containing compounds, 2 – 4 , have been isolated from the Hainan sponge Axinyssa variabilis. The structure of 1 was elucidated by detailed analysis of the spectroscopic data and by chemical methods. Lingshuine represents the first example of a Passerini product formed during the isolation process.     

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