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11.
Vladimir S. Koroliuk Raimondo Manca Guglielmo D’Amico 《Journal of Mathematical Sciences》2014,196(5):644-651
The storage impulsive processes given by a sum of random variables on a superposition of two renewal processes are considered on increasing time intervals. The averaging, diffusion approximation, and large deviation problem are studied in the series scheme with a small parameter series under suitable scaling. 相似文献
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Guglielmo D’Amico 《Applications of Mathematics》2014,59(5):571-588
Markov chain usage models were successfully used to model systems and software. The most prominent approaches are the so-called failure state models Whittaker and Thomason (1994) and the arc-based Bayesian models Sayre and Poore (2000). In this paper we propose arc-based semi-Markov usage models to test systems. We extend previous studies that rely on the Markov chain assumption to the more general semi-Markovian setting. Among the obtained results we give a closed form representation of the first and second moments of the single-use reliability. The model and the validity of the results are illustrated through a numerical example. 相似文献
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Depending on their relative orientation, coupled oscillating carbonyl groups provide a VCD spectrum with a characteristic CO bond stretching region showing a strong bisignate VCD feature, which can be readily predicted adopting long available semiempirical methods. The extended coupled oscillator (ECO) formalism has been used to assign the absolute configuration of a recently synthesized chiral 3-substituted isoindolinone. The prediction of (S) configuration for the (−) enantiomer has been confirmed by quantum mechanical calculations. 相似文献
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Highly Axial Magnetic Anisotropy in a N3O5 Dysprosium(III) Coordination Environment Generated by a Merocyanine Ligand
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Pramila Selvanathan Gang Huang Thierry Guizouarn Dr. Thierry Roisnel Dr. Guglielmo Fernandez‐Garcia Dr. Federico Totti Dr. Boris Le Guennic Dr. Guillaume Calvez Dr. Kévin Bernot Dr. Lucie Norel Prof. Stéphane Rigaut 《Chemistry (Weinheim an der Bergstrasse, Germany)》2016,22(43):15222-15226
A spiropyran‐based switchable ligand isomerizes upon reaction with lanthanide(III) precursors to generate complexes with an unusual N3O5 coordination sphere. The air‐stable dysprosium(III) complex shows a hysteresis loop at 2 K and a very strong axial magnetic anisotropy generated by the merocyanine phenolate donor. 相似文献
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The dynamic structure factor of m-toluidine has been measured by inelastic x-ray scattering in the mesoscopic Q range between 1 and 10 nm(-1), where a prepeak is revealed in the static structure factor resulting from the existence of hydrogen bonded, nanometer size clusters. Evidence is given of (i) a square-root cusp in the nonergodicity factor and of (ii) critical nonergodicity parameters which oscillate in phase with the static structure factor. These results demonstrate that local order in a liquid can coexist with the signatures of the ergodic to nonergodic transition predicted by the mode coupling theory for simple, dense liquids. 相似文献
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Correlation-induced double-plasmon excitation in simple metals studied by inelastic x-ray scattering
Sternemann C Huotari S Vankó G Volmer M Monaco G Gusarov A Lustfeld H Sturm K Schülke W 《Physical review letters》2005,95(15):157401
We report a new type of peaklike structure observed in the tail of the dynamic structure factor of simple metals, measured by inelastic x-ray scattering. Based on the momentum-transfer dependence of the energy position and the intensity of this structure, it has been unambiguously attributed to intrinsic plasmon-plasmon excitations, an electronic correlation effect that was theoretically predicted by many-body perturbation theory of the homogeneous-electron-gas model beyond the random-phase approximation. This signature appears to be largely unaffected by electron-ion interaction effects. Thus a structure that is primarily caused by correlation effects in the electron gas has been found experimentally in the dynamic structure factor of simple metals. 相似文献
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