Constituents of the roots of Rubia yunnanensis

Four new naphthohydroquinones, rubinaphthins A (1), B (2), C (3), and D (4), together with 11 known compounds were isolated and characterized from the roots of Rubia yunnanensis. The structures of 1-4 were elucidated by spectral analysis and chemical transformation.     

Stress singularity due to traction discontinuity on an anisotropic elastic half-plane

In a half-plane problem with x₁ paralleling with the straight boundary and x₂ pointing into the medium, the stress components on the boundary whose acting plane is perpendicular to x₁ direction may be denoted by t₁ = [σ₁₁, σ₁₂, σ₁₃]^T. Stress components σ₁₁ and σ₁₃ are of more interests since σ₁₂ is completely determined by the boundary conditions. For isotropic materials, it is known that under uniform normal loading σ₁₁ is constant in the loaded region and vanishes in the unloaded part. Under uniform shear loading, σ₁₁ will have a logarithmic singularity at the end points of shear loading. In this paper, the behavior of the stress components σ₁₁ and σ₁₃ induced by traction-discontinuity on general anisotropic elastic surfaces is studied. By analyzing the problem of uniform tractions applied on the half-plane boundary over a finite loaded region, exact expressions of the stress components σ₁₁ and σ₁₃ are obtained which reveal that these components consist of in general a constant term and a logarithmic term in the loaded region, while only a logarithmic term exists in unloaded region. Whether the constant term or the logarithmic term will appear or not completely depends on what values of the elements of matrices Ω and Γ will take for a material under consideration. Elements for both matrices are expressed explicitly in terms of elastic stiffness. Results for monoclinic and orthotropic materials are all deduced. The isotropic material is a special case of the present results.     

硼酰化钴中硼的快速测定

硼酰化钴中硼的测定采用EDTA作为钴的络合掩蔽剂,消除了钴对测定硼的影响。同时改用溴甲酚绿-甲基红-酚酞三元混合指示剂作为测定硼的指示剂,使滴定终点灵敏、准确。建立了一种测定硼酰化钴中硼含量的简便、快速的分析方法。     

On Topological Index of Solutions for Variational Inequalities on Riemannian Manifolds

In this paper, based on the fixed point index theory for a class of -multivalued maps on absolute neighbourhood retracts, we introduce the notion of index of solvability for a variational inequality on a Riemannian manifold involving a multivalued vector field. We describe the main properties of this topological characteristic and use it to justify the existence of a solution for a variational inequality problem. As application, the problem of optimization of a non-smooth functional on a Hadamard manifold is considered.     

Ignition and combustion study of JP-8 fuel in a supersonic flowfield

The ignition and combustion process of fuels in a supersonic combustion chamber plays an important role in the design of hypersonic propulsion system. However, it is a quite complicated process, due to the large variation of inlet air velocity, temperature, oxygen concentration, and shocks in the supersonic combustion chamber. The purpose of this paper is to observe the ignition delay and combustion phenomenon of the JP-8 fuel droplets in a supersonic flowfield experimentally. A shock tube is used as a basic test facility to create a high-speed and high-temperature flowfield as a supersonic combustor. In the experiments, several test parameters are controlled, such as shock velocity, gas temperature, fuel droplet size and distance, initial fuel temperature, and oxygen concentration, etc. The test results show the influence of these parameters on ignition delay, ignition limitation, and detonation. The most important factor in the experiment is the initial fuel temperature effect, which is influenced by the altitude variation during a flight. Received 4 August 1995 / Accepted 12 December 1995     

Emulsion Polymerization of Acrylic Monomers Stabilized by Poly(Ethylene Oxide)

Abstract

The stability of acrylic latices stabilized by poly(ethylene oxide) (PEO) is governed by the bridging flocculation process during polymerization. The final latex particle size increases with increasing concentration of initiator, PEO, or NaCl. The total scrap formed during the reaction increases rapidly with increasing NaCl concentration due to the ionic strength effect. It is shown that the final latex particle size decreases rapidly with an increase in the agitation speed. The amount of total scrap formed during polymerization is generally greater at a higher agitation speed. These results suggest that the fraction of the particle surface covered by PEO and the ratio of the thickness of the PEO adsorption layer to that of the electric double layer of the latex particles should play an important role in determining the final latex particle size and colloidal stability.     

Novel thermally stable poly(amine hydrazide)s and poly(amine‐1,3,4‐oxadiazole)s for luminescent and electrochromic materials

We describe the preparation, characterization, and luminescence of four novel electrochromic aromatic poly(amine hydrazide)s containing main‐chain triphenylamine units with or without a para‐substituted N,N‐diphenylamino group on the pendent phenyl ring. These polymers were prepared from either 4,4′‐dicarboxy‐4″‐N,N‐diphenylaminotriphenylamine or 4,4′‐dicarboxytriphenylamine and the respective aromatic dihydrazide monomers via a direct phosphorylation polycondensation reaction. All the poly(amine hydrazide)s were amorphous and readily soluble in many common organic solvents and could be solution‐cast into transparent and flexible films with good mechanical properties. These poly(amine hydrazide)s exhibited strong ultraviolet–visible absorption bands at 346–348 nm in N‐methyl‐2‐pyrrolidone (NMP) solutions. Their photoluminescence spectra in NMP solutions or as cast films showed maximum bands around 508–544 and 448–487 nm in the green and blue region for the two series of polymers. The hole‐transporting and electrochromic properties were examined by electrochemical and spectroelectrochemical methods. All obtained poly(amine hydrazide)s and poly(amine‐1,3,4‐oxadiazole)s exhibited two reversible oxidation redox couples at 0.8 and 1.24 V vs. Ag/AgCl in acetonitrile solution and revealed excellent stability of electrochromic characteristics, changing color from original pale yellow to green and then to blue at electrode potentials of 0.87 and 1.24 V, respectively. © 2005 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 43: 3245–3256, 2005