首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   3720篇
  免费   541篇
  国内免费   604篇
化学   2982篇
晶体学   48篇
力学   174篇
综合类   75篇
数学   388篇
物理学   1198篇
  2024年   14篇
  2023年   69篇
  2022年   145篇
  2021年   141篇
  2020年   149篇
  2019年   181篇
  2018年   131篇
  2017年   148篇
  2016年   191篇
  2015年   189篇
  2014年   223篇
  2013年   241篇
  2012年   311篇
  2011年   331篇
  2010年   246篇
  2009年   226篇
  2008年   259篇
  2007年   233篇
  2006年   196篇
  2005年   181篇
  2004年   168篇
  2003年   117篇
  2002年   142篇
  2001年   127篇
  2000年   89篇
  1999年   71篇
  1998年   43篇
  1997年   35篇
  1996年   44篇
  1995年   47篇
  1994年   30篇
  1993年   21篇
  1992年   14篇
  1991年   27篇
  1990年   15篇
  1989年   19篇
  1988年   9篇
  1987年   9篇
  1986年   8篇
  1985年   7篇
  1983年   6篇
  1982年   1篇
  1981年   1篇
  1980年   1篇
  1979年   2篇
  1977年   1篇
  1975年   3篇
  1961年   1篇
  1957年   1篇
  1936年   1篇
排序方式: 共有4865条查询结果,搜索用时 15 毫秒
91.
A program is modeled to describe nitriding depth by a new mixing laser and plasma beams nitriding (LPN) technique. The model extends the transport of ions in matter (TRIM) program by adding temperature and energy factors into the energy function. The nitriding depths and nitrogen distribution in substrate were calculated by Monte Carlo program. There is a good agreement between calculation and experiment results at different laser energy intensities, scanning velocities and nitrogen ion energies respectively. Moreover, the nitriding process diagrams by LPN technique are shown from calculation results.  相似文献   
92.
Motivated by the recent pioneering advances on nanoscale plasmonics and also nanophotonics technology based on the surface plasmons (SPs), in this work, we give a master equation model in the Lindblad form and investigate the quantum optical properties of single quantum dot (QD) emitter coupled to the SPs of a metallic nanowire. Our main results demonstrate the QD luminescence results of photon emission show three distinctive regimes depending on the distance between QD and metallic nanowire, which elucidates a crossover passing from being metallic dissipative for much smaller emitter-nanowire distances to surface plasmon (SP) emission for larger separations at the vicinity of plasmonic metallic nanowire. Besides, our results also indicate that, for both the resonant case and the detuning case, through measuring QD emitter luminescence spectra and second-order correlation functions, the information about the QD emitter coupling to the SPs of the dissipative metallic nanowire can be extracted. This theoretical study will serve as an introduction to understanding the nanoplasmonic imaging spectroscopy and pave a new way to realize the quantum information devices.  相似文献   
93.
Synthetic hydromagnesite (SHM), used as flame retardant for polymers, may have similar or better flame retardancy effectiveness than aluminum tri-hydroxide (ATH) and magnesium di-hydroxide (MDH). Suitable surface modifiers are often employed to improve its dispersion and compatibility with polymer matrix. In this study, we chose stearic acid (SA) and zinc stearate (ZS) as the surface modifier, and investigated the properties of SHM modified with various surface modifier content using dry blending coating process. Scanning electron microscope (SEM), X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FT-IR), thermogravimetry (TG), particle size distribution, contact angle, oil absorption, bulk density, tapped density and Carr's index were employed to characterize the effect of surface modification. The results showed that the surface of SHM powders was changed from hydrophilic to lipophilic. The flowability of the surface modified powder was also improved. TG graphs showed that the surface modifier had no obvious influence on the degradation pathway of the SHM.  相似文献   
94.
Nanosecond-pulsed KrF (248 nm, 25 ns) and Nd:YAG (1064 nm, 532 nm, 355 nm, 5 ns) lasers were used to ablate a polycrystalline Si target in a background pressure of <10−4 Pa. Si films were deposited on Si and GaAs substrates at room temperature. The surface morphology of the films was characterized using scanning electron microscopy (SEM) and atomic force microscopy (AFM). Round droplets from 20 nm to 5 μm were detected on the deposited films. Raman Spectroscopy indicated that the micron-sized droplets were crystalline and the films were amorphous. The dependence of the properties of the films on laser wavelengths and fluence is discussed.  相似文献   
95.
薛珊  曹国华  杨浦良  刘晗  宋玉龙 《应用光学》2011,32(6):1067-1071
 转板是光电雷达稳定平台的关键元件之一。为了更好地设计和分析某光电雷达稳定平台的转板,运用Pro E软件对其进行三维实体建模,合理简化后,进入Ansys软件界面建立有限元模型。应用有限元理论和Ansys软件对其进行动态特性分析,得到了转板前八阶模态的固有频率和振型,以及要求范围内的谐响应。对比了不同方法划分网格的网格质量,采取不同材料得到了不同模态。分析结果表明:设计的转板在关心的频段0~50 Hz,2 000 Hz~8 000 Hz内不发生共振,符合设计要求。  相似文献   
96.
The accumulation effects in high-reflectivity(HR) HfO2/SiO2 coatings under laser irradiation are investigated.The HR HfO2/SiO2 coatings are prepared by electron beam evaporation at 1 064 nm.The laser-induced damage threshold(LIDT) are measured at 1 064 nm and at a pulse duration of 12 ns,in 1-on-1 and S-on-1 modes.Multi-shot LIDT is lower than single-shot LIDT.The laser-induced and native defects play an important role in the multi-shot mode.A correlative theory model based on critical conduction band electron density is constructed to elucidate the experimental phenomena.  相似文献   
97.
朱峰  董珊  承刚 《中国物理 B》2011,20(7):77103-077103
The global greenhouse effect makes it urgent to deal with the increasing greenhouse gases.In this paper the performance of MgO-decorated carbon nanotubes for CO 2 adsorption is investigated through first principles calculations.The results show that the MgO-decorated carbon nanotubes can adsorb CO 2 well and are relatively insensitive to O 2 and N 2 at the same time.The binding energy arrives at 1.18 eV for the single-MgO-decorated carbon nanotube adsorbing one CO 2 molecule,while the corresponding values for O 2 and N 2 are 0.55 eV and 0.06 eV,respectively.In addition,multi-molecule adsorption is also proved to be very satisfactory.These results indicate that MgO-decorated carbon nanotubes have great potential applications in industrial and environmental processes.  相似文献   
98.
钙钛矿CaTiO3的超高压结构研究   总被引:4,自引:0,他引:4       下载免费PDF全文
巫翔  秦善  吴自玉  董宇辉  刘景  李晓东 《物理学报》2004,53(6):1967-1971
利用同步辐射x射线衍射和 DAC 高压技术在室温下测量了钙钛矿CaTiO3在压力0—44.53 GPa下的结构变化.结果表明,随着压力的增加CaTiO3的三个晶轴都受到不同程度的压缩,a,b的压缩率相近且相对比较大,c的压缩率最小,但没有证据表明有相变的发生.在压力范围内CaTiO3的P-V关系用Murnaghan状态方程表示,设定K′0=4,得到V0=0.2245(6)nm3和K0=222(9) GPa.应用赝立方角γpc与压力的关系,初 关键词: 3')" href="#">CaTiO3 结构 超高压 状态方程  相似文献   
99.
A gas-filled type of recoil separator for heavy element research was installed at an experimental hall of RIKEN Linear Accelerator facility to realize getting higher intensity of primary beam and long beam time. Performance of the separator was studied using target recoils and various nuclear reactions. The results show the high performance of the separator for heave element research. As an application of the GARIS, production and identification of an isotope of the 110th element 271[110] have been performed using the 208Pb(64Ni,1n)271[110] reaction. Three decay chains coincide well both in decay times and energies with the ones reported by the group of SHIP experiment at GSI, Germany. Our results provide a confirmation of the synthesis of an isotope 271[110] of element 110.  相似文献   
100.
The detection of saccharides in biological media is of great current importance for the monitoring of disease states. We have previously reported that solutions of boronic acid-functionalized macrocycles form acyclic oligomeric materials in situ. The oligomers contain fluorescent xanthene moieties. Current efforts are aimed at modulating the spectroscopic responses of these materials for the analysis of specific sugars. We describe conditions whereby the xanthene boronic acids exhibit high colorimetric fructose selectivity. In contrast, at physiological levels selective glucose monitoring can be achieved via fluorescence. Additionally, we describe a method which exhibits promise for detecting both glucose and fructose at dual wavelengths in the UV-Vis region. Mechanistic rationale for each of these findings is presented.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号